Mechanochemistry - a new powerful green approach to the direct synthesis of alkoxysilanes

The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes by silicon mechanoactivation followed by a reaction with an alcohol. Alkoxysilanes were obtained with nearly complete silicon and alcohol conversion. This method allows for a considerable simplifi...

Full description

Saved in:
Bibliographic Details
Published inGreen chemistry : an international journal and green chemistry resource : GC Vol. 2; no. 9; pp. 1962 - 1969
Main Authors Temnikov, Maxim N, Anisimov, Anton A, Zhemchugov, Pavel V, Kholodkov, Dmitry N, Goloveshkin, Alexander S, Naumkin, Alexander V, Chistovalov, Sergey M, Katsoulis, Dimitris, Muzafarov, Aziz M
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 2018
Subjects
Abrasion
Alcohol
Alcohols
Alkoxysilanes
Catalysis
catalysts
Chemical synthesis
Comminution
energy-dispersive X-ray analysis
Green chemistry
grinding
mechanochemistry
milling
Oxide coatings
Photoelectron spectroscopy
Reactors
Scanning electron microscopy
Silicon
vibration
X ray photoelectron spectroscopy
X ray powder diffraction
X-ray diffraction
X-ray spectroscopy
Online AccessGet full text

Cover

Abstract The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes by silicon mechanoactivation followed by a reaction with an alcohol. Alkoxysilanes were obtained with nearly complete silicon and alcohol conversion. This method allows for a considerable simplification of the traditional multistage process by eliminating three stages that include silicon and catalyst preparation, and adapts it to green chemistry requirements. Vibration milling removed the oxide film, and the mechanoactivation of the large silicon fraction (1000-2000 μm) occurs in the reactor working space. Abrasion of the reactor walls and grinding bodies made of brass results in a developed catalytic surface on silicon, as it has been proven by a set of physical analytical methods such as scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), powder X-ray diffraction (PXRD), and X-ray photoelectron spectroscopy (XPS). The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes.
AbstractList The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes by silicon mechanoactivation followed by a reaction with an alcohol. Alkoxysilanes were obtained with nearly complete silicon and alcohol conversion. This method allows for a considerable simplification of the traditional multistage process by eliminating three stages that include silicon and catalyst preparation, and adapts it to green chemistry requirements. Vibration milling removed the oxide film, and the mechanoactivation of the large silicon fraction (1000-2000 μm) occurs in the reactor working space. Abrasion of the reactor walls and grinding bodies made of brass results in a developed catalytic surface on silicon, as it has been proven by a set of physical analytical methods such as scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), powder X-ray diffraction (PXRD), and X-ray photoelectron spectroscopy (XPS). The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes.
The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes by silicon mechanoactivation followed by a reaction with an alcohol. Alkoxysilanes were obtained with nearly complete silicon and alcohol conversion. This method allows for a considerable simplification of the traditional multistage process by eliminating three stages that include silicon and catalyst preparation, and adapts it to green chemistry requirements. Vibration milling removed the oxide film, and the mechanoactivation of the large silicon fraction (1000–2000 μm) occurs in the reactor working space. Abrasion of the reactor walls and grinding bodies made of brass results in a developed catalytic surface on silicon, as it has been proven by a set of physical analytical methods such as scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), powder X-ray diffraction (PXRD), and X-ray photoelectron spectroscopy (XPS).
