Broad Tunability in mechanical properties of closed cellular foams using micro-bubble assembly of Graphene/silica Nanocomposites

• Published in: Materials & design Vol. 202; p. 109558
• Main Authors: Lee, Je Hyun, Oh, Min Jun, Yoo, Pil J.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.04.2021; Elsevier
• Subjects: Closed-cellular structure; Composites; Foams; Microfluidic; Solid bubbles; Foams; Solid bubbles; Composites; Closed-cellular structure; Microfluidic
• ISSN: 0264-1275; 1873-4197
• DOI: 10.1016/j.matdes.2021.109558

Cellular structures are central to the design of lightweight yet strong materials for engineering development. However, the material properties of cellular foams made of specific elements are placed in a narrow range in their density and corresponding mechanical properties. Here, this study presents an innovative design of creating closed-cellular structured (CCS) foams with a wide range of physical controllability. The CCS foams are prepared by assembly of solid bubbles consisting of reduced graphene oxide (rGO) and silica nanoparticles. By varying their compositional ratio, the resulting CCS foams exhibit completely discerned structural morphologies: Rhombic dodecahedral (RDH) internal cells for higher rGO content, whereas a fused face centered cubic (FCC)-like internal cells for a higher content of silica. As such, these tunable CCS foams manifest an extended relationship in density and resulting mechanical properties, spanning from a density of 2.3 mg/cm3 and corresponding Young's modulus of 0.102 MPa (for RDH) to 444.27 mg/cm3 and 180.3 MPa (for fused-FCC). Moreover, silica-containing CCS can exhibit a thermal insulation property with a greatly reduced thermal conductivity (κ) of 48 mW/m·K. therefore, this approach of creating the structurally tunable CCS foams would offer a concrete toolkit for designing high-performance cellular structures with on-demand physical/mechanical properties [Display omitted] •The elaborate control in the compositional ratio of frame-forming species (graphene oxide nanosheets and silica nanoparticles) leads to the tunable implementation of structurally-varied lightweight foams ranging from completely closed to partially opened cellular structures.•The controllability over the density of monolithic foams is remarkably extended even broader than two orders of magnitude in the Ashby plot.•On-demand versatility in applications of foams are readily achieved with compositional variation, spanning from ultra-lightweight yet strong foams (2.3 mg/cm3 with Young's modulus of 0.102 MPa) to flame-retardant insulation foams (444.27 mg/cm3 with thermal conductivity of 48 mW/m·K).