Direct synthesis of cis-dihalido-bis(NHC) complex of nickel(II) and catalytic application in olefin addition polymerization: effect of halogen co-ligands and density functional theory study
Two novel amine-containing N-heterocyclic carbene ligand precursors [H(1a-b)]Br have been prepared in good yield and fully characterized. Direct syntheses of cis- and trans-dihalido-bis(NHC) nickel complexes [Ni(NHC)2X2] (X = Cl, Br) are reported. The solid structures of trans-[Ni(1a-b)2Br2] (2a-b)...
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Published in | Dalton transactions : an international journal of inorganic chemistry Vol. 42; no. 33; pp. 12020 - 12030 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
England
01.01.2013
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Subjects | |
Online Access | Get full text |
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