Author Muzafarov, Aziz M
Katsoulis, Dimitris
Kholodkov, Dmitry N
Naumkin, Alexander V
Goloveshkin, Alexander S
Zhemchugov, Pavel V
Temnikov, Maxim N
Anisimov, Anton A
Chistovalov, Sergey M
AuthorAffiliation Dow Corning Corporation. A wholly owned subsidiary of The Dow Chemical Company
A.N. Nesmeyanov Institute of Organoelement Compounds
N.S. Enikolopov Institute of Synthetic Polymeric Materials
Russian Academy of Sciences (ISPM RAS)
Russian Academy of Sciences (INEOS RAS)
AuthorAffiliation_xml – sequence: 0
  name: Dow Corning Corporation. A wholly owned subsidiary of The Dow Chemical Company
– sequence: 0
  name: N.S. Enikolopov Institute of Synthetic Polymeric Materials
– sequence: 0
  name: A.N. Nesmeyanov Institute of Organoelement Compounds
– sequence: 0
  name: Russian Academy of Sciences (INEOS RAS)
– sequence: 0
  name: Russian Academy of Sciences (ISPM RAS)
Author_xml – sequence: 1
  givenname: Maxim N
  surname: Temnikov
  fullname: Temnikov, Maxim N
– sequence: 2
  givenname: Anton A
  surname: Anisimov
  fullname: Anisimov, Anton A
– sequence: 3
  givenname: Pavel V
  surname: Zhemchugov
  fullname: Zhemchugov, Pavel V
– sequence: 4
  givenname: Dmitry N
  surname: Kholodkov
  fullname: Kholodkov, Dmitry N
– sequence: 5
  givenname: Alexander S
  surname: Goloveshkin
  fullname: Goloveshkin, Alexander S
– sequence: 6
  givenname: Alexander V
  surname: Naumkin
  fullname: Naumkin, Alexander V
– sequence: 7
  givenname: Sergey M
  surname: Chistovalov
  fullname: Chistovalov, Sergey M
– sequence: 8
  givenname: Dimitris
  surname: Katsoulis
  fullname: Katsoulis, Dimitris
– sequence: 9
  givenname: Aziz M
  surname: Muzafarov
  fullname: Muzafarov, Aziz M
BookMark eNptkU1LAzEQhoMoqNWLdyHgRYTVZJNN3KMsWoWKFz14WrLjxK5uk5qk1P57oxUF8TQfPDO8884u2XTeISEHnJ1yJuoz0M_AxLkqYYPscKlEUZeabf7kqtwmuzG-MMa5VnKHPN4iTI3zMMVZH1NY0YIa6nBJ536JwS4G-hwQHTXzefAGpjR5mqZIn_qAkGhcuVzFPlJvqRle_fsq9oNxGPfIljVDxP3vOCIPV5f3zXUxuRvfNBeTAiTXqZBdJSorJANVd4IhN5W2vFaYe-esQysBOitR1Vo9Gc1rQG0rIRV0lZJYiRE5Xu_N-t4WGFObDwEcPkX4RWzLsuQse8N4Ro_-oC9-EVxW15ZMKCFkqVWmTtYUBB9jQNvOQz8zYdVy1n663DZ63Hy53GSY_YGhTyb13qVg-uH_kcP1SIjws_r3ceIDK92K4w
CitedBy_id crossref_primary_10_1002_admi_201801789
crossref_primary_10_3390_ijms25105504
crossref_primary_10_1002_cssc_202100478
crossref_primary_10_1016_j_powtec_2024_119558
crossref_primary_10_1002_ejic_202000848
crossref_primary_10_1016_j_jorganchem_2022_122482
crossref_primary_10_1016_j_cej_2022_135286
crossref_primary_10_1021_acssuschemeng_8b04458
crossref_primary_10_3390_appliedchem3010007
crossref_primary_10_3390_polym17030279
crossref_primary_10_59761_RCR5081
crossref_primary_10_1016_j_jorganchem_2021_121976
crossref_primary_10_1021_acssuschemeng_0c05493
crossref_primary_10_1007_s11172_019_2382_x
crossref_primary_10_1039_D4GC00472H
crossref_primary_10_1039_D1RE00522G
crossref_primary_10_1016_j_polymer_2024_127925
crossref_primary_10_1002_nadc_20194085243
crossref_primary_10_1021_acssuschemeng_2c04086
crossref_primary_10_1021_acssuschemeng_3c03290
crossref_primary_10_1021_acs_iecr_3c03711
crossref_primary_10_1016_j_apsusc_2021_150455
crossref_primary_10_3762_bjoc_14_131
crossref_primary_10_1021_acsapm_2c01265
crossref_primary_10_1021_acs_iecr_0c00505
crossref_primary_10_1039_C9GC02781E
Cites_doi 10.1007/s12633-014-9233-z
10.1039/C7GC01078H
10.1021/acssuschemeng.5b01620
10.1021/ma047984n
10.1002/anie.201001640
10.1021/acscentsci.6b00277
10.1021/am503845s
10.1016/0021-9517(90)90312-8
10.1039/C7GC01463E
10.1021/acssuschemeng.6b00363
10.1021/acs.jpcc.6b04054
10.1007/BF00814244
