MXene-Based Materials for Multivalent Metal-Ion Batteries

Multivalent metal ion (Mg2+, Zn2+, Ca2+, and Al3+) batteries (MMIBs) emerged as promising technologies for large-scale energy storage systems in recent years due to the abundant metal reserves in the Earth’s crust and potentially low cost. However, the lack of high-performance electrode materials is...

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Published inBatteries (Basel) Vol. 9; no. 3; p. 174
Main Authors Wang, Chunlei, Pan, Zibing, Chen, Huaqi, Pu, Xiangjun, Chen, Zhongxue
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 01.03.2023
Subjects
Acids
Alternative energy sources
Aluminum
Batteries
Calcium ions
Carbon nitride
composite materials
Controllability
Design and construction
Earth crust
Electricity distribution
Electrode materials
Electrodes
Energy storage
Etching
Fluorides
Fluorine
Heterojunctions
Interlayers
Lithium
Materials
Metal carbides
Metal ions
Methods
multivalent metal-ion batteries
MXenes
Renewable resources
Storage systems
Transition metals
China
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Abstract Multivalent metal ion (Mg2+, Zn2+, Ca2+, and Al3+) batteries (MMIBs) emerged as promising technologies for large-scale energy storage systems in recent years due to the abundant metal reserves in the Earth’s crust and potentially low cost. However, the lack of high-performance electrode materials is still the main obstacle to the development of MMIBs. As a newly large family of two-dimensional transition metal carbides, nitrides, and carbonitrides, MXenes have attracted growing focus in the energy storage field because of their large specific surface area, excellent conductivity, tunable interlayer spaces, and compositional diversity. In particular, the multifunctional chemistry and superior hydrophilicity enable MXenes to serve not only as electrode materials but also as important functional components for heterojunction composite electrodes. Herein, the advances of MXene-based materials since its discovery for MMIBs are summarized, with an emphasis on the rational design and controllable synthesis of MXenes. More importantly, the fundamental understanding of the relationship between the morphology, structure, and function of MXenes is highlighted. Finally, the existing challenges and future research directions on MXene-based materials toward MMIBs application are critically discussed and prospected.
AbstractList Multivalent metal ion (Mg[sup.2+] , Zn[sup.2+] , Ca[sup.2+] , and Al[sup.3+] ) batteries (MMIBs) emerged as promising technologies for large-scale energy storage systems in recent years due to the abundant metal reserves in the Earth's crust and potentially low cost. However, the lack of high-performance electrode materials is still the main obstacle to the development of MMIBs. As a newly large family of two-dimensional transition metal carbides, nitrides, and carbonitrides, MXenes have attracted growing focus in the energy storage field because of their large specific surface area, excellent conductivity, tunable interlayer spaces, and compositional diversity. In particular, the multifunctional chemistry and superior hydrophilicity enable MXenes to serve not only as electrode materials but also as important functional components for heterojunction composite electrodes. Herein, the advances of MXene-based materials since its discovery for MMIBs are summarized, with an emphasis on the rational design and controllable synthesis of MXenes. More importantly, the fundamental understanding of the relationship between the morphology, structure, and function of MXenes is highlighted. Finally, the existing challenges and future research directions on MXene-based materials toward MMIBs application are critically discussed and prospected.
Multivalent metal ion (Mg2+, Zn2+, Ca2+, and Al3+) batteries (MMIBs) emerged as promising technologies for large-scale energy storage systems in recent years due to the abundant metal reserves in the Earth’s crust and potentially low cost. However, the lack of high-performance electrode materials is still the main obstacle to the development of MMIBs. As a newly large family of two-dimensional transition metal carbides, nitrides, and carbonitrides, MXenes have attracted growing focus in the energy storage field because of their large specific surface area, excellent conductivity, tunable interlayer spaces, and compositional diversity. In particular, the multifunctional chemistry and superior hydrophilicity enable MXenes to serve not only as electrode materials but also as important functional components for heterojunction composite electrodes. Herein, the advances of MXene-based materials since its discovery for MMIBs are summarized, with an emphasis on the rational design and controllable synthesis of MXenes. More importantly, the fundamental understanding of the relationship between the morphology, structure, and function of MXenes is highlighted. Finally, the existing challenges and future research directions on MXene-based materials toward MMIBs application are critically discussed and prospected.
Audience Academic
Author Pan, Zibing
Chen, Zhongxue
Pu, Xiangjun
Wang, Chunlei
Chen, Huaqi
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  orcidid: 0000-0002-1526-7336
  surname: Chen
  fullname: Chen, Zhongxue
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Snippet Multivalent metal ion (Mg2+, Zn2+, Ca2+, and Al3+) batteries (MMIBs) emerged as promising technologies for large-scale energy storage systems in recent years...
Multivalent metal ion (Mg[sup.2+] , Zn[sup.2+] , Ca[sup.2+] , and Al[sup.3+] ) batteries (MMIBs) emerged as promising technologies for large-scale energy...
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StartPage 174
SubjectTerms Acids
Alternative energy sources
Aluminum
Batteries
Calcium ions
Carbon nitride
composite materials
Controllability
Design and construction
Earth crust
Electricity distribution
Electrode materials
Electrodes
Energy storage
Etching
Fluorides
Fluorine
Heterojunctions
Interlayers
Lithium
Materials
Metal carbides
Metal ions
Methods
multivalent metal-ion batteries
MXenes
Renewable resources
Storage systems
Transition metals
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Title MXene-Based Materials for Multivalent Metal-Ion Batteries
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https://doaj.org/article/25da50156e5644538344f6eae2c5e7d7
Volume 9
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