On the solubility of whitlockite, Ca9Mg(HPO4)(PO4)6, in aqueous solution at 298.15 K
Whitlockite was assigned the ideal formula Ca 9 Mg(HPO 4 )(PO 4 ) 6 , but the synthesis of a solid phase with this exact composition is very difficult. One of the reasons arises from the fact that there are no accurate values published for its solubility constant and/or other thermodynamic parameter...
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Published in | Monatshefte für Chemie Vol. 149; no. 2; pp. 253 - 260 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
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01.02.2018
Springer Nature B.V |
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Abstract | Whitlockite was assigned the ideal formula Ca
9
Mg(HPO
4
)(PO
4
)
6
, but the synthesis of a solid phase with this exact composition is very difficult. One of the reasons arises from the fact that there are no accurate values published for its solubility constant and/or other thermodynamic parameters. These could help to delineate a stability field in relation to the most common solid calcium and magnesium phosphates which normally co-occur with whitlockite. Calcium magnesium phosphates with the structure of whitlockite containing various
n
Mg
/
n
Ca
ratios were synthesized from aqueous solution of pH between 5.0 and 6.0, with the ratio of the concentrations of magnesium and calcium between 0.4 and 1.5, and excess of total calcium and magnesium over total phosphate. Those solids were used to determine the solubility of whitlockite with the ideal formula [lg
K
s
(whitlockite, solid, 298.15 K) = − 113.75 ± 2.18], which was used to determine its standard molar Gibbs energy of formation. This value, together with the previously published values for the standard molar Gibbs energy of formation of the relevant calcium and magnesium solid phosphates and other species at equilibrium, allowed the construction of a phase diagram containing all the relevant solid calcium and magnesium phosphates.
Graphical abstract |
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AbstractList | Whitlockite was assigned the ideal formula Ca9Mg(HPO4)(PO4)6, but the synthesis of a solid phase with this exact composition is very difficult. One of the reasons arises from the fact that there are no accurate values published for its solubility constant and/or other thermodynamic parameters. These could help to delineate a stability field in relation to the most common solid calcium and magnesium phosphates which normally co-occur with whitlockite. Calcium magnesium phosphates with the structure of whitlockite containing various nMg/nCa ratios were synthesized from aqueous solution of pH between 5.0 and 6.0, with the ratio of the concentrations of magnesium and calcium between 0.4 and 1.5, and excess of total calcium and magnesium over total phosphate. Those solids were used to determine the solubility of whitlockite with the ideal formula [lg Ks(whitlockite, solid, 298.15 K) = − 113.75 ± 2.18], which was used to determine its standard molar Gibbs energy of formation. This value, together with the previously published values for the standard molar Gibbs energy of formation of the relevant calcium and magnesium solid phosphates and other species at equilibrium, allowed the construction of a phase diagram containing all the relevant solid calcium and magnesium phosphates.Graphical abstract Whitlockite was assigned the ideal formula Ca 9 Mg(HPO 4 )(PO 4 ) 6 , but the synthesis of a solid phase with this exact composition is very difficult. One of the reasons arises from the fact that there