10.1002/anie.201504236
10.1007/s11172-013-0096-z
10.1007/s11172-014-0422-0
10.1016/j.jcat.2016.03.012
10.4028/www.scientific.net/AMR.455-456.80
10.1039/C4PY00919C
10.1021/acscatal.6b00861
10.1021/ja0778491
10.1007/s12633-014-9236-9
10.1021/ja01222a026
10.1016/S1007-0214(06)70185-7
10.1002/aoc.1794
10.1021/jp302788s
10.1021/es506016w
10.1002/asia.201700160
10.1128/AAC.03728-14
10.1016/0167-2738(91)90186-F
10.5012/bkcs.2009.30.12.3147
10.1021/acssuschemeng.6b02226
10.1002/app.26252
10.1039/C4RA13619E
10.1021/ja3042977
10.1134/S0012500809010042
10.1007/s11172-016-1405-0
10.1007/s11172-017-1726-7
10.1002/anie.201104948
10.1021/acs.joc.6b01138
10.1016/0022-328X(89)85131-9
10.1134/S1070363216080144
10.1007/s11172-016-1419-7
10.1002/(SICI)1099-0739(199703)11:3<237::AID-AOC557>3.0.CO;2-4
10.1134/S108765961203008X
10.1016/0022-328X(91)86378-4
10.1021/acsmacrolett.6b00529
10.1016/S0925-8388(98)00527-1
10.1021/acs.joc.6b02197
10.1039/C3GC41370E
10.1002/cplu.201300027
10.1163/156856706777346462
10.1007/s11172-015-1183-0
10.1023/A:1020757522785
10.1039/c3gc36720g
10.1021/cm4023387
10.1016/j.polymer.2012.05.033
10.1016/S0022-328X(00)00543-X
ContentType Journal Article
Copyright Copyright Royal Society of Chemistry 2018
Copyright_xml – notice: Copyright Royal Society of Chemistry 2018
DBID AAYXX
CITATION
7SR
7ST
7U6
8BQ
8FD
C1K
JG9
7S9
L.6
DOI 10.1039/c7gc03862c
DatabaseName CrossRef
Engineered Materials Abstracts
Environment Abstracts
Sustainability Science Abstracts
METADEX
Technology Research Database
Environmental Sciences and Pollution Management
Materials Research Database
AGRICOLA
AGRICOLA - Academic
DatabaseTitle CrossRef
Materials Research Database
Engineered Materials Abstracts
Technology Research Database
Sustainability Science Abstracts
Environment Abstracts
METADEX
Environmental Sciences and Pollution Management
AGRICOLA
AGRICOLA - Academic
DatabaseTitleList
CrossRef
AGRICOLA
Materials Research Database
DeliveryMethod fulltext_linktorsrc
Discipline Engineering
Chemistry
Environmental Sciences
EISSN 1463-9270
EndPage 1969
ExternalDocumentID 10_1039_C7GC03862C
c7gc03862c
GroupedDBID -JG
0-7
0R~
29I
4.4
5GY
705
70~
7~J
AAEMU
AAHBH
AAIWI
AAJAE
AAMEH
AANOJ
AAWGC
AAXHV
AAXPP
ABASK
ABDVN
ABEMK
ABJNI
ABPDG
ABRYZ
ABXOH
ACGFO
ACGFS
ACIWK
ACLDK
ADMRA
ADSRN
AEFDR
AENEX
AENGV
AESAV
AETIL
AFLYV
AFOGI
AFRAH
AFRDS
AFVBQ
AGEGJ
AGKEF
AGRSR
AGSTE
AHGCF
ALMA_UNASSIGNED_HOLDINGS
ANUXI
APEMP
ASKNT
AUDPV
BLAPV
BSQNT
C6K
COF
CS3
D0L
DU5
EBS
ECGLT
EE0
EF-
EJD
F5P
GGIMP
GNO
H13
HZ~
H~N
IDZ
J3I
M4U
N9A
O9-
OK1
P2P
R7B
RAOCF
RCNCU
RNS
RPMJG
RRA
RRC
RSCEA
SKA
SLH
VH6
0UZ
1TJ
53G
71~
AAYXX
ACHDF
ACRPL
ADNMO
ADVLN
AFFNX
AFRZK
AGQPQ
AHGXI
AITUG
AKMSF
AKRWK
ALSGL
ALUYA
AMRAJ
ANBJS
ANLMG
ASPBG
AVWKF
AZFZN
BBWZM
CAG
CITATION
EEHRC
FEDTE
HVGLF
H~9
IDY
J3G
J3H
L-8
NDZJH
R56
RCLXC
ROL
7SR
7ST
7U6
8BQ
8FD
C1K
JG9
7S9
L.6
ID FETCH-LOGICAL-c417t-4b535f340c69b30e1a57f196ef3480bef4ccbf4e6976da719ce7f5346cb564e53
ISSN 1463-9262
1463-9270
IngestDate Fri Jul 11 01:11:32 EDT 2025
Mon Jun 30 11:57:00 EDT 2025
Tue Jul 01 01:41:14 EDT 2025
Thu Apr 24 23:08:40 EDT 2025
Tue Dec 17 20:58:55 EST 2024
IsPeerReviewed true
IsScholarly true
Issue 9
Language English
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-c417t-4b535f340c69b30e1a57f196ef3480bef4ccbf4e6976da719ce7f5346cb564e53
Notes Electronic supplementary information (ESI) available. See DOI
10.1039/c7gc03862c
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
content type line 23
ORCID 0000-0002-0345-8725
0000-0002-3050-3253
0000-0001-5696-5723
PQID 2036334276
PQPubID 2047490
PageCount 8
ParticipantIDs proquest_journals_2036334276
proquest_miscellaneous_2221003901
crossref_primary_10_1039_C7GC03862C
rsc_primary_c7gc03862c
crossref_citationtrail_10_1039_C7GC03862C
ProviderPackageCode CITATION
