Crystal phase regulation of MnO2 for alcohol oxidation with ultra-stability in acidic solution
The stability of non-noble metal catalysts for water oxidation is remaining a great challenge in acidic solution. Herein, alcohols oxidation instead of water oxidation coupled with ultradurable H2 production was realized. The MnO2 crystal phase regulation could optimize the electronic structure, and...
Saved in:
| Published in | Catalysis communications Vol. 178; p. 106675 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.05.2023
Elsevier |
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | The stability of non-noble metal catalysts for water oxidation is remaining a great challenge in acidic solution. Herein, alcohols oxidation instead of water oxidation coupled with ultradurable H2 production was realized. The MnO2 crystal phase regulation could optimize the electronic structure, and the δ-MnO2 with more Mn3+ showed a higher activity, including a low overpotential of 1.48 V at 50 mA cm−2, and a small Tafel slope of 176.22 mV dec−1. Moreover, the δ-MnO2 catalyst exhibited extremely high stability after 24 h for EG oxidation, while the activity was quickly lost within 0.5 h for water oxidation. This work indicated that crystal phase regulation could improve the active and stability of acidic water splitting catalysts.
•Acidic OER replaced by alcohol oxidation greatly enhanced the catalysts stability.•The proportion of Mn3+ in δ-MnO2 could efficiently improve the activity.•The -CH2OH oxidation inhibited the lattice oxygen mechanism.•The crystal phase regulation of MnO2 could optimize the electronic structure. |
|---|---|
| AbstractList | The stability of non-noble metal catalysts for water oxidation is remaining a great challenge in acidic solution. Herein, alcohols oxidation instead of water oxidation coupled with ultradurable H2 production was realized. The MnO2 crystal phase regulation could optimize the electronic structure, and the δ-MnO2 with more Mn3+ showed a higher activity, including a low overpotential of 1.48 V at 50 mA cm−2, and a small Tafel slope of 176.22 mV dec−1. Moreover, the δ-MnO2 catalyst exhibited extremely high stability after 24 h for EG oxidation, while the activity was quickly lost within 0.5 h for water oxidation. This work indicated that crystal phase regulation could improve the active and stability of acidic water splitting catalysts.
•Acidic OER replaced by alcohol oxidation greatly enhanced the catalysts stability.•The proportion of Mn3+ in δ-MnO2 could efficiently improve the activity.•The -CH2OH oxidation inhibited the lattice oxygen mechanism.•The crystal phase regulation of MnO2 could optimize the electronic structure. The stability of non-noble metal catalysts for water oxidation is remaining a great challenge in acidic solution. Herein, alcohols oxidation instead of water oxidation coupled with ultradurable H2 production was realized. The MnO2 crystal phase regulation could optimize the electronic structure, and the δ-MnO2 with more Mn3+ showed a higher activity, including a low overpotential of 1.48 V at 50 mA cm−2, and a small Tafel slope of 176.22 mV dec−1. Moreover, the δ-MnO2 catalyst exhibited extremely high stability after 24 h for EG oxidation, while the activity was quickly lost within 0.5 h for water oxidation. This work indicated that crystal phase regulation could improve the active and stability of acidic water splitting catalysts. |
