Tunable structural color of bottlebrush block copolymers through direct-write 3D printing from solution

Additive manufacturing of functional materials is limited by control of microstructure and assembly at the nanoscale. In this work, we integrate nonequilibrium self-assembly with direct-write three-dimensional (3D) printing to prepare bottlebrush block copolymer (BBCP) photonic crystals (PCs) with t...

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Published inScience advances Vol. 6; no. 24; p. eaaz7202
Main Authors Patel, Bijal B, Walsh, Dylan J, Kim, Do Hoon, Kwok, Justin, Lee, Byeongdu, Guironnet, Damien, Diao, Ying
Format Journal Article
LanguageEnglish
Published United States AAAS 01.06.2020
American Association for the Advancement of Science
Subjects
ENGINEERING
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
MATERIALS SCIENCE
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Abstract Additive manufacturing of functional materials is limited by control of microstructure and assembly at the nanoscale. In this work, we integrate nonequilibrium self-assembly with direct-write three-dimensional (3D) printing to prepare bottlebrush block copolymer (BBCP) photonic crystals (PCs) with tunable structure color. After varying deposition conditions during printing of a single ink solution, peak reflected wavelength for BBCP PCs span a range of 403 to 626 nm (blue to red), corresponding to an estimated change in d-spacing of >70 nm (Bragg- Snell equation). Physical characterization confirms that these vivid optical effects are underpinned by tuning of lamellar domain spacing, which we attribute to modulation of polymer conformation. Using in situ optical microscopy and solvent-vapor annealing, we identify kinetic trapping of metastable microstructures during printing as the mechanism for domain size control. More generally, we present a robust processing scheme with potential for on-the-fly property tuning of a variety of functional materials.
AbstractList Additive manufacturing of functional materials is limited by control of microstructure and assembly at the nanoscale. In this work, we integrate nonequilibrium self-assembly with direct-write three-dimensional (3D) printing to prepare bottlebrush block copolymer (BBCP) photonic crystals (PCs) with tunable structure color. After varying deposition conditions during printing of a single ink solution, peak reflected wavelength for BBCP PCs span a range of 403 to 626 nm (blue to red), corresponding to an estimated change in d-spacing of >70 nm (Bragg- Snell equation). Physical characterization confirms that these vivid optical effects are underpinned by tuning of lamellar domain spacing, which we attribute to modulation of polymer conformation. Using in situ optical microscopy and solvent-vapor annealing, we identify kinetic trapping of metastable microstructures during printing as the mechanism for domain size control. More generally, we present a robust processing scheme with potential for on-the-fly property tuning of a variety of functional materials.
Using direct-write 3D printing, we tune structural color of bottlebrush block copolymer photonics via kinetic trapping. Additive manufacturing of functional materials is limited by control of microstructure and assembly at the nanoscale. In this work, we integrate nonequilibrium self-assembly with direct-write three-dimensional (3D) printing to prepare bottlebrush block copolymer (BBCP) photonic crystals (PCs) with tunable structure color. After varying deposition conditions during printing of a single ink solution, peak reflected wavelength for BBCP PCs span a range of 403 to 626 nm (blue to red), corresponding to an estimated change in d-spacing of >70 nm (Bragg- Snell equation). Physical characterization confirms that these vivid optical effects are underpinned by tuning of lamellar domain spacing, which we attribute to modulation of polymer conformation. Using in situ optical microscopy and solvent-vapor annealing, we identify kinetic trapping of metastable microstructures during printing as the mechanism for domain size control. More generally, we present a robust processing scheme with potential for on-the-fly property tuning of a variety of functional materials.
Author Walsh, Dylan J
Guironnet, Damien
Kim, Do Hoon
Lee, Byeongdu
Kwok, Justin
Diao, Ying
Patel, Bijal B
Author_xml – sequence: 1
  givenname: Bijal B
  orcidid: 0000-0002-8015-9075
  surname: Patel
  fullname: Patel, Bijal B
  organization: Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, IL 61801, USA
– sequence: 2
  givenname: Dylan J
  orcidid: 0000-0001-7981-2770
  surname: Walsh
  fullname: Walsh, Dylan J
  organization: Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, IL 61801, USA
– sequence: 3
  givenname: Do Hoon
  orcidid: 0000-0002-7187-3306
  surname: Kim
  fullname: Kim, Do Hoon
  organization: Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109, USA
– sequence: 4
  givenname: Justin
  orcidid: 0000-0003-3909-4369
  surname: Kwok
  fullname: Kwok, Justin
  organization: Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 1304 W. Green St., Urbana, IL 61801, USA
– sequence: 5
  givenname: Byeongdu
  orcidid: 0000-0003-2514-8805
  surname: Lee
  fullname: Lee, Byeongdu
  organization: X-Ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439, USA
– sequence: 6
  givenname: Damien
  orcidid: 0000-0002-0356-6697
  surname: Guironnet
  fullname: Guironnet, Damien
  organization: Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, IL 61801, USA
– sequence: 7
  givenname: Ying
  orcidid: 0000-0002-8984-0051
  surname: Diao
  fullname: Diao, Ying
  organization: Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, IL 61801, USA
BackLink https://www.ncbi.nlm.nih.gov/pubmed/32577511$$D View this record in MEDLINE/PubMed
https://www.osti.gov/servlets/purl/1815527$$D View this record in Osti.gov
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Snippet Additive manufacturing of functional materials is limited by control of microstructure and assembly at the nanoscale. In this work, we integrate nonequilibrium...
Using direct-write 3D printing, we tune structural color of bottlebrush block copolymer photonics via kinetic trapping. Additive manufacturing of functional...
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MATERIALS SCIENCE
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Title Tunable structural color of bottlebrush block copolymers through direct-write 3D printing from solution
URI https://www.ncbi.nlm.nih.gov/pubmed/32577511
https://search.proquest.com/docview/2416945981
https://www.osti.gov/servlets/purl/1815527
https://pubmed.ncbi.nlm.nih.gov/PMC7286684
Volume 6
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