AAYXX
PublicationCentury 2000
PublicationDate 2018-00-00
PublicationDateYYYYMMDD 2018-01-01
PublicationDate_xml – year: 2018
  text: 2018-00-00
PublicationDecade 2010
PublicationPlace Cambridge
PublicationPlace_xml – name: Cambridge
PublicationTitle Green chemistry : an international journal and green chemistry resource : GC
PublicationYear 2018
Publisher Royal Society of Chemistry
Publisher_xml – name: Royal Society of Chemistry
References Temnikov (C7GC03862C-(cit34)/*[position()=1]) 2015; 7
Lu (C7GC03862C-(cit71)/*[position()=1]) 2016; 4
Gillot (C7GC03862C-(cit72)/*[position()=1]) 1998; 270
Qi (C7GC03862C-(cit62)/*[position()=1]) 2014; 16
Kalinina (C7GC03862C-(cit2)/*[position()=1]) 2016; 65
Clarke (C7GC03862C-(cit38)/*[position()=1]) 1991; 408
Gupta (C7GC03862C-(cit67)/*[position()=1]) 2017; 19
Milenin (C7GC03862C-(cit7)/*[position()=1]) 2015; 64
Maratkanova (C7GC03862C-(cit69)/*[position()=1]) 2012; 116
Brook (C7GC03862C-(cit19)/*[position()=1]) 2010; 235
Do (C7GC03862C-(cit58)/*[position()=1]) 2017; 3
Jia (C7GC03862C-(cit65)/*[position()=1]) 2016; 81
Lou (C7GC03862C-(cit66)/*[position()=1]) 2016; 6
Chlenol (C7GC03862C-(cit75)/*[position()=1]) 1972
Laengert (C7GC03862C-(cit15)/*[position()=1]) 2017; 12
Krylova (C7GC03862C-(cit82)/*[position()=1]) 2017; 66
Gorshkov (C7GC03862C-(cit56)/*[position()=1]) 2002; 75
Thompson (C7GC03862C-(cit17)/*[position()=1]) 2008; 130
Tan (C7GC03862C-(cit70)/*[position()=1]) 2015; 49
Okamoto (C7GC03862C-(cit81)/*[position()=1]) 1995; 33
Madsen (C7GC03862C-(cit13)/*[position()=1]) 2014; 5
Sugawara (C7GC03862C-(cit25)/*[position()=1]) 2014; 58
Wakabayashi (C7GC03862C-(cit16)/*[position()=1]) 2013; 78
Zhang (C7GC03862C-(cit37)/*[position()=1]) 2011; 233–235
Xunjun (C7GC03862C-(cit12)/*[position()=1]) 2007; 106
Kalinina (C7GC03862C-(cit5)/*[position()=1]) 2014; 7
Yu (C7GC03862C-(cit59)/*[position()=1]) 2016; 120
Rochow (C7GC03862C-(cit1)/*[position()=1]) 1945; 67
Milenin (C7GC03862C-(cit3)/*[position()=1]) 2013; 62
Kuroda (C7GC03862C-(cit9)/*[position()=1]) 2013; 26
Khalimon (C7GC03862C-(cit11)/*[position()=1]) 2012; 134
Kalinina (C7GC03862C-(cit20)/*[position()=1]) 2015; 5
Okamoto (C7GC03862C-(cit27)/*[position()=1]) 2006; 32
Wang (C7GC03862C-(cit31)/*[position()=1]) 2012; 455
Luo (C7GC03862C-(cit80)/*[position()=1]) 2006; 11
Lei (C7GC03862C-(cit32)/*[position()=1]) 2011; 25
Julien (C7GC03862C-(cit61)/*[position()=1]) 2017; 19
Kareem (C7GC03862C-(cit30)/*[position()=1]) 2012; 12
Brook (C7GC03862C-(cit21)/*[position()=1]) 2000
Ladilina (C7GC03862C-(cit10)/*[position()=1]) 2012; 38
Kalinina (C7GC03862C-(cit6)/*[position()=1]) 2016; 65
Rubinsztajn (C7GC03862C-(cit18)/*[position()=1]) 2005; 38
Han (C7GC03862C-(cit33)/*[position()=1]) 2009; 30
Suzuki (C7GC03862C-(cit79)/*[position()=1]) 1990; 125
Grande (C7GC03862C-(cit14)/*[position()=1]) 2012; 53
Oka (C7GC03862C-(cit68)/*[position()=1]) 2016; 5
Yu (C7GC03862C-(cit63)/*[position()=1]) 2016; 81
Suzuki (C7GC03862C-(cit77)/*[position()=1]) 1991; 47
Chigondo (C7GC03862C-(cit29)/*[position()=1]) 2016; 4
Soldatov (C7GC03862C-(cit4)/*[position()=1]) 2014; 63
Wakabayashi (C7GC03862C-(cit23)/*[position()=1]) 2010; 49
Okamoto (C7GC03862C-(cit78)/*[position()=1]) 2000; 616
Wakabayashi (C7GC03862C-(cit22)/*[position()=1]) 2011; 50
Chen (C7GC03862C-(cit73)/*[position()=1]) 2015; 54
Cook (C7GC03862C-(cit64)/*[position()=1]) 2013; 15
Haley (C7GC03862C-(cit74)/*[position()=1]) 2016; 4
Ehrich (C7GC03862C-(cit76)/*[position()=1]) 1997; 11
Sun (C7GC03862C-(cit35)/*[position()=1]) 1997; 46
Adonin (C7GC03862C-(cit28)/*[position()=1]) 2016; 338
Clarke (C7GC03862C-(cit36)/*[position()=1]) 1989; 376
Egorova (C7GC03862C-(cit8)/*[position()=1]) 2009; 424
Lebedev (C7GC03862C-(cit26)/*[position()=1]) 2016; 86
McMahon (C7GC03862C-(cit60)/*[position()=1]) 2014; 6
