Novel Reaction Kinetic Model for Anionic Polyamide-6
Semi‐adiabatic temperature measurements are recorded and used to define semi‐empirical equations for the simulation and prediction of the anionic polyamide‐6 (APA‐6) reaction kinetics. The resin mixture used has a long infusion window before the reaction starts. The prediction of the induction time...
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| Published in | Macromolecular materials and engineering Vol. 298; no. 2; pp. 163 - 173 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
01.02.2013
WILEY‐VCH Verlag Wiley John Wiley & Sons, Inc |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1438-7492 1439-2054 |
| DOI | 10.1002/mame.201100457 |
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| Abstract | Semi‐adiabatic temperature measurements are recorded and used to define semi‐empirical equations for the simulation and prediction of the anionic polyamide‐6 (APA‐6) reaction kinetics. The resin mixture used has a long infusion window before the reaction starts. The prediction of the induction time and its corresponding initial temperature of reaction is explored. By means of this semi‐empirical approach and an optimised fitting procedure, the reaction kinetics of APA‐6 can successfully be described. The adiabatic polymerisation can be predicted on the basis of an autocatalytic Kamal‐Sourour model for thermoset resins, and the crystallisation can be described using the isothermal crystallisation model.
The reaction kinetics of APA‐6 is successfully described by introducing a new kinetic equation providing a more predictable way of describing the kinetics of this autocatalytic system. The resin mixture used has a long infusion window before reaction starts. Equations are defined for the prediction of the infusion window, i.e., induction time and the corresponding initial temperature of reaction. |
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| AbstractList | Semi-adiabatic temperature measurements are recorded and used to define semi-empirical equations for the simulation and prediction of the anionic polyamide-6 (APA-6) reaction kinetics. The resin mixture used has a long infusion window before the reaction starts. The prediction of the induction time and its corresponding initial temperature of reaction is explored. By means of this semi-empirical approach and an optimised fitting procedure, the reaction kinetics of APA-6 can successfully be described. The adiabatic polymerisation can be predicted on the basis of an autocatalytic Kamal-Sourour model for thermoset resins, and the crystallisation can be described using the isothermal crystallisation model. The reaction kinetics of APA-6 is successfully described by introducing a new kinetic equation providing a more predictable way of describing the kinetics of this autocatalytic system. The resin mixture used has a long infusion window before reaction starts. Equations are defined for the prediction of the infusion window, i.e., induction time and the corresponding initial temperature of reaction. Semi-adiabatic temperature measurements are recorded and used to define semi-empirical equations for the simulation and prediction of the anionic polyamide-6 (APA-6) reaction kinetics. The resin mixture used has a long infusion window