| ArticleNumber | 106675 |
| Author | Wang, Xiaojun Yang, Longfei Guo, Zhiyan Li, Junhua Chen, Dawei Du, Fanglin Miao, Ruping Jiang, Yi |
| Author_xml | – sequence: 1 givenname: Junhua surname: Li fullname: Li, Junhua organization: College of Material Science and Engineering, Qingdao University of Science and Technology, Zhengzhou Road 53, Qingdao 266042, PR China – sequence: 2 givenname: Xiaojun surname: Wang fullname: Wang, Xiaojun organization: Qingdao Hiworld New Materials Co., Ltd, donghaixi Road 33, Qingdao, 266071, P. R. China – sequence: 3 givenname: Yi surname: Jiang fullname: Jiang, Yi organization: College of Material Science and Engineering, Qingdao University of Science and Technology, Zhengzhou Road 53, Qingdao 266042, PR China – sequence: 4 givenname: Ruping surname: Miao fullname: Miao, Ruping organization: College of Material Science and Engineering, Qingdao University of Science and Technology, Zhengzhou Road 53, Qingdao 266042, PR China – sequence: 5 givenname: Longfei surname: Yang fullname: Yang, Longfei organization: College of Material Science and Engineering, Qingdao University of Science and Technology, Zhengzhou Road 53, Qingdao 266042, PR China – sequence: 6 givenname: Zhiyan surname: Guo fullname: Guo, Zhiyan email: zhiyanguo@qust.edu.cn organization: College of Material Science and Engineering, Qingdao University of Science and Technology, Zhengzhou Road 53, Qingdao 266042, PR China – sequence: 7 givenname: Dawei surname: Chen fullname: Chen, Dawei email: daweichen@qust.edu.cn organization: College of Material Science and Engineering, Qingdao University of Science and Technology, Zhengzhou Road 53, Qingdao 266042, PR China – sequence: 8 givenname: Fanglin surname: Du fullname: Du, Fanglin organization: College of Material Science and Engineering, Qingdao University of Science and Technology, Zhengzhou Road 53, Qingdao 266042, PR China |
| BookMark | eNp9kMtOIzEQRa0RIxFg_oCFf6BDu91-bUYaRQNEArGBLVa1H8SR00a2A-Tv6UyPWLKq0q26R1X3DJ2MaXQIXZJ2SVrCr7ZLA9Wk3bJrOzpJnAv2Ay2IFLShqmUnU884bwTl4hSdlbJtJ5uiaoGeV_lQKkT8uoHicHYv-wg1pBEnj-_Hhw77lDFEkzYp4vQR7Dx9D3WD97FmaCb7EGKoBxxGDCbYYHBJcX_cu0A_PcTifv2v5-jp-u_j6ra5e7hZr_7cNaYnsjadHXo3yJ54BsI6yYGBsVx6q4iQrBOC0IFJGGwPxsvWUE4Vp6CkogygpedoPXNtgq1-zWEH-aATBP1PSPlFQ67BRKcFEFCWeyAd7a0g4BjlPeWcgyKO-YnVzyyTUynZ-S8eafUxb73Vc976mLee855sv2ebm_58Cy7rYoIbjbMhO1OnQ8L3gE8i1Y2o |
| CitedBy_id | crossref_primary_10_1021_acs_chemrev_3c00402 |
| Cites_doi | 10.1016/j.jechem.2022.08.009 10.1039/D1EE03522C 10.1002/anie.202107510 10.1016/j.chempr.2020.07.022 10.1007/s40820-021-00699-z 10.1016/j.electacta.2013.04.007 10.1007/s12274-022-4907-0 10.1002/adma.202003786 10.1021/acscatal.1c01666 10.1039/D1EE01277K 10.1039/C9TA03879E 10.1002/anie.202015773 10.1021/acs.est.8b03696 10.1016/j.jallcom.2020.156625 10.1016/j.cclet.2021.09.076 10.1021/jacs.0c01135 10.1021/acscatal.8b02203 10.1039/C7SC01239J |
| ContentType | Journal Article |
| Copyright | 2023 The Authors |
| Copyright_xml | – notice: 2023 The Authors |
| DBID | 6I. AAFTH AAYXX CITATION DOA |
| DOI | 10.1016/j.catcom.2023.106675 |
