Self-assembly of graphitic carbon nitride nanosheets–carbon nanotube composite for electrochemical simultaneous determination of catechol and hydroquinone

Schematic diagram of hydrothermal synthesis graphitic carbon nitride nanosheets-carbon nanotube composite and theirs application for electrochemical sensing catechol and hydroquinone. [Display omitted] •Self-assembly of graphitic carbon nitride nanosheets-carbon nanotube composite.•CNNS-CNT show mor...

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Published inElectrochimica acta Vol. 176; pp. 28 - 35
Main Authors Zhang, Hanqiang, Huang, Yihong, Hu, Shirong, Huang, Qitong, Wei, Chan, Zhang, Wuxiang, Yang, Weize, Dong, Peihui, Hao, Aiyou
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 10.09.2015
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Abstract Schematic diagram of hydrothermal synthesis graphitic carbon nitride nanosheets-carbon nanotube composite and theirs application for electrochemical sensing catechol and hydroquinone. [Display omitted] •Self-assembly of graphitic carbon nitride nanosheets-carbon nanotube composite.•CNNS-CNT show more stronger conductivity than CNNS and CNT.•CNNS-CNT has been performed for detection of catechol and hydroquinone.•The probe was applied to detect practical samples with satisfactory results. In this paper, three-dimensional (3D) graphitic carbon nitride nanosheets-carbon nanotube (CNNS-CNT) composite was synthesized via hydrothermal reaction of 2D CNNS and 1D CNT-COOH by π-π stacking and electrostatic interactions. This CNNS-CNT composite was characterized by transmission electron microscope, scanning electron microscope, x-ray diffraction and fourier-transform infrared. In addition, the CNNS-CNT composite displayed excellent conductivity comparing with CNNS and CNT-COOH monomer. This composite was applied for electrochemical simultaneous determination of catechol (CC) and hydroquinone (HQ) with good sensitivity, wide linear range and low detection limit. In addition, this CNNS-CNT composite modified electrode was also applied to detect practical samples with satisfactory results.
AbstractList Schematic diagram of hydrothermal synthesis graphitic carbon nitride nanosheets-carbon nanotube composite and theirs application for electrochemical sensing catechol and hydroquinone. [Display omitted] •Self-assembly of graphitic carbon nitride nanosheets-carbon nanotube composite.•CNNS-CNT show more stronger conductivity than CNNS and CNT.•CNNS-CNT has been performed for detection of catechol and hydroquinone.•The probe was applied to detect practical samples with satisfactory results. In this paper, three-dimensional (3D) graphitic carbon nitride nanosheets-carbon nanotube (CNNS-CNT) composite was synthesized via hydrothermal reaction of 2D CNNS and 1D CNT-COOH by π-π stacking and electrostatic interactions. This CNNS-CNT composite was characterized by transmission electron microscope, scanning electron microscope, x-ray diffraction and fourier-transform infrared. In addition, the CNNS-CNT composite displayed excellent conductivity comparing with CNNS and CNT-COOH monomer. This composite was applied for electrochemical simultaneous determination of catechol (CC) and hydroquinone (HQ) with good sensitivity, wide linear range and low detection limit. In addition, this CNNS-CNT composite modified electrode was also applied to detect practical samples with satisfactory results.
Author Dong, Peihui
Zhang, Hanqiang
Zhang, Wuxiang
Huang, Qitong
Hao, Aiyou
Yang, Weize
Huang, Yihong
Hu, Shirong
Wei, Chan
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  surname: Hao
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  email: haoay@sdu.edu.cn
  organization: School of Chemistry & Chemical Engineering, Shandong University, Jinan 250100, PR China
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Keywords Graphitic carbon nitride nanosheets
Carbon nanotube
Hydroquinone
Electrochemical determination
Catechol
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Snippet Schematic diagram of hydrothermal synthesis graphitic carbon nitride nanosheets-carbon nanotube composite and theirs application for electrochemical sensing...
SourceID crossref
elsevier
SourceType Enrichment Source
Index Database
Publisher
StartPage 28
SubjectTerms Carbon nanotube
Catechol
Electrochemical determination
Graphitic carbon nitride nanosheets
Hydroquinone
Title Self-assembly of graphitic carbon nitride nanosheets–carbon nanotube composite for electrochemical simultaneous determination of catechol and hydroquinone
URI https://dx.doi.org/10.1016/j.electacta.2015.06.119
Volume 176
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