before the reaction starts. The prediction of the induction time and its corresponding initial temperature of reaction is explored. By means of this semi-empirical approach and an optimised fitting procedure, the reaction kinetics of APA-6 can successfully be described. The adiabatic polymerisation can be predicted on the basis of an autocatalytic Kamal-Sourour model for thermoset resins, and the crystallisation can be described using the isothermal crystallisation model. [PUBLICATION ABSTRACT] Semi‐adiabatic temperature measurements are recorded and used to define semi‐empirical equations for the simulation and prediction of the anionic polyamide‐6 (APA‐6) reaction kinetics. The resin mixture used has a long infusion window before the reaction starts. The prediction of the induction time and its corresponding initial temperature of reaction is explored. By means of this semi‐empirical approach and an optimised fitting procedure, the reaction kinetics of APA‐6 can successfully be described. The adiabatic polymerisation can be predicted on the basis of an autocatalytic Kamal‐Sourour model for thermoset resins, and the crystallisation can be described using the isothermal crystallisation model. magnified image Semi‐adiabatic temperature measurements are recorded and used to define semi‐empirical equations for the simulation and prediction of the anionic polyamide‐6 (APA‐6) reaction kinetics. The resin mixture used has a long infusion window before the reaction starts. The prediction of the induction time and its corresponding initial temperature of reaction is explored. By means of this semi‐empirical approach and an optimised fitting procedure, the reaction kinetics of APA‐6 can successfully be described. The adiabatic polymerisation can be predicted on the basis of an autocatalytic Kamal‐Sourour model for thermoset resins, and the crystallisation can be described using the isothermal crystallisation model. The reaction kinetics of APA‐6 is successfully described by introducing a new kinetic equation providing a more predictable way of describing the kinetics of this autocatalytic system. The resin mixture used has a long infusion window before reaction starts. Equations are defined for the prediction of the infusion window, i.e., induction time and the corresponding initial temperature of reaction. |
| Author | Bersee, Harald E. N. van Geenen, Ab A. Teuwen, Julie J. E. |
| Author_xml | – sequence: 1 givenname: Julie J. E. surname: Teuwen fullname: Teuwen, Julie J. E. email: jjeteuwen@gmail.com organization: Delft University of Technology, Faculty of Aerospace Engineering, Design and Production of Composite Structures, Kluyverweg 1, 2629HS Delft, The Netherlands – sequence: 2 givenname: Ab A. surname: van Geenen fullname: van Geenen, Ab A. organization: Delft University of Technology, Faculty of Aerospace Engineering, Design and Production of Composite Structures, Kluyverweg 1, 2629HS Delft, The Netherlands – sequence: 3 givenname: Harald E. N. surname: Bersee fullname: Bersee, Harald E. N. organization: Delft University of Technology, Faculty of Aerospace Engineering, Design and Production of Composite Structures, Kluyverweg 1, 2629HS Delft, The Netherlands |