| DatabaseName | ScienceDirect Open Access Titles Elsevier:ScienceDirect:Open Access CrossRef Directory of Open Access Journals |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| Database_xml | – sequence: 1 dbid: DOA name: Directory of Open Access Journals url: https://www.doaj.org/ sourceTypes: Open Website |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1873-3905 |
| ExternalDocumentID | oai_doaj_org_article_7a1a9d6fa1234d71ae53643666a91e5f 10_1016_j_catcom_2023_106675 S1566736723000778 |
| GroupedDBID | --K --M .~1 0R~ 1B1 1~. 1~5 29B 4.4 457 4G. 5GY 5VS 6I. 7-5 71M 8P~ AABNK AACTN AAEDT AAEDW AAFTH AAFWJ AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AAXUO ABFNM ABMAC ABNUV ABXDB ABYKQ ACDAQ ACGFS ACRLP ADBBV ADEWK ADEZE ADMUD AEBSH AEKER AENEX AFKWA AFPKN AFTJW AGHFR AGUBO AGYEJ AHPOS AIEXJ AIKHN AITUG AJBFU AJOXV AKURH ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG AVWKF AXJTR AZFZN BKOJK BLXMC CS3 DU5 EBS EFJIC EFLBG EJD ENUVR EO8 EO9 EP2 EP3 F5P FDB FEDTE FGOYB FIRID FNPLU FYGXN G-Q GBLVA GROUPED_DOAJ HVGLF HZ~ IHE J1W KOM M41 MO0 N9A O-L O9- OAUVE OK1 OZT P-8 P-9 P2P PC. Q38 R2- RIG ROL RPZ SDF SDG SES SEW SPC SPCBC SSG SSZ T5K UHS ~G- 0SF AAXKI AAYXX ADVLN AFJKZ AKRWK CITATION |
| ID | FETCH-LOGICAL-c418t-2db4eb841f5a7de86a5acd68fd9178527713b58abd4acf80c363963a98935aa03 |
| IEDL.DBID | DOA |
| ISSN | 1566-7367 |
| IngestDate | Tue Oct 22 15:12:59 EDT 2024 Thu Sep 26 16:58:56 EDT 2024 Fri Feb 23 02:37:02 EST 2024 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Keywords | MnO2 Nanoparticles Surfaces Oxidation Hydrogen production |
| Language | English |
| License | This is an open access article under the CC BY-NC-ND license. |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c418t-2db4eb841f5a7de86a5acd68fd9178527713b58abd4acf80c363963a98935aa03 |
| OpenAccessLink | https://doaj.org/article/7a1a9d6fa1234d71ae53643666a91e5f |
| ParticipantIDs | doaj_primary_oai_doaj_org_article_7a1a9d6fa1234d71ae53643666a91e5f crossref_primary_10_1016_j_catcom_2023_106675 elsevier_sciencedirect_doi_10_1016_j_catcom_2023_106675 |
| PublicationCentury | 2000 |
| PublicationDate | May 2023 2023-05-00 2023-05-01 |
| PublicationDateYYYYMMDD | 2023-05-01 |
| PublicationDate_xml | – month: 05 year: 2023 text: May 2023 |
| PublicationDecade | 2020 |
| PublicationTitle | Catalysis communications |
| PublicationYear | 2023 |
| Publisher | Elsevier B.V Elsevier |
| Publisher_xml | – name: Elsevier B.V – name: Elsevier |
| References | Ding, Li, Jin, Huang, Wu, Feng (bb0010) 2022; 33 Gao, Tao, Liu (bb0070) 2021; 33 Xia, Xu, Wang, Yang, Huang, Hu, He, Shu, Leung, Pang (bb0085) 2018; 52 Yao, Wan, Chen, Ji, Wang, Zheng, Duan, Wang, Ma, Tao, Wang, Zhang, Wang (bb0090) 2021; 13 Zhou, Wang, Tian, Feng (bb0060) 2022; 15 Zhang, Chai (bb0020) 2021; 14 Chen, Xu, Zhu, Huang, Zhou, Wang, Zhou, Du, Li, Xie, Tao, Dong, Liu, Wang, Chen, Su, Chen, Zou, Li, Liu, Wang (bb0045) 2021; 60 Yan, Lian, Gu, Yang, Sun, Mu, Li, Zhu, Zheng, Chen, Zhu, Deng, Peng (bb0080) 2018; 8 Chen, Xie, Wang, Zou, Dong, Huang, Xiao, Wei, Du, Chen, Zhou, Ma, Wang (bb0095) 2020; 6 Dupont, Hollenkamp, Donne (bb0105) 2013; 104 Deng, Toe, Li, Tan, Yang, Hu, He (bb0035) 2022; 12 Huynh, Ozel, Liu, Lau, Nocera (bb0005) 2017; 8 Zhang, Song, Kang, Zhu, Liu, Zhang, Brett, Shearing, Mai, Parkin, He (bb0050) 2022; 2 Li, Wei, Han, Chen, Shi (bb0065) 2021; 60 Jin, Ruqia, Park, Kim, Oh, Choi, Lee (bb0015) 2021; 11 Bae, Shin, Jeong, Choe, Choi, Han, Lee (bb0040) 2021; 11 Choi, Lim, Oh, Lim, Baeck (bb0075) 2019; 7 Zhou, Wang, Tian, Chang, Feng (bb0025) 2022; 75 Kuznetsov, Naeem, Kumar, Abdala, Fedorov, Müller (bb0030) 2020; 142 Lin, Kang, Zhao, Feng, Celorrio, Zhang, Cibin, Kucernak, Brett, Cora, Parkin, He (bb0055) 2022; 15 Dmitriev, Khristyuk, Popkov (bb0100) 2020; 849 Zhou (10.1016/j.catcom.2023.106675_bb0025) 2022; 75 Chen (10.1016/j.catcom.2023.106675_bb0095) 2020; 6 Deng (10.1016/j.catcom.2023.106675_bb0035) 2022; 12 Ding (10.1016/j.catcom.2023.106675_bb0010) 2022; 33 Zhang (10.1016/j.catcom.2023.106675_bb0050) 2022; 2 Kuznetsov (10.1016/j.catcom.2023.106675_bb0030) 2020; 142 Li (10.1016/j.catcom.2023.106675_bb0065) 2021; 60 Chen (10.1016/j.catcom.2023.106675_bb0045) 2021; 60 Dmitriev (10.1016/j.catcom.2023.106675_bb0100) 2020; 849 Zhou (10.1016/j.catcom.2023.106675_bb0060) 2022; 15 Zhang (10.1016/j.catcom.2023.106675_bb0020) 2021; 14 Gao (10.1016/j.catcom.2023.106675_bb0070) 2021; 33 Yao (10.1016/j.catcom.2023.106675_bb0090) 2021; 13 Dupont (10.1016/j.catcom.2023.106675_bb0105) 2013; 104 Lin (10.1016/j.catcom.2023.106675_bb0055) 2022; 15 Xia (10.1016/j.catcom.2023.106675_bb0085) 2018; 52 Yan (10.1016/j.catcom.2023.106675_bb0080) 2018; 8 Bae (10.1016/j.catcom.2023.106675_bb0040) 2021; 11 Jin (10.1016/j.catcom.2023.106675_bb0015) 2021; 11 Choi (10.1016/j.catcom.2023.106675_bb0075) 2019; 7 Huynh (10.1016/j.catcom.2023.106675_bb0005) 2017; 8 |
| References_xml | – volume: 60 start-page: 7297 year: 2021 end-page: 7307 ident: bb0045 article-title: Unveiling the Electrooxidation of urea: intramolecular coupling of the N-N bond publication-title: Angew. Chem. Int. Ed. contributor: fullname: Wang – volume: 33 start-page: 18 year: 2021 ident: bb0070 article-title: Progress of nonprecious-metal-based Electrocatalysts for oxygen evolution in acidic media publication-title: Adv. Mater. contributor: fullname: Liu – volume: 12 start-page: 2201047 year: 2022 ident: bb0035 article-title: Earth-Abundant Metal-Based Electrocatalysts Promoted Anodic Reaction in Hybrid Water Electrolysis for Efficient Hydrogen Production: Recent Progress and Perspectives contributor: fullname: He – volume: 7 start-page: 11659 year: 2019 end-page: 11664 ident: bb0075 article-title: Effect of proton irradiation on electrocatalytic properties of MnO2 for oxygen reduction reaction publication-title: J. Mater. Chem. A contributor: fullname: Baeck – volume: 11 start-page: 2003188 year: 2021 ident: bb0015 article-title: Nanocatalyst Design for Long-Term Operation of Proton/Anion Exchange Membrane Water Electrolysis contributor: fullname: Lee – volume: 15 start-page: 8936 year: 2022 end-page: 8945 ident: bb0060 article-title: Efficient bifunctional catalysts of CoSe/N-doped carbon nanospheres supported Pt nanoparticles for methanol electrolysis of hydrogen generation publication-title: Nano Res. contributor: fullname: Feng – volume: 60 start-page: 21464 year: 2021 end-page: 21472 ident: bb0065 article-title: MnO publication-title: Angew. Chem. Int. Ed. contributor: fullname: Shi – volume: 33 start-page: 2687 year: 2022 end-page: 2691 ident: bb0010 article-title: Graphene aerogel supported Pt-Ni alloy as efficient electrocatalysts for alcohol fuel oxidation publication-title: Chin. Chem. Lett. contributor: fullname: Feng – volume: 6 start-page: 2974 year: 2020 end-page: 2993 ident: bb0095 article-title: Activity origins and design principles of nickel-based catalysts for nucleophile Electrooxidation publication-title: Chem contributor: fullname: Wang – volume: 849 year: 2020 ident: bb0100 article-title: Electrodeposition of α-Ni/β-Co composite coatings on the carbon felt: structural features and electrochemical performance publication-title: J. Alloys Compd. contributor: fullname: Popkov – volume: 8 start-page: 4779 year: 2017 end-page: 4794 ident: bb0005 article-title: Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid publication-title: Chem. Sci. contributor: fullname: Nocera – volume: 52 start-page: 13399 year: 2018 end-page: 13409 ident: bb0085 article-title: Enhanced performance and conversion pathway for catalytic ozonation of methyl Mercaptan on single-atom ag deposited three-dimensional ordered mesoporous MnO2 publication-title: Environ. Sci. Technol. contributor: fullname: Pang – volume: 104 start-page: 140 year: 2013 end-page: 147 ident: bb0105 article-title: Electrochemically active surface area effects on the performance of manganese dioxide for electrochemical capacitor applications publication-title: Electrochim. Acta contributor: fullname: Donne – volume: 14 start-page: 4647 year: 2021 end-page: 4671 ident: bb0020 article-title: Lattice oxygen redox chemistry in solid-state electrocatalysts for water oxidation publication-title: Energy Environ. Sci. contributor: fullname: Chai – volume: 13 start-page: 14 year: 2021 ident: bb0090 article-title: Oxygen-defect enhanced anion adsorption energy toward super-rate and durable cathode for Ni-Zn batteries publication-title: Nano-Micro. Lett. contributor: fullname: Wang – volume: 15 start-page: 2386 year: 2022 end-page: 2396 ident: bb0055 article-title: Identification and manipulation of dynamic active site deficiency-induced competing reactions in electrocatalytic oxidation processes publication-title: Energy Environ. Sci. contributor: fullname: He – volume: 11 start-page: 11066 year: 2021 end-page: 11074 ident: bb0040 article-title: Facet-dependent Mn doping on shaped Co3O4 crystals for catalytic oxidation publication-title: ACS Catal. contributor: fullname: Lee – volume: 8 start-page: 10137 year: 2018 end-page: 10147 ident: bb0080 article-title: Phase and morphology transformation of MnO2 induced by ionic liquids toward efficient water oxidation publication-title: ACS Catal. contributor: fullname: Peng – volume: 2 start-page: 3254 year: 2022 end-page: 3270 ident: bb0050 article-title: Stabilizing efficient structures of superwetting electrocatalysts for enhanced urea oxidation reactions, Chem publication-title: Catalysis contributor: fullname: He – volume: 75 start-page: 46 year: 2022 end-page: 54 ident: bb0025 article-title: Electron-enriched Pt induced by CoSe2 promoted bifunctional catalytic ability for low carbon alcohol fuel electro-reforming of hydrogen evolution