are no accurate values published for its solubility constant and/or other thermodynamic parameters. These could help to delineate a stability field in relation to the most common solid calcium and magnesium phosphates which normally co-occur with whitlockite. Calcium magnesium phosphates with the structure of whitlockite containing various n Mg / n Ca ratios were synthesized from aqueous solution of pH between 5.0 and 6.0, with the ratio of the concentrations of magnesium and calcium between 0.4 and 1.5, and excess of total calcium and magnesium over total phosphate. Those solids were used to determine the solubility of whitlockite with the ideal formula [lg K s (whitlockite, solid, 298.15 K) = − 113.75 ± 2.18], which was used to determine its standard molar Gibbs energy of formation. This value, together with the previously published values for the standard molar Gibbs energy of formation of the relevant calcium and magnesium solid phosphates and other species at equilibrium, allowed the construction of a phase diagram containing all the relevant solid calcium and magnesium phosphates. Graphical abstract |
Author | Costa, M. Odete G. Magalhães, M. Clara F. |
Author_xml | – sequence: 1 givenname: M. Clara F. orcidid: 0000-0002-3359-850X surname: Magalhães fullname: Magalhães, M. Clara F. email: mclara@ua.pt organization: Department of Chemistry and CICECO-Aveiro Institute of Materials, University of Aveiro – sequence: 2 givenname: M. Odete G. surname: Costa fullname: Costa, M. Odete G. organization: Department of Chemistry and CICECO-Aveiro Institute of Materials, University of Aveiro |
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Cites_doi | 10.1016/S0016-7037(02)00833-5 10.1016/S1063-4584(05)80041-X 10.1002/crat.200900017 10.1007/s003920170062 10.1007/BF00601470 10.1127/0935-1221/2003/0015-1001 10.1016/0039-9140(67)80105-X 10.1016/0022-0248(86)90435-5 10.1078/0344-0338-00425 10.2134/jeq1999.00472425002800020018x 10.1136/ard.54.5.339 10.1021/j100847a039 10.4028/www.scientific.net/MSF.587-588.7 10.1039/tf9635901585 10.1002/0470092122.ch3 10.1007/978-1-4757-5506-0 10.1007/s003450050152 10.1038/sj.ki.5002028 10.1021/nn405246h |
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Keywords | Calcium–magnesium phosphate Whitlockite Phase diagram Solubility constant |
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References | JangHLJinKLeeJKimYNahmSHHongKSNamKTACS Nano201486341:CAS:528:DC%2BC3sXhvFSqtL7N10.1021/nn405246h GodinhoMMMem Not197069971:CAS:528:DyaE2MXhtlOhsLg%3D Wagman DD, Evans WH, Parker VB, Schumm RH, Halow I, Bailey SM, Churney KL, Nuttall RL (1982) Journal of Physical and Chemical Reference Data 11, (Suppl 2), pp 64, 73, 76, 260, 267, 270 FrondelCAm Min194934692 DanilchenkoSProtsenkoISukhodubLCryst Res Technol2009445531:CAS:528:DC%2BD1MXmslaqsLs%3D10.1002/crat.200900017 LagierRBaudCAPathol Res Pract20031993291:CAS:528:DC%2BD3sXnvFOhurc%3D10.1078/0344-0338-00425 VerberckmoesSPersyVBehetsGNevenEHufkensAZebger-GongHMüllerDHaffnerDQuerfeldUBothicSDe BroeMD’HaesePKidney Int2007712981:CAS:528:DC%2BD2sXhsVersL0%3D10.1038/sj.ki.5002028 CorlettMKepplerUNaturwissenschaften1966531051:CAS:528:DyaF28XhtVamsLs%3D10.1007/BF00601470 ScotchfordCAAliSYAnn Rheum Dis1995543391:STN:280:DyaK2MzhsVersg%3D%3D10.1136/ard.54.5.339 Marques PAAP (2003) Surface reactions of calcium phosphates ceramics in simulated plasmas. Unpublished PhD Thesis (in Portuguese), Universidade de Aveiro, Aveiro Robie RA, Hemingway BS, Fisher JR (1978) Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 Pascal) pressure and at higher temperatures. U.S. Geological Survey bulletin 