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| Cites_doi | 10.1135/cccc19640610 10.1002/pol.1977.230120102 10.1002/macp.1979.021800621 10.5254/1.3538154 10.1002/pen.10447 10.1002/pen.760201305 10.1016/S0014-3057(99)00197-4 10.1016/0040-6031(76)80056-1 10.1021/ma60012a001 10.1002/(SICI)1097-4628(19971107)66:6<1195::AID-APP19>3.0.CO;2-0 10.1016/0032-3861(82)90124-0 10.1002/macp.1981.021820324 10.1016/j.compositesa.2008.03.018 10.1002/pen.11199 10.1002/macp.1965.020890103 10.1002/pc.10270 10.1002/pen.760251808 10.1016/0032-3950(81)90118-0 10.1016/j.polymertesting.2005.11.008 10.1016/0032-3950(79)90296-X 10.1016/0032-3861(79)90222-2 10.1002/pen.20274 10.1002/pen.760280104 10.1002/app.1984.070290437 10.1002/pen.760130110 10.1002/app.1995.070571111 10.1002/pol.1980.180180704 10.1016/0032-3861(82)90340-8 10.1002/app.21495 10.1002/pen.760241805 10.1002/(SICI)1097-4628(19980425)68:4<543::AID-APP5>3.0.CO;2-M |
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| Copyright | Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 2014 INIST-CNRS Copyright 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Keywords | Ring opening polymerization Amide 6 polymer Kinetic model Bulk polymerization polyamides Anionic polymerization Semiempirical method kinetics (polym.) Experimental study Activation energy Modeling Chemical reaction kinetics |
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| References | G. C. Alfonso, G. Bonta, S. Russo, A. Traverso, Makromol. Chem. Phys. 1981, 182, 929. M. E. Ryan, A. Dutta, Polymer 1979, 20, 203. M. R. Kamal, S. Sourour, M. Ryan, Polym. Sci. Eng. 1973, 13, 59. S. Sourour, M. R. Kamal, Thermochim. Acta 1976, 14, 41. J. Mijovic, J. Kim, J. Slaby, J. Appl. Polym. Sci. 1984, 29, 1449. A. Maazouz, J. Dupuy, G. Seytre, Polym. Eng. Sci. 2000, 40, 690. R. E. Camargo, V. M. Gonzalez, C. W. Macosko, M. Tirrell, Rubber Chem. Technol. 1983, 56, 774. K. Rijswijk, J. J. E. Teuwen, H. E. N. Bersee, A. Beukers, Compos. Part A: Appl. Sci. Manuf. 2009, 40, 1. A. Yousefi, P. G. Lafleur, R. Gauvin, Polym. Compos. 1997, 18, 157. M. Naffakh, M. Dumon, J. Dupuy, J.-F. Gerard, J. Appl. Polym. Sci. 2005, 96, 660. K. J. Kim, Y. Y. Kim, B. S. Yoon, K. J. Yoon, J. Appl. Polym. Sci. 1995, 57, 1347. J. Karger-Kocsis, L. Kiss, Makromol. Chem. Phys. 1979, 180, 1593. P. W. Sibal, R. E. Camargo, C. W. Macosko, Polym. Process Eng. 1983, 1, 147. T. M. Frunze, R. B. Shleifman, E. M. Belavtseva, Ya. V. Genin, T. V. Volkova, V. A. Kotel'nikov, L. G. Radchenko, S. P. Davtyan, V. V. Kraschev, D. Ya. Tsvankin, J. Polym. Sci., Polym. Phys. Ed. 1980, 18, 1523. H. K. Reimschuessel, J. Polym. Sci. Macromol. Rev. 1977, 12, 65. V. P. Wittmer, H. Gerrens, Die Makromol. Chem. 1965, 89, 27. D. J. Lin, J. M. Ottino, E. L. Thomas, Polym. Eng. Sci. 1985, 25, 1155. A. Ya Malkin, S. L. Ivanova, V. G. Frolov, A. N. Ivanova, Z. S. Andrianova, Polymer 1982, 23, 1791. M. R. Kamal, M. E. Ryan, Polym. Eng. Sci. 1980, 20, 859. S. A. Bolgov, V. P. Begishev, A. Ya Malkin, V. G. Frolov, Polym. Sci. USSR 1981, 23, 1485. C. Hedreul, J. Galy, J. Dupuy, M. Delmotte, C. More, J. Appl. Polym. Sci. 1998, 68, 543. P. J. Halley, M. E. Mackay, Polym. Eng. Sci. 1996, 36, 593. A. Ya Malkin, V. P. Beghishev, S. A. Bolgov, Polymer 1982, 23, 385. R. Z. Greenley, J. C. Stauffer, J. E. Kurz, Macromolecules 1969, 2, 561. A. Ya Malkin, V. P. Beghishev, I. A. Keapin, S. A. Bolgov, Polym. Eng. Sci. 1984, 