publication-title: J. Energy Chem. contributor: fullname: Feng – volume: 142 start-page: 7883 year: 2020 end-page: 7888 ident: bb0030 article-title: Tailoring lattice oxygen binding in ruthenium Pyrochlores to enhance oxygen evolution activity publication-title: J. Am. Chem. Soc. contributor: fullname: Müller – volume: 75 start-page: 46 year: 2022 ident: 10.1016/j.catcom.2023.106675_bb0025 article-title: Electron-enriched Pt induced by CoSe2 promoted bifunctional catalytic ability for low carbon alcohol fuel electro-reforming of hydrogen evolution publication-title: J. Energy Chem. doi: 10.1016/j.jechem.2022.08.009 contributor: fullname: Zhou – volume: 12 start-page: 2201047 year: 2022 ident: 10.1016/j.catcom.2023.106675_bb0035 contributor: fullname: Deng – volume: 15 start-page: 2386 year: 2022 ident: 10.1016/j.catcom.2023.106675_bb0055 article-title: Identification and manipulation of dynamic active site deficiency-induced competing reactions in electrocatalytic oxidation processes publication-title: Energy Environ. Sci. doi: 10.1039/D1EE03522C contributor: fullname: Lin – volume: 60 start-page: 21464 year: 2021 ident: 10.1016/j.catcom.2023.106675_bb0065 article-title: MnO2 Electrocatalysts coordinating alcohol oxidation for ultra-durable hydrogen and chemical productions in acidic solutions publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202107510 contributor: fullname: Li – volume: 6 start-page: 2974 year: 2020 ident: 10.1016/j.catcom.2023.106675_bb0095 article-title: Activity origins and design principles of nickel-based catalysts for nucleophile Electrooxidation publication-title: Chem doi: 10.1016/j.chempr.2020.07.022 contributor: fullname: Chen – volume: 2 start-page: 3254 year: 2022 ident: 10.1016/j.catcom.2023.106675_bb0050 article-title: Stabilizing efficient structures of superwetting electrocatalysts for enhanced urea oxidation reactions, Chem publication-title: Catalysis contributor: fullname: Zhang – volume: 13 start-page: 14 year: 2021 ident: 10.1016/j.catcom.2023.106675_bb0090 article-title: Oxygen-defect enhanced anion adsorption energy toward super-rate and durable cathode for Ni-Zn batteries publication-title: Nano-Micro. Lett. doi: 10.1007/s40820-021-00699-z contributor: fullname: Yao – volume: 104 start-page: 140 year: 2013 ident: 10.1016/j.catcom.2023.106675_bb0105 article-title: Electrochemically active surface area effects on the performance of manganese dioxide for electrochemical capacitor applications publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2013.04.007 contributor: fullname: Dupont – volume: 15 start-page: 8936 year: 2022 ident: 10.1016/j.catcom.2023.106675_bb0060 article-title: Efficient bifunctional catalysts of CoSe/N-doped carbon nanospheres supported Pt nanoparticles for methanol electrolysis of hydrogen generation publication-title: Nano Res. doi: 10.1007/s12274-022-4907-0 contributor: fullname: Zhou – volume: 33 start-page: 18 year: 2021 ident: 10.1016/j.catcom.2023.106675_bb0070 article-title: Progress of nonprecious-metal-based Electrocatalysts for oxygen evolution in acidic media publication-title: Adv. Mater. doi: 10.1002/adma.202003786 contributor: fullname: Gao – volume: 11 start-page: 11066 year: 2021 ident: 10.1016/j.catcom.2023.106675_bb0040 