A novel approach used to study the corrosion susceptibility of metallic materials at a dynamic seawater/air interface
•A novel seawater/air interfacial measurement device is constructed.•An electrochemical sensor is used to study the localized corrosion susceptibility.•Aluminum exposed to the interfacial region show better corrosion resistance than that in the full immersion region. A novel device is constructed to...
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Published in | Corrosion communications Vol. 6; pp. 62 - 66 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
01.06.2022
Elsevier |
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Abstract | •A novel seawater/air interfacial measurement device is constructed.•An electrochemical sensor is used to study the localized corrosion susceptibility.•Aluminum exposed to the interfacial region show better corrosion resistance than that in the full immersion region.
A novel device is constructed to study the localized corrosion susceptibility of 2024 aluminum alloy at a dynamic seawater/air interface. Corrosion in three distinct regions are identified: full immersion region, seawater/air interfacial region (alternant wet/dry region), and atmosphere region. The corrosion process in the interfacial region over time was studied by EIS and the corrosion product was characterized by SEM. Experimental results revealed that, a layer of intense and uniform corrosion product was formed on the seawater/air interfacial region, due to the oxygen enrichment in that region. Pitting corrosion was more severe in the full immersion region than that in the seawater/air interface, as verified by a lower charge transfer resistance and more severe pitting corrosion and intergranular corrosion extent. |
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AbstractList | •A novel seawater/air interfacial measurement device is constructed.•An electrochemical sensor is used to study the localized corrosion susceptibility.•Aluminum exposed to the interfacial region show better corrosion resistance than that in the full immersion region.
A novel device is constructed to study the localized corrosion susceptibility of 2024 aluminum alloy at a dynamic seawater/air interface. Corrosion in three distinct regions are identified: full immersion region, seawater/air interfacial region (alternant wet/dry region), and atmosphere region. The corrosion process in the interfacial region over time was studied by EIS and the corrosion product was characterized by SEM. Experimental results revealed that, a layer of intense and uniform corrosion product was formed on the seawater/air interfacial region, due to the oxygen enrichment in that region. Pitting corrosion was more severe in the full immersion region than that in the seawater/air interface, as verified by a lower charge transfer resistance and more severe pitting corrosion and intergranular corrosion extent. A novel device is constructed to study the localized corrosion susceptibility of 2024 aluminum alloy at a dynamic seawater/air interface. Corrosion in three distinct regions are identified: full immersion region, seawater/air interfacial region (alternant wet/dry region), and atmosphere region. The corrosion process in the interfacial region over time was studied by EIS and the corrosion product was characterized by SEM. Experimental results revealed that, a layer of intense and uniform corrosion product was formed on the seawater/air interfacial region, due to the oxygen enrichment in that region. Pitting corrosion was more severe in the full immersion region than that in the seawater/air interface, as verified by a lower charge transfer resistance and more severe pitting corrosion and intergranular corrosion extent. |
Author | Xia, Da-Hai Zhu, Yu Deng, Cheng-Man Hu, Wenbin Yuan, Quan Mao, Yingchang |
Author_xml | – sequence: 1 givenname: Da-Hai surname: Xia fullname: Xia, Da-Hai email: dahaixia@tju.edu.cn organization: School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China – sequence: 2 givenname: Yingchang surname: Mao fullname: Mao, Yingchang organization: School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China – sequence: 3 givenname: Yu surname: Zhu fullname: Zhu, Yu organization: School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China – sequence: 4 givenname: Quan surname: Yuan fullname: Yuan, Quan organization: Renai College of Tianjin, Tianjin 301636, China – sequence: 5 givenname: Cheng-Man surname: Deng fullname: Deng, Cheng-Man organization: School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China – sequence: 6 givenname: Wenbin surname: Hu fullname: Hu, Wenbin email: wbhu@tju.edu.cn organization: School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China |
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CitedBy_id | crossref_primary_10_1016_j_corsci_2024_112033 crossref_primary_10_1016_j_energy_2023_129560 crossref_primary_10_3390_met13111850 crossref_primary_10_1016_j_engfailanal_2022_106759 crossref_primary_10_1080_1478422X_2022_2162662 crossref_primary_10_1108_ACMM_01_2023_2747 crossref_primary_10_1016_j_jmst_2024_05_014 crossref_primary_10_1016_j_matchemphys_2022_127122 crossref_primary_10_1016_j_corcom_2024_03_002 crossref_primary_10_1016_j_corsci_2023_110985 |
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Keywords | Localized corrosion Seawater/air interface EIS Aluminum alloy |
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Snippet | •A novel seawater/air interfacial measurement device is constructed.•An electrochemical sensor is used to study the localized corrosion... A novel device is constructed to study the localized corrosion susceptibility of 2024 aluminum alloy at a dynamic seawater/air interface. Corrosion in three... |
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Title | A novel approach used to study the corrosion susceptibility of metallic materials at a dynamic seawater/air interface |
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