24, 1396. K. J. Kim, D. S. Hong, A. R. Tripathy, J. Appl. Polym. Sci. 1997, 66, 1195. D. Lahlali, M. Naffakh, M. Dumon, Polym. Eng. Sci. 2005, 45, 1581. K. H. Lee, S. C. Kim, Polym. Eng. Sci. 1988, 28, 13. L. Bonnaud, J. P. Pascault, H. Sautereau, Eur. Polym. J. 2000, 36, 1313. K. Rijswijk, H. E. N. Bersee, A. Beukers, S. J. Picken, A. A. Geenen, Polym. Test. 2006, 25, 392. A. Ya Malkin, V. G. Frolov, A. N. Ivanova, Z. S. Andrianova, Polym. Sci. USSR 1979, 21, 691. K. C. Frisch, S. L. Reegen, Eds., Kinetics and Mechanisms of Polymerisation - Ring Opening Polymerization, Marcel Dekker, New York, London 1969. O. Wichterle, J. Tomka, J. Sebenda, Collect. Czech. Chem. Commun. 1964, 29, 610. 1981; 182 2009; 40 1997; 66 1964; 29 1980; 20 1973; 13 1983; 1 1995; 57 1984; 24 1984; 29 1996; 36 2005; 45 1981; 23 1985; 25 1983; 56 1998; 68 1982; 23 1976; 14 1965; 89 1980; 18 2000; 36 1969; 2 2006; 25 1988; 28 1997; 18 2005; 96 2000; 40 1977; 12 1979; 20 1979; 21 1969 1979; 180 e_1_2_7_5_2 e_1_2_7_4_2 e_1_2_7_3_2 e_1_2_7_2_2 e_1_2_7_9_2 e_1_2_7_8_2 e_1_2_7_6_2 e_1_2_7_19_2 e_1_2_7_17_2 e_1_2_7_16_2 e_1_2_7_15_2 e_1_2_7_1_2 e_1_2_7_14_2 e_1_2_7_13_2 e_1_2_7_12_2 e_1_2_7_11_2 e_1_2_7_10_2 e_1_2_7_26_2 e_1_2_7_27_2 e_1_2_7_28_2 e_1_2_7_29_2 Frisch K. C. (e_1_2_7_18_2) 1969 e_1_2_7_25_2 e_1_2_7_24_2 e_1_2_7_30_2 e_1_2_7_23_2 e_1_2_7_31_2 e_1_2_7_22_2 e_1_2_7_32_2 Sibal P. W. (e_1_2_7_7_2) 1983; 1 e_1_2_7_21_2 e_1_2_7_33_2 e_1_2_7_20_2 |
| References_xml | – reference: K. Rijswijk, H. E. N. Bersee, A. Beukers, S. J. Picken, A. A. Geenen, Polym. Test. 2006, 25, 392. – reference: A. Yousefi, P. G. Lafleur, R. Gauvin, Polym. Compos. 1997, 18, 157. – reference: M. R. Kamal, S. Sourour, M. Ryan, Polym. Sci. Eng. 1973, 13, 59. – reference: G. C. Alfonso, G. Bonta, S. Russo, A. Traverso, Makromol. Chem. Phys. 1981, 182, 929. – reference: D. Lahlali, M. Naffakh, M. Dumon, Polym. Eng. Sci. 2005, 45, 1581. – reference: R. Z. Greenley, J. C. Stauffer, J. E. Kurz, Macromolecules 1969, 2, 561. – reference: K. Rijswijk, J. J. E. Teuwen, H. E. N. Bersee, A. Beukers, Compos. Part A: Appl. Sci. Manuf. 2009, 40, 1. – reference: S. Sourour, M. R. Kamal, Thermochim. Acta 1976, 14, 41. – reference: P. W. Sibal, R. E. Camargo, C. W. Macosko, Polym. Process Eng. 1983, 1, 147. – reference: K. H. Lee, S. C. Kim, Polym. Eng. Sci. 1988, 28, 13. – reference: S. A. Bolgov, V. P. Begishev, A. Ya Malkin, V. G. Frolov, Polym. Sci. USSR 1981, 23, 1485. – reference: A. Ya Malkin, S. L. Ivanova, V. G. Frolov, A. N. Ivanova, Z. S. Andrianova, Polymer 1982, 23, 1791. – reference: H. K. Reimschuessel, J. Polym. Sci. Macromol. Rev. 1977, 12, 65. – reference: M. Naffakh, M. Dumon, J. Dupuy, J.-F. Gerard, J. Appl. Polym. Sci. 2005, 96, 660. – reference: M. E. Ryan, A. Dutta, Polymer 1979, 20, 203. – reference: C. Hedreul, J. Galy, J. Dupuy, M. Delmotte, C. More, J. Appl. Polym. Sci. 1998, 68, 543. – reference: A. Ya Malkin, V. P. Beghishev, I. A. Keapin, S. A. Bolgov, Polym. Eng. Sci. 1984, 24, 1396. – reference: O. Wichterle, J. Tomka, J. Sebenda, Collect. Czech. Chem. Commun. 