References_xml – issn: 2009
  volume-title: Process for Preparation of Trialkoxysilanes
  end-page: 7.582.788B2
  publication-title: US Patent
  doi: Roston Cody Bowman
– issn: 1972
  publication-title: Vibrokipyashchiy sloy
  doi: Chlenol Mikhaylov
– issn: 2000
  publication-title: Silicon in Organic, Organometallic, and Polymer Chemistry
  doi: Brook
– issn: 2008
  volume-title: Process for the Direct Synthesis of Trialkoxysilane
  end-page: 7.429.672B2
  publication-title: US Patent
  doi: Lewis Cameron Ritscher
– issn: 2011
  volume-title: Method of Producing a Hydrolyzable Silicone-Containing Compound
  end-page: WO2012091154A1
  doi: Wakabayashi Oda Taniguchi Sugiura
– issn: 2006
  volume-title: Method for Preparing Alkoxysilanes
  end-page: 2277537C1
  publication-title: RU Patent
  doi: Gorshkov Storozhenko
– issn: 2008
  volume-title: Nanosized Copper Catalyst Precursors for the Direct Synthesis of Trialkoxysilanes
  end-page: 2008081923A1
  publication-title: US Patent
  doi: Lewis Eng Cromer Mereigh O'Young
– issn: 2002
  volume-title: Method of Regeneration of Solvent in Process Direct Synthesis of Alkoxysilane
  end-page: 2185384C1
  publication-title: RU Patent
  doi: Kopylov Markacheva Polivanov
– issn: 2004
  volume-title: Apparatus and Process for Preparing Substantially Halogen-Free Trialkoxysilanes
  end-page: 6.727.375B2
  publication-title: US Patent
  doi: Steding Grund Standke Horn Frings Monkiewicz Srebny Seiler Kotzsch
– issn: 2007
  end-page: 20070073076A1
  publication-title: US Patent
  doi: Lewis Wang
– issn: 2007
  volume-title: Process for the Direct Synthesis of Trialkoxysilane
  end-page: 2007/0060764A1
  publication-title: US Patent
  doi: Lewis Mereigh O'Young Cameron
– issn: 2010
  issue: 235
  end-page: 161-183
  publication-title: Advances in Polymer Science
  doi: Brook Grande Ganachaud
– issn: 2003
  volume-title: "Ivtekhim," Method of Synthesis of Alkoxysilanes
  end-page: 2196142C2
  publication-title: RU Patent
– issn: 2002
  volume-title: Freshly Precipitated CuO as Catalyst for the trialkoxysilane synthesis
  end-page: 6.380.414B2
  publication-title: US Patent
  doi: Brand
– issn: 2002
  volume-title: Fluorinated copper salts as catalysts for the synthesis of trialkoxysilanes
  end-page: 6.410.771B1
  publication-title: US Patent
  doi: Brand
– issn: 2012
  volume-title: Catalyst of Direct Synthesis of Triethoxysilane and Method of its Obtaining
  end-page: 2468865C1
  publication-title: RU Patent
  doi: Parmon Adonin Zajkovskij Prosvirin Mel'gunov Storozhenko Monin Bykova Rusakov Martynov Rogozhin
– issn: 2013
  volume-title: Method of Production Trialkoxysilane
  end-page: 2476435C1
  publication-title: RU Patent
  doi: Monin Storozhenko Bykova Rusakov
– issn: 2001
  volume-title: Removal of Dissolved Silicates from Alcohol-Silicon Direct Synthesis Solvents
  end-page: 01/12635A1
  publication-title: WO Patent
  doi: Simandan Mendicino
– issn: 2008
  volume-title: Process for Preparation of alkoxysilanes
  end-page: 2008/0132721A1
  publication-title: US Patent
  doi: Roston Cody Bowman
– issn: 2007
  volume-title: Surface-Active Additives in the Direct Synthesis of Trialkoxysilanes
  end-page: RE39.650E
  publication-title: US Patent
  doi: Mendicino Lewis Magri Yu Childress
– issn: 2004
  volume-title: Method of Synthesis of Alkoxysilanes
  end-page: 2235726C1
  publication-title: RU Patent
  doi: Gorshkov Markacheva Storozhenko
– issn: 2001
  volume-title: Nanosize copper catalyst precursors for the direct synthesis of trialkoxysilanes
  end-page: 2319851A1
  publication-title: EP Patent
  doi: Lewis Eng Cromer O'Young Mereigh
– volume: 233–235
  start-page: 1534
  year: 2011
  ident: C7GC03862C-(cit37)/*[position()=1]
  publication-title: Adv. Mater. Res.