1452, pp 12, 14, 19, 20 FrondelCAm Min1941261451:CAS:528:DyaH3MXjtVSrtQ%3D%3D XiandeXMinittiMEMingCHo-KwangMDeqiangWJinfuSYingweiFGeochim Cosmochim Acta200266243910.1016/S0016-7037(02)00833-5 PerrinDDSayceIGTalanta1967148331:CAS:528:DyaF2sXkvVGns74%3D10.1016/0039-9140(67)80105-X MagalhãesMCFMarquesPAAPCorreiaRNKönigsbergerEKönigsbergerLCCalcium and Magnesium phosphates: Normal and Pathological MineralizationBiomineralization: medical aspects of solubility2006ChichesterWiley7110.1002/0470092122.ch3 HamadMHeughebaertJCJ Cryst Growth1986791921:CAS:528:DyaL2sXhtFWmsrs%3D10.1016/0022-0248(86)90435-5 XiandeXMinittiMEMingCHo-KwangMDeqiangWJinfuSYingweiFEur J Miner200315100110.1127/0935-1221/2003/0015-1001 LeGerosRZCalcium Phosphates in Oral Biology and Medicine1991BaselKarger JaynesWMoorePMillerDJ Environ Qual1999285301:CAS:528:DyaK1MXhvFyrt74%3D10.2134/jeq1999.00472425002800020018x SakaeTYamamotoHMishimaHMatsumotoTKozawaYScanning Microsc198938551:CAS:528:DyaK3cXitlegsrc%3D ScotchfordCAVickersMAliSYOsteoarthr Cartil19953791:STN:280:DyaK28%2FhtVCmsA%3D%3D10.1016/S1063-4584(05)80041-X MohrWGörzEZ Kardiol2001909161:CAS:528:DC%2BD38XhsVKlsrg%3D10.1007/s003920170062 ChughtaiAMarshallRNancollasGHJ Phys Chem1968722081:CAS:528:DyaF1cXltl2ltg%3D%3D10.1021/j100847a039 HesseAHeimbachDWorld J Urol1999173081:STN:280:DC%2BD3c%2FhvF2guw%3D%3D10.1007/s003450050152 TaylorAWFrazierAWGurneyELSmithJPTrans Faraday Soc19635915851:CAS:528:DyaF3sXksFWrtLY%3D10.1039/tf9635901585 TruesdellAHJonesBFJ Res US Geol Surv197422331:CAS:528:DyaE2MXhtVaqsrs%3D FerreiraBJMLMagalhãesMCFCorreiaRNMater Sci Forum2008587–588710.4028/www.scientific.net/MSF.587-588.7 SmithRMMartellAECritical Stability Constants1976Inorganic complexesPlenum Press, New York10.1007/978-1-4757-5506-0 AH Truesdell (2129_CR25) 1974; 2 S Danilchenko (2129_CR15) 2009; 44 2129_CR23 2129_CR22 CA Scotchford (2129_CR9) 1995; 3 C Frondel (2129_CR1) 1941; 26 RZ LeGeros (2129_CR18) 1991 BJML Ferreira (2129_CR20) 2008; 587–588 W Jaynes (2129_CR13) 1999; 28 A Chughtai (2129_CR24) 1968; 72 S Verberckmoes (2129_CR7) 2007; 71 M Corlett (2129_CR12) 1966; 53 X Xiande (2129_CR17) 2003; 15 MCF Magalhães (2129_CR4) 2006 C Frondel (2129_CR2) 1949; 34 M Hamad (2129_CR19) 1986; 79 T Sakae (2129_CR6) 1989; 3 DD Perrin (2129_CR21) 1967; 14 2129_CR14 HL Jang (2129_CR3) 2014; 8 W Mohr (2129_CR8) 2001; 90 MM Godinho (2129_CR11) 1970; 69 CA Scotchford (2129_CR10) 1995; 54 RM Smith (2129_CR26) 1976 X Xiande (2129_CR16) 2002; 66 A Hesse (2129_CR28) 1999; 17 R Lagier (2129_CR5) 2003; 199 AW Taylor (2129_CR27) 1963; 59 |
References_xml | – volume: 34 start-page: 692 year: 1949 ident: 2129_CR2 publication-title: Am Min contributor: fullname: C Frondel – ident: 2129_CR22 – volume: 66 start-page: 2439 year: 2002 ident: 2129_CR16 publication-title: Geochim Cosmochim Acta doi: 10.1016/S0016-7037(02)00833-5 contributor: fullname: X Xiande – volume: 26 start-page: 145 year: 1941 ident: 2129_CR1 publication-title: Am Min contributor: fullname: C Frondel – volume: 3 start-page: 79 year: 1995 ident: 2129_CR9 publication-title: Osteoarthr Cartil doi: 10.1016/S1063-4584(05)80041-X contributor: fullname: CA Scotchford – volume: 69 start-page: 97 year: 1970 ident: 2129_CR11 publication-title: Mem Not contributor: fullname: MM Godinho – volume: 3 start-page: 855 year: 1989 ident: 2129_CR6 publication-title: Scanning Microsc contributor: fullname: T Sakae – volume: 2 start-page: 233 year: 1974 ident: 2129_CR25 publication-title: J Res US Geol Surv contributor: fullname: AH Truesdell – volume: 44 start-page: 553 year: 2009 ident: 2129_CR15 publication-title: Cryst Res Technol