1964, 29, 610. – reference: J. Mijovic, J. Kim, J. Slaby, J. Appl. Polym. Sci. 1984, 29, 1449. – reference: D. J. Lin, J. M. Ottino, E. L. Thomas, Polym. Eng. Sci. 1985, 25, 1155. – reference: P. J. Halley, M. E. Mackay, Polym. Eng. Sci. 1996, 36, 593. – reference: L. Bonnaud, J. P. Pascault, H. Sautereau, Eur. Polym. J. 2000, 36, 1313. – reference: A. Ya Malkin, V. G. Frolov, A. N. Ivanova, Z. S. Andrianova, Polym. Sci. USSR 1979, 21, 691. – reference: K. C. Frisch, S. L. Reegen, Eds., Kinetics and Mechanisms of Polymerisation - Ring Opening Polymerization, Marcel Dekker, New York, London 1969. – reference: T. M. Frunze, R. B. Shleifman, E. M. Belavtseva, Ya. V. Genin, T. V. Volkova, V. A. Kotel'nikov, L. G. Radchenko, S. P. Davtyan, V. V. Kraschev, D. Ya. Tsvankin, J. Polym. Sci., Polym. Phys. Ed. 1980, 18, 1523. – reference: V. P. Wittmer, H. Gerrens, Die Makromol. Chem. 1965, 89, 27. – reference: K. J. Kim, Y. Y. Kim, B. S. Yoon, K. J. Yoon, J. Appl. Polym. Sci. 1995, 57, 1347. – reference: K. J. Kim, D. S. Hong, A. R. Tripathy, J. Appl. Polym. Sci. 1997, 66, 1195. – reference: A. Ya Malkin, V. P. Beghishev, S. A. Bolgov, Polymer 1982, 23, 385. – reference: A. Maazouz, J. Dupuy, G. Seytre, Polym. Eng. Sci. 2000, 40, 690. – reference: R. E. Camargo, V. M. Gonzalez, C. W. Macosko, M. Tirrell, Rubber Chem. Technol. 1983, 56, 774. – reference: J. Karger-Kocsis, L. Kiss, Makromol. Chem. Phys. 1979, 180, 1593. – reference: M. R. Kamal, M. E. Ryan, Polym. Eng. Sci. 1980, 20, 859. – volume: 14 start-page: 41 year: 1976 publication-title: Thermochim. Acta – volume: 23 start-page: 385 year: 1982 publication-title: Polymer – volume: 182 start-page: 929 year: 1981 publication-title: Makromol. Chem. Phys. – volume: 66 start-page: 1195 year: 1997 publication-title: J. Appl. Polym. Sci. – volume: 96 start-page: 660 year: 2005 publication-title: J. Appl. Polym. Sci. – volume: 36 start-page: 1313 year: 2000 publication-title: Eur. Polym. J. – volume: 25 start-page: 1155 year: 1985 publication-title: Polym. Eng. Sci. – volume: 180 start-page: 1593 year: 1979 publication-title: Makromol. Chem. Phys. – volume: 68 start-page: 543 year: 1998 publication-title: J. Appl. Polym. Sci. – volume: 23 start-page: 1485 year: 1981 publication-title: Polym. Sci. USSR – volume: 29 start-page: 1449 year: 1984 publication-title: J. Appl. Polym. Sci. – volume: 40 start-page: 690 year: 2000 publication-title: Polym. Eng. Sci. – volume: 40 start-page: 1 year: 2009 publication-title: Compos. Part A: Appl. Sci. Manuf. – volume: 89 start-page: 27 year: 1965 publication-title: Die Makromol. Chem. – volume: 2 start-page: 561 year: 1969 publication-title: Macromolecules – volume: 18 start-page: 1523 year: 1980 publication-title: J. Polym. Sci., Polym. Phys. Ed. – volume: 29 start-page: 610 year: 1964 publication-title: Collect. Czech. Chem. Commun. – volume: 21 start-page: 691 year: 1979 publication-title: Polym. Sci. USSR – volume: 57 start-page: 1347 year: 1995 publication-title: J. Appl. Polym. Sci. – volume: 28 start-page: 13 year: 1988 publication-title: Polym. Eng. Sci. – volume: 24 start-page: 1396 year: 1984 publication-title: Polym. Eng. Sci. – year: 1969 – volume: 20 start-page: 859 year: 1980 publication-title: Polym. Eng. Sci. – volume: 45 start-page: 1581 year: 2005 publication-title: Polym. Eng. Sci. – volume: 23 start-page: 1791 year: 1982 publication-title: Polymer – volume: 36 start-page: 593 year: 1996 publication-title: Polym. Eng. Sci. – volume: 20 start-page: 203 year: 1979 publication-title: Polymer – volume: 