– volume: 7
  start-page: 95
  year: 2014
  ident: C7GC03862C-(cit5)/*[position()=1]
  publication-title: Silicon
  doi: 10.1007/s12633-014-9233-z
– volume: 19
  start-page: 2729
  year: 2017
  ident: C7GC03862C-(cit61)/*[position()=1]
  publication-title: Green Chem.
  doi: 10.1039/C7GC01078H
– volume: 4
  start-page: 2165
  year: 2016
  ident: C7GC03862C-(cit71)/*[position()=1]
  publication-title: ACS Sustainable Chem. Eng.
  doi: 10.1021/acssuschemeng.5b01620
– volume: 38
  start-page: 1061
  year: 2005
  ident: C7GC03862C-(cit18)/*[position()=1]
  publication-title: Macromolecules
  doi: 10.1021/ma047984n
– volume: 49
  start-page: 5273
  year: 2010
  ident: C7GC03862C-(cit23)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201001640
– volume: 3
  start-page: 13
  year: 2017
  ident: C7GC03862C-(cit58)/*[position()=1]
  publication-title: ACS Cent. Sci.
  doi: 10.1021/acscentsci.6b00277
– volume: 6
  start-page: 19579
  year: 2014
  ident: C7GC03862C-(cit60)/*[position()=1]
  publication-title: ACS Appl. Mater. Interfaces
  doi: 10.1021/am503845s
– volume: 125
  start-page: 390
  year: 1990
  ident: C7GC03862C-(cit79)/*[position()=1]
  publication-title: J. Catal.
  doi: 10.1016/0021-9517(90)90312-8
– volume: 19
  start-page: 4153
  year: 2017
  ident: C7GC03862C-(cit67)/*[position()=1]
  publication-title: Green Chem.
  doi: 10.1039/C7GC01463E
– volume: 4
  start-page: 2464
  year: 2016
  ident: C7GC03862C-(cit74)/*[position()=1]
  publication-title: ACS Sustainable Chem. Eng.
  doi: 10.1021/acssuschemeng.6b00363
– volume: 120
  start-page: 19613
  year: 2016
  ident: C7GC03862C-(cit59)/*[position()=1]
  publication-title: J. Phys. Chem. C
  doi: 10.1021/acs.jpcc.6b04054
– volume: 33
  start-page: 421
  year: 1995
  ident: C7GC03862C-(cit81)/*[position()=1]
  publication-title: Catal. Lett.
  doi: 10.1007/BF00814244
– volume: 54
  start-page: 11084
  year: 2015
  ident: C7GC03862C-(cit73)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201504236
– volume: 62
  start-page: 705
  year: 2013
  ident: C7GC03862C-(cit3)/*[position()=1]
  publication-title: Russ. Chem. Bull.
  doi: 10.1007/s11172-013-0096-z
– volume: 63
  start-page: 267
  year: 2014
  ident: C7GC03862C-(cit4)/*[position()=1]
  publication-title: Russ. Chem. Bull.
  doi: 10.1007/s11172-014-0422-0
– volume: 338
  start-page: 143
  year: 2016
  ident: C7GC03862C-(cit28)/*[position()=1]
  publication-title: J. Catal.
  doi: 10.1016/j.jcat.2016.03.012
– volume-title: Vibrokipyashchiy sloy
  year: 1972
  ident: C7GC03862C-(cit75)/*[position()=1]
– volume: 455
  start-page: 80
  year: 2012
  ident: C7GC03862C-(cit31)/*[position()=1]
  publication-title: Adv. Mater. Res.
  doi: 10.4028/www.scientific.net/AMR.455-456.80
– volume: 5
  start-page: 7054
  year: 2014
  ident: C7GC03862C-(cit13)/*[position()=1]
  publication-title: Polym. Chem.
  doi: 10.1039/C4PY00919C
– volume-title: Silicon in Organic, Organometallic, and Polymer Chemistry
  year: 2000
  ident: C7GC03862C-(cit21)/*[position()=1]
– volume: 6
  start-page: 3890
  year: 2016
  ident: C7GC03862C-(cit66)/*[position()=1]
  publication-title: ACS Catal.
  doi: 10.1021/acscatal.6b00861
– volume: 12
  start-page: 27
  year: 2012
  ident: C7GC03862C-(cit30)/*[position()=1]
  publication-title: J. Assoc. Arab Univ. Basic Appl. Sci.
– volume: 130
  start-page: 32
  year: 2008
  ident: C7GC03862C-(cit17)/*[position()=1]
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja0778491
– volume: 7
  start-page: 69
  year: 2015
  ident: C7GC03862C-(cit34)/*[position()=1]
  publication-title: Silicon
  doi: 10.1007/s12633-014-9236-9
– volume: 67
  start-page: 963
  year: 1945
  ident: C7GC03862C-(cit1)/*[position()=1]
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja01222a026
– volume: 11
  start-page: 252
  year: 2006
  ident: C7GC03862C-(cit80)/*[position()=1]
  publication-title: Tsinghua Sci. Technol.
  doi: 10.1016/S1007-0214(06)70185-7
– volume: 25
  start-page: 508
  year: 2011
  ident: C7GC03862C-(cit32)/*[position()=1]
  publication-title: Appl. Organomet. Chem.