article-title: Facet-dependent Mn doping on shaped Co3O4 crystals for catalytic oxidation publication-title: ACS Catal. doi: 10.1021/acscatal.1c01666 contributor: fullname: Bae – volume: 11 start-page: 2003188 year: 2021 ident: 10.1016/j.catcom.2023.106675_bb0015 contributor: fullname: Jin – volume: 14 start-page: 4647 year: 2021 ident: 10.1016/j.catcom.2023.106675_bb0020 article-title: Lattice oxygen redox chemistry in solid-state electrocatalysts for water oxidation publication-title: Energy Environ. Sci. doi: 10.1039/D1EE01277K contributor: fullname: Zhang – volume: 7 start-page: 11659 year: 2019 ident: 10.1016/j.catcom.2023.106675_bb0075 article-title: Effect of proton irradiation on electrocatalytic properties of MnO2 for oxygen reduction reaction publication-title: J. Mater. Chem. A doi: 10.1039/C9TA03879E contributor: fullname: Choi – volume: 60 start-page: 7297 year: 2021 ident: 10.1016/j.catcom.2023.106675_bb0045 article-title: Unveiling the Electrooxidation of urea: intramolecular coupling of the N-N bond publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202015773 contributor: fullname: Chen – volume: 52 start-page: 13399 year: 2018 ident: 10.1016/j.catcom.2023.106675_bb0085 article-title: Enhanced performance and conversion pathway for catalytic ozonation of methyl Mercaptan on single-atom ag deposited three-dimensional ordered mesoporous MnO2 publication-title: Environ. Sci. Technol. doi: 10.1021/acs.est.8b03696 contributor: fullname: Xia – volume: 849 year: 2020 ident: 10.1016/j.catcom.2023.106675_bb0100 article-title: Electrodeposition of α-Ni/β-Co composite coatings on the carbon felt: structural features and electrochemical performance publication-title: J. Alloys Compd. doi: 10.1016/j.jallcom.2020.156625 contributor: fullname: Dmitriev – volume: 33 start-page: 2687 year: 2022 ident: 10.1016/j.catcom.2023.106675_bb0010 article-title: Graphene aerogel supported Pt-Ni alloy as efficient electrocatalysts for alcohol fuel oxidation publication-title: Chin. Chem. Lett. doi: 10.1016/j.cclet.2021.09.076 contributor: fullname: Ding – volume: 142 start-page: 7883 year: 2020 ident: 10.1016/j.catcom.2023.106675_bb0030 article-title: Tailoring lattice oxygen binding in ruthenium Pyrochlores to enhance oxygen evolution activity publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.0c01135 contributor: fullname: Kuznetsov – volume: 8 start-page: 10137 year: 2018 ident: 10.1016/j.catcom.2023.106675_bb0080 article-title: Phase and morphology transformation of MnO2 induced by ionic liquids toward efficient water oxidation publication-title: ACS Catal. doi: 10.1021/acscatal.8b02203 contributor: fullname: Yan – volume: 8 start-page: 4779 year: 2017 ident: 10.1016/j.catcom.2023.106675_bb0005 article-title: Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid publication-title: Chem. Sci. doi: 10.1039/C7SC01239J contributor: fullname: Huynh |
| SSID | ssj0016939 |
| Score | 2.44067 |
| Snippet | The stability of non-noble metal catalysts for water oxidation is remaining a great challenge in acidic solution. Herein, alcohols oxidation instead of water... |
| SourceID | doaj crossref elsevier |
| SourceType | Open Website Aggregation Database Publisher |
| StartPage | 106675 |
