Dye-sensitized solar cell characteristics of nanocomposite zinc ferrite working electrode: Effect of composite precursors and titania as a blocking layer on photovoltaic performance

[Display omitted] •Nanocomposites of zinc ferrite have been prepared by different precursors.•Nanocomposites of zinc ferrite working electrode have been fabricated.•Dye-sensitized solar cell characteristics of composites have been examined.•Zinc ferrite was used as working electrodes in dye sensitiz...

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Published inSpectrochimica acta. Part A, Molecular and biomolecular spectroscopy Vol. 110; pp. 226 - 232
Main Authors Habibi, Mohammad Hossein, Habibi, Amir Hossein, Zendehdel, Mahmoud, Habibi, Mehdi
Format Journal Article
LanguageEnglish
Published England Elsevier B.V 01.06.2013
Subjects
Coloring Agents - chemistry
Dye-sensitized solar cell (DSSC)
Electric Power Supplies
Electrodes
Ferric Compounds - chemistry
Nanocomposites - chemistry
Nanoporous
Precursor
Solar Energy
Zinc Compounds - chemistry
ZnFe2O4 photoelectrode sol–gel method
ZnFe2O4 photoelectrode sol–gel method
Dye-sensitized solar cell (DSSC)
Nanoporous
Precursor
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Abstract [Display omitted] •Nanocomposites of zinc ferrite have been prepared by different precursors.•Nanocomposites of zinc ferrite working electrode have been fabricated.•Dye-sensitized solar cell characteristics of composites have been examined.•Zinc ferrite was used as working electrodes in dye sensitized solar cells. This research investigates the performance of a zinc ferrite (ZF) as working electrodes in a dye-sensitized solar cell (DSSC). This ZF working electrode was prepared by sol–gel and thermal decomposition of four different precursors including: zinc acetate dihydrate (Zn(CH3COO)2⋅2H2O), ferric nitrate nonahydrate (Fe(NO3)3⋅9H2O), iron(III) acetate; Fe(C2H3O2)3, and zinc nitrate hexahydrate, Zn(NO3)2⋅6H2O. The effects of annealing temperature and precursors on the structural, morphological, and optical properties were investigated. The field emission scanning electron microscope images (FESEM) and scanning electron microscopy (SEM) show that ZFe films are polycrystalline in nature and homogeneous with densely packed grains. Nanoporous zinc ferrite coatings were prepared by doctor blade technique on the fluorine-doped tin oxide (FTO) and used as working electrodes in DSSC. In all DSSCs, platinized FTO and [Co(bpy)3]2+/3+ in 3-methoxy proponitrile were used as counter electrode and redox mediator system respectively. Comparing the fill factors of four different zinc ferrite nanocomposites, the highest fill factor was for ZnFe2O4–TBL sample. Cell fabricated with ZnFeA working electrode shows relatively higher Jsc.
AbstractList [Display omitted] •Nanocomposites of zinc ferrite have been prepared by different precursors.•Nanocomposites of zinc ferrite working electrode have been fabricated.•Dye-sensitized solar cell characteristics of composites have been examined.•Zinc ferrite was used as working electrodes in dye sensitized solar cells. This research investigates the performance of a zinc ferrite (ZF) as working electrodes in a dye-sensitized solar cell (DSSC). This ZF working electrode was prepared by sol–gel and thermal decomposition of four different precursors including: zinc acetate dihydrate (Zn(CH3COO)2⋅2H2O), ferric nitrate nonahydrate (Fe(NO3)3⋅9H2O), iron(III) acetate; Fe(C2H3O2)3, and zinc nitrate hexahydrate, Zn(NO3)2⋅6H2O. The effects of annealing temperature and precursors on the structural, morphological, and optical properties were investigated. The field emission scanning electron microscope images (FESEM) and scanning electron microscopy (SEM) show that ZFe films are polycrystalline in nature and homogeneous with densely packed grains. Nanoporous zinc ferrite coatings were prepared by doctor blade technique on the fluorine-doped tin oxide (FTO) and used as working electrodes in DSSC. In all DSSCs, platinized FTO and [Co(bpy)3]2+/3+ in 3-methoxy proponitrile were used as counter electrode and redox mediator system respectively. Comparing the fill factors of four different zinc ferrite nanocomposites, the highest fill factor was for ZnFe2O4–TBL sample. Cell fabricated with ZnFeA working electrode shows relatively higher Jsc.
This research investigates the performance of a zinc ferrite (ZF) as working electrodes in a dye-sensitized solar cell (DSSC). This ZF working electrode was prepared by sol-gel and thermal decomposition of four different precursors including: zinc acetate dihydrate (Zn(CH3COO)2·2H2O), ferric nitrate nonahydrate (Fe(NO3)3·9H2O), iron(III) acetate; Fe(C2H3O2)3, and zinc nitrate hexahydrate, Zn(NO3)2·6H2O. The effects of annealing temperature and precursors on the structural, morphological, and optical properties were investigated. The field emission scanning electron microscope images (FESEM) and scanning electron microscopy (SEM) show that ZFe films are polycrystalline in nature and homogeneous with densely packed grains. Nanoporous zinc ferrite coatings were prepared by doctor blade technique on the fluorine-doped tin oxide (FTO) and used as working electrodes in DSSC. In all DSSCs, platinized FTO and [Co(bpy)3](2+/3+) in 3-methoxy proponitrile were used as counter electrode and redox mediator system respectively. Comparing the fill factors of four different zinc ferrite nanocomposites, the highest fill factor was for ZnFe2O4-TBL sample. Cell fabricated with ZnFeA working electrode shows relatively higher Jsc.
Author Habibi, Amir Hossein
Zendehdel, Mahmoud
Habibi, Mohammad Hossein
Habibi, Mehdi
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Keywords ZnFe2O4 photoelectrode sol–gel method
Dye-sensitized solar cell (DSSC)
Nanoporous
Precursor
Language English
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Snippet [Display omitted] •Nanocomposites of zinc ferrite have been prepared by different precursors.•Nanocomposites of zinc ferrite working electrode have been...
This research investigates the performance of a zinc ferrite (ZF) as working electrodes in a dye-sensitized solar cell (DSSC). This ZF working electrode was...
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SubjectTerms Coloring Agents - chemistry
Dye-sensitized solar cell (DSSC)
Electric Power Supplies
Electrodes
Ferric Compounds - chemistry
Nanocomposites - chemistry
Nanoporous
Precursor
Solar Energy
Zinc Compounds - chemistry
ZnFe2O4 photoelectrode sol–gel method
Title Dye-sensitized solar cell characteristics of nanocomposite zinc ferrite working electrode: Effect of composite precursors and titania as a blocking layer on photovoltaic performance
URI https://dx.doi.org/10.1016/j.saa.2013.03.051
https://www.ncbi.nlm.nih.gov/pubmed/23571086
Volume 110
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