  doi: 10.1002/aoc.1794
– volume: 116
  start-page: 14005
  year: 2012
  ident: C7GC03862C-(cit69)/*[position()=1]
  publication-title: J. Phys. Chem. C
  doi: 10.1021/jp302788s
– volume: 235
  volume-title: Advances in Polymer Science
  year: 2010
  ident: C7GC03862C-(cit19)/*[position()=1]
– volume: 49
  start-page: 5849
  year: 2015
  ident: C7GC03862C-(cit70)/*[position()=1]
  publication-title: Environ. Sci. Technol.
  doi: 10.1021/es506016w
– volume: 12
  start-page: 1208
  year: 2017
  ident: C7GC03862C-(cit15)/*[position()=1]
  publication-title: Chem. – Asian J.
  doi: 10.1002/asia.201700160
– volume: 58
  start-page: 7250
  year: 2014
  ident: C7GC03862C-(cit25)/*[position()=1]
  publication-title: Antimicrob. Agents Chemother.
  doi: 10.1128/AAC.03728-14
– volume: 47
  start-page: 97
  year: 1991
  ident: C7GC03862C-(cit77)/*[position()=1]
  publication-title: Solid State Ionics
  doi: 10.1016/0167-2738(91)90186-F
– volume: 30
  start-page: 683
  year: 2009
  ident: C7GC03862C-(cit33)/*[position()=1]
  publication-title: Bull. Korean Chem. Soc.
  doi: 10.5012/bkcs.2009.30.12.3147
– volume: 4
  start-page: 6237
  year: 2016
  ident: C7GC03862C-(cit29)/*[position()=1]
  publication-title: ACS Sustainable Chem. Eng.
  doi: 10.1021/acssuschemeng.6b02226
– volume: 106
  start-page: 1007
  year: 2007
  ident: C7GC03862C-(cit12)/*[position()=1]
  publication-title: J. Appl. Polym. Sci.
  doi: 10.1002/app.26252
– volume: 5
  start-page: 5664
  year: 2015
  ident: C7GC03862C-(cit20)/*[position()=1]
  publication-title: RSC Adv.
  doi: 10.1039/C4RA13619E
– volume: 134
  start-page: 9601
  year: 2012
  ident: C7GC03862C-(cit11)/*[position()=1]
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja3042977
– volume: 424
  start-page: 15
  year: 2009
  ident: C7GC03862C-(cit8)/*[position()=1]
  publication-title: Dokl. Chem.
  doi: 10.1134/S0012500809010042
– volume: 65
  start-page: 1013
  year: 2016
  ident: C7GC03862C-(cit6)/*[position()=1]
  publication-title: Russ. Chem. Bull.
  doi: 10.1007/s11172-016-1405-0
– volume: 66
  start-page: 260
  year: 2017
  ident: C7GC03862C-(cit82)/*[position()=1]
  publication-title: Russ. Chem. Bull.
  doi: 10.1007/s11172-017-1726-7
– volume: 50
  start-page: 10708
  year: 2011
  ident: C7GC03862C-(cit22)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201104948
– volume: 81
  start-page: 6049
  year: 2016
  ident: C7GC03862C-(cit65)/*[position()=1]
  publication-title: J. Org. Chem.
  doi: 10.1021/acs.joc.6b01138
– volume: 376
  start-page: 165
  year: 1989
  ident: C7GC03862C-(cit36)/*[position()=1]
  publication-title: J. Organomet. Chem.
  doi: 10.1016/0022-328X(89)85131-9
– volume: 86
  start-page: 1859
  year: 2016
  ident: C7GC03862C-(cit26)/*[position()=1]
  publication-title: Russ. J. Gen. Chem.
  doi: 10.1134/S1070363216080144
– volume: 65
  start-page: 1104
  year: 2016
  ident: C7GC03862C-(cit2)/*[position()=1]
  publication-title: Russ. Chem. Bull.
  doi: 10.1007/s11172-016-1419-7
– volume: 11
  start-page: 237
  year: 1997
  ident: C7GC03862C-(cit76)/*[position()=1]
  publication-title: Appl. Organomet. Chem.
  doi: 10.1002/(SICI)1099-0739(199703)11:3<237::AID-AOC557>3.0.CO;2-4
– volume: 38
  start-page: 347
  year: 2012
  ident: C7GC03862C-(cit10)/*[position()=1]
  publication-title: Glass Phys. Chem.
  doi: 10.1134/S108765961203008X
– volume: 408
  start-page: 149
  year: 1991
  ident: C7GC03862C-(cit38)/*[position()=1]
  publication-title: J. Organomet. Chem.
  doi: 10.1016/0022-328X(91)86378-4
– volume: 5
  start-page: 1124
  year: 2016
  ident: C7GC03862C-(cit68)/*[position()=1]
  publication-title: ACS Macro Lett.
  doi: 10.1021/acsmacrolett.6b00529
– volume: 46
  start-page: 127
  year: 1997
  ident: C7GC03862C-(cit35)/*[position()=1]
  publication-title: Thin Solid Films
– volume: 270
  start-page: 275
  year: 1998
  ident: C7GC03862C-(cit72)/*[position()=1]
  publication-title: J. Alloys Compd.