doi: 10.1002/crat.200900017 contributor: fullname: S Danilchenko – volume: 90 start-page: 916 year: 2001 ident: 2129_CR8 publication-title: Z Kardiol doi: 10.1007/s003920170062 contributor: fullname: W Mohr – volume: 53 start-page: 105 year: 1966 ident: 2129_CR12 publication-title: Naturwissenschaften doi: 10.1007/BF00601470 contributor: fullname: M Corlett – volume: 15 start-page: 1001 year: 2003 ident: 2129_CR17 publication-title: Eur J Miner doi: 10.1127/0935-1221/2003/0015-1001 contributor: fullname: X Xiande – volume: 14 start-page: 833 year: 1967 ident: 2129_CR21 publication-title: Talanta doi: 10.1016/0039-9140(67)80105-X contributor: fullname: DD Perrin – volume: 79 start-page: 192 year: 1986 ident: 2129_CR19 publication-title: J Cryst Growth doi: 10.1016/0022-0248(86)90435-5 contributor: fullname: M Hamad – volume: 199 start-page: 329 year: 2003 ident: 2129_CR5 publication-title: Pathol Res Pract doi: 10.1078/0344-0338-00425 contributor: fullname: R Lagier – volume: 28 start-page: 530 year: 1999 ident: 2129_CR13 publication-title: J Environ Qual doi: 10.2134/jeq1999.00472425002800020018x contributor: fullname: W Jaynes – volume-title: Calcium Phosphates in Oral Biology and Medicine year: 1991 ident: 2129_CR18 contributor: fullname: RZ LeGeros – volume: 54 start-page: 339 year: 1995 ident: 2129_CR10 publication-title: Ann Rheum Dis doi: 10.1136/ard.54.5.339 contributor: fullname: CA Scotchford – ident: 2129_CR23 – volume: 72 start-page: 208 year: 1968 ident: 2129_CR24 publication-title: J Phys Chem doi: 10.1021/j100847a039 contributor: fullname: A Chughtai – volume: 587–588 start-page: 7 year: 2008 ident: 2129_CR20 publication-title: Mater Sci Forum doi: 10.4028/www.scientific.net/MSF.587-588.7 contributor: fullname: BJML Ferreira – volume: 59 start-page: 1585 year: 1963 ident: 2129_CR27 publication-title: Trans Faraday Soc doi: 10.1039/tf9635901585 contributor: fullname: AW Taylor – ident: 2129_CR14 – start-page: 71 volume-title: Biomineralization: medical aspects of solubility year: 2006 ident: 2129_CR4 doi: 10.1002/0470092122.ch3 contributor: fullname: MCF Magalhães – volume-title: Critical Stability Constants year: 1976 ident: 2129_CR26 doi: 10.1007/978-1-4757-5506-0 contributor: fullname: RM Smith – volume: 17 start-page: 308 year: 1999 ident: 2129_CR28 publication-title: World J Urol doi: 10.1007/s003450050152 contributor: fullname: A Hesse – volume: 71 start-page: 298 year: 2007 ident: 2129_CR7 publication-title: Kidney Int doi: 10.1038/sj.ki.5002028 contributor: fullname: S Verberckmoes – volume: 8 start-page: 634 year: 2014 ident: 2129_CR3 publication-title: ACS Nano doi: 10.1021/nn405246h contributor: fullname: HL Jang |
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Snippet | Whitlockite was assigned the ideal formula Ca
9
Mg(HPO
4
)(PO
4
)
6
, but the synthesis of a solid phase with this exact composition is very difficult. One of... Whitlockite was assigned the ideal formula Ca9Mg(HPO4)(PO4)6, but the synthesis of a solid phase with this exact composition is very difficult. One of the... |
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StartPage | 253 |
SubjectTerms | Analytical Chemistry Aqueous solutions Calcium Chemistry Chemistry and Materials Science Chemistry/Food Science Energy of formation Free energy Heat of formation Inorganic Chemistry Magnesium Organic Chemistry Original Paper Phosphates Physical Chemistry Solids Solubility Theoretical and Computational Chemistry |
Title | On the solubility of whitlockite, Ca9Mg(HPO4)(PO4)6, in aqueous solution at 298.15 K |
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