| SubjectTerms | Hydrogen production MnO2 Nanoparticles Oxidation Surfaces |
| SummonAdditionalLinks | – databaseName: ScienceDirect Freedom Collection Journals dbid: AIKHN link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9QwEB6V7QEuiKdYXvKBq7VJHD9yLCuqBUQ5QKWeiMYvCKqSVbSV6L9nHCdVe-HAMZbtRJ-tme-LxzMA76IQ2pPo4o3SNa-jIzvoioJHjbJpbLA2TNEWZ2p3Xn-6kBdHsF3uwqSwytn2Z5s-Weu5ZTOjudl33eZbUh5aKE0kOiWlMffgmNxRZVZwfPLx8-7s5jBBNVNBsdSfpwHLDbopzMuRxRvSlfRKUBPNKO94qCmR_y1Hdcv5nD6ChzNrZCf5wx7DUeifwP3tUqztKfzYjtfE8y7Z_he5JTbmCvOEORsi-9J_rRiRU4a5Hi4b_nS5lBJLv2HZ1eVhRE7Dp0DZa9b1DF3nO8eWjfkMzk8_fN_u-Fw6gbu6NAdeeVsHa-oyStQ-GIUSnVcmepJnRlaatKmVBq2v0UVTOEFMRQlsiL5IxEI8h1U_9OEFMOUjhjL4wngSY0YRo2pKSzKOelkU1Rr4Ale7zxky2iV07Heb4W0TvG2Gdw3vE6Y3fVN-66lhGH-28wK3GktsvIpIjrX2usQgBXEn0lrYlEHGNehlRdo724Wm6v75-pf_PfIVPEhPOdrxNawO41V4Q4zkYN_OO-4vN4TfEg priority: 102 providerName: Elsevier |
| Title | Crystal phase regulation of MnO2 for alcohol oxidation with ultra-stability in acidic solution |
| URI | https://dx.doi.org/10.1016/j.catcom.2023.106675 https://doaj.org/article/7a1a9d6fa1234d71ae53643666a91e5f |
| Volume | 178 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1NT9wwELUoHNoLAtqqC-3KB65pkzh27OM2Ai39AFQViVOj8ZcahJLValdiL_x2xnFS7YleOEWyEjt6Y828SZ5nCDn1jJUWk65EibJICm_QD5o0TXwJXCnttHa92uJSzG-Kb7f8dqvVV9CExfLAEbgvJWSgrPCALrawZQaOM4yiyLpBZY773vumakymhv8HQjE1HpTr1VwGHVsXTp7nDIeECLrCrUDU1-vfikdbMeb8gOwP5JDO4ksdkh3XHpHX1diT7S35Uy03SOfu6eIvRh-6jI3kEVraefqzvcopclAKse0t7R6a2DGJhq-tdH2_WkKCj_d62A1tWgqmsY2h4_57R27Oz35X82TokJCYIpOrJLe6cFoWmedQWicFcDBWSG8xC5M8LzEF1VyCtgUYL1PDkJAIBgpZCgdI2Xuy23at-0CosB5c5mwqLeZcUiBxUpnGbA3v0sDyCUlGuOpFLIRRjwqxuzrCWwd46wjvhHwNmP67N5Sx7gfQuPVg3Pp_xp2QcrRIPTCCGOlxqubZ5Y9fYvkT8iZMGfWNH8nuarl2n5CDrPSUvPr8mE3J3qz69eM6XC--zy-n_SZ8AvM-3qY |
| link.rule.ids | 315,783,787,867,2109,4509,24128,27936,27937,45597,45691 |
| linkProvider | Directory of Open Access Journals |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9QwELZKeygXxFMsTx-4WpuXX8eyotrSdjnQSj1hjV8QVCWraCvRf884Tqr2woGrYzvRZ2fm-5LxDCGfYl1Lj6KLaSEb1kSHdtAVBYsSuNY2WBvGaIuNWF82X6_41R5ZzWdhUljlZPuzTR-t9dSynNBcbtt2-T0pD1kLiSQ6JaVRj8gBsgGNb-fB0cnpenP3M0HosaBY6s_SgPkE3Rjm5dDi9elIelVjE87IH3ioMZH_PUd1z_kcPyVPJtZIj_KDPSN7oXtODldzsbYX5MdquEWed023v9At0SFXmEfMaR_pefetokhOKeR6uLT_0-ZSSjR9hqU317sBGA4fA2VvadtRcK1vHZ035ktyefzlYrVmU-kE5ppS7VjlbROsasrIQfqgBHBwXqjoUZ4pXknUppYrsL4BF1XhamQqogaN9IUDFPUrst_1XXhNqPARQhl8oTyKMSWQUenSoozDXhbqakHYDJfZ5gwZZg4d-20yvCbBazK8C_I5YXrXN-W3Hhv64aeZFthIKEF7EQEda-NlCYHXyJ1Qa4EuA48LIucVMQ-2C07V_vP2b_575EdyuL44PzNnJ5vTt-RxupIjH9-R_d1wE94jO9nZD9Pu-wvhROIE |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Crystal+phase+regulation+of+MnO2+for+alcohol+oxidation+with+ultra-stability+in+acidic+solution&rft.jtitle=Catalysis+communications&rft.au=Junhua+Li&rft.au=Yi+Jiang&rft.au=Ruping+Miao&rft.au=Longfei+Yang&rft.date=2023-05-01&rft.pub=Elsevier&rft.eissn=1873-3905&rft.volume=178&rft.spage=106675&rft_id=info:doi/10.1016%2Fj.catcom.2023.106675&rft.externalDBID=DOA&rft.externalDocID=oai_doaj_org_article_7a1a9d6fa1234d71ae53643666a91e5f |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1566-7367&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1566-7367&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1566-7367&client=summon |