  doi: 10.1016/S0925-8388(98)00527-1
– volume: 81
  start-page: 11514
  year: 2016
  ident: C7GC03862C-(cit63)/*[position()=1]
  publication-title: J. Org. Chem.
  doi: 10.1021/acs.joc.6b02197
– volume: 16
  start-page: 121
  year: 2014
  ident: C7GC03862C-(cit62)/*[position()=1]
  publication-title: Green Chem.
  doi: 10.1039/C3GC41370E
– volume: 78
  start-page: 764
  year: 2013
  ident: C7GC03862C-(cit16)/*[position()=1]
  publication-title: ChemPlusChem
  doi: 10.1002/cplu.201300027
– volume: 32
  start-page: 317
  year: 2006
  ident: C7GC03862C-(cit27)/*[position()=1]
  publication-title: Res. Chem. Intermed.
  doi: 10.1163/156856706777346462
– volume: 64
  start-page: 2498
  year: 2015
  ident: C7GC03862C-(cit7)/*[position()=1]
  publication-title: Russ. Chem. Bull.
  doi: 10.1007/s11172-015-1183-0
– volume: 75
  start-page: 1196
  year: 2002
  ident: C7GC03862C-(cit56)/*[position()=1]
  publication-title: Russ. J. Appl. Chem.
  doi: 10.1023/A:1020757522785
– volume: 15
  start-page: 617
  year: 2013
  ident: C7GC03862C-(cit64)/*[position()=1]
  publication-title: Green Chem.
  doi: 10.1039/c3gc36720g
– volume: 26
  start-page: 211
  year: 2013
  ident: C7GC03862C-(cit9)/*[position()=1]
  publication-title: Chem. Mater.
  doi: 10.1021/cm4023387
– volume: 53
  start-page: 3135
  year: 2012
  ident: C7GC03862C-(cit14)/*[position()=1]
  publication-title: Polymer
  doi: 10.1016/j.polymer.2012.05.033
– volume: 616
  start-page: 74
  year: 2000
  ident: C7GC03862C-(cit78)/*[position()=1]
  publication-title: J. Organomet. Chem.
  doi: 10.1016/S0022-328X(00)00543-X
SSID ssj0011764
Score 2.3990517
Snippet The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes by silicon mechanoactivation followed by a reaction...
SourceID proquest
crossref
rsc
SourceType Aggregation Database
Enrichment Source
Index Database
Publisher
StartPage 1962
SubjectTerms Abrasion
Alcohol
Alcohols
Alkoxysilanes
Catalysis
catalysts
Chemical synthesis
Comminution
energy-dispersive X-ray analysis
Green chemistry
grinding
mechanochemistry
milling
Oxide coatings
Photoelectron spectroscopy
Reactors
Scanning electron microscopy
Silicon
vibration
X ray photoelectron spectroscopy
X ray powder diffraction
X-ray diffraction
X-ray spectroscopy
Title Mechanochemistry - a new powerful green approach to the direct synthesis of alkoxysilanes
URI https://www.proquest.com/docview/2036334276
https://www.proquest.com/docview/2221003901
Volume 2
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LbxMxELbS9AAcKghEhBZkBBcULawf680eoxBaHq04pFLhEq0dO0RNdqu8VPFz-KWM9-VNFSTgskrstR15vnjG9sw3CL3ucc7j0Pge11R4PKKhJwmTHokJVwIM2kjbaOTzC3F2yT9dBVeNxq-a19JmLd-qn3vjSv5HqlAGcrVRsv8g2apTKIDPIF94goTh-VcyPtc2btfmvMqTtnW9bmxzhHdvbO4z6308tW41FXF4aWjmesyyFcC3gpEknl-ntyAz6_y6qpusmWdO142RhUcnGc-EO0osCSjsMfz0ToNlcUOQtTx159p6kcyu020eMXQ7W7hboX4yWwGGtgW7AQC0wtl36Fb92Ezzyq_xVs-dn-5nu5RPij7fL2Z29Iv6ucbOIswF8yyPYa6j6mV5kpFy5aY1gEa1VRhWFVrT6JYBaK-28JklW1XhVPkMdnbK6cTKU9FVHqBDClsR2kSH_eHo45fqroqEGUlZ9atLElwWvXOtd80et5c5WJaJZjKDZvQQHRU7EdzPYfUINXTSQvcGpdha6EGNq7KF2kMXEgnNCp2weoy-3UUh9nCMAYW4RCHOEIFLFOJ1igF3OEchrlCIU4N3UPgEXX4YjgZnXpGww1OchGuPy4AFhnFfiUgyX5M4CA3Mvoayni-14UpJw7UAG3gShyRSOjQB40LJQHAdsDZqJmminyLsT4xVJlwqKjnxTdyTQmoiAmKMppHpoDflfI5VwWZvk6rMx5lXBYvGg_B0kM39oINeVe_e5Bwue986KcUyLv40q7G9pmeM01B00