13 start-page: 59 year: 1973 publication-title: Polym. Sci. Eng. – volume: 1 start-page: 147 year: 1983 publication-title: Polym. Process Eng. – volume: 12 start-page: 65 year: 1977 publication-title: J. Polym. Sci. Macromol. Rev. – volume: 18 start-page: 157 year: 1997 publication-title: Polym. Compos. – volume: 56 start-page: 774 year: 1983 publication-title: Rubber Chem. Technol. – volume: 25 start-page: 392 year: 2006 publication-title: Polym. Test. – ident: e_1_2_7_20_2 doi: 10.1135/cccc19640610 – ident: e_1_2_7_22_2 doi: 10.1002/pol.1977.230120102 – ident: e_1_2_7_23_2 doi: 10.1002/macp.1979.021800621 – ident: e_1_2_7_6_2 doi: 10.5254/1.3538154 – ident: e_1_2_7_24_2 doi: 10.1002/pen.10447 – ident: e_1_2_7_32_2 doi: 10.1002/pen.760201305 – ident: e_1_2_7_28_2 doi: 10.1016/S0014-3057(99)00197-4 – ident: e_1_2_7_13_2 doi: 10.1016/0040-6031(76)80056-1 – ident: e_1_2_7_3_2 doi: 10.1021/ma60012a001 – ident: e_1_2_7_14_2 doi: 10.1002/(SICI)1097-4628(19971107)66:6<1195::AID-APP19>3.0.CO;2-0 – ident: e_1_2_7_16_2 doi: 10.1016/0032-3861(82)90124-0 – volume-title: Kinetics and Mechanisms of Polymerisation – Ring Opening Polymerization year: 1969 ident: e_1_2_7_18_2 – volume: 1 start-page: 147 year: 1983 ident: e_1_2_7_7_2 publication-title: Polym. Process Eng. – ident: e_1_2_7_19_2 doi: 10.1002/macp.1981.021820324 – ident: e_1_2_7_2_2 doi: 10.1016/j.compositesa.2008.03.018 – ident: e_1_2_7_31_2 doi: 10.1002/pen.11199 – ident: e_1_2_7_17_2 doi: 10.1002/macp.1965.020890103 – ident: e_1_2_7_25_2 doi: 10.1002/pc.10270 – ident: e_1_2_7_5_2 doi: 10.1002/pen.760251808 – ident: e_1_2_7_10_2 doi: 10.1016/0032-3950(81)90118-0 – ident: e_1_2_7_1_2 doi: 10.1016/j.polymertesting.2005.11.008 – ident: e_1_2_7_4_2 doi: 10.1016/0032-3950(79)90296-X – ident: e_1_2_7_33_2 doi: 10.1016/0032-3861(79)90222-2 – ident: e_1_2_7_29_2 doi: 10.1002/pen.20274 – ident: e_1_2_7_8_2 doi: 10.1002/pen.760280104 – ident: e_1_2_7_30_2 doi: 10.1002/app.1984.070290437 – ident: e_1_2_7_12_2 doi: 10.1002/pen.760130110 – ident: e_1_2_7_9_2 doi: 10.1002/app.1995.070571111 – ident: e_1_2_7_21_2 doi: 10.1002/pol.1980.180180704 – ident: e_1_2_7_15_2 doi: 10.1016/0032-3861(82)90340-8 – ident: e_1_2_7_27_2 doi: 10.1002/app.21495 – ident: e_1_2_7_11_2 doi: 10.1002/pen.760241805 – ident: e_1_2_7_26_2 doi: 10.1002/(SICI)1097-4628(19980425)68:4<543::AID-APP5>3.0.CO;2-M |
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| Snippet | Semi‐adiabatic temperature measurements are recorded and used to define semi‐empirical equations for the simulation and prediction of the anionic polyamide‐6... Semi-adiabatic temperature measurements are recorded and used to define semi-empirical equations for the simulation and prediction of the anionic polyamide-6... |
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| SubjectTerms | activation energy anionic polymerization Applied sciences Crystallization Exact sciences and technology Infusion Kinetics kinetics (polym.) Mathematical analysis Mathematical models Organic polymers Physicochemistry of polymers polyamides Polymerization Polymers Preparation, kinetics, thermodynamics, mechanism and catalysts Reaction kinetics Resins Studies Thermosetting resins |
| Title | Novel Reaction Kinetic Model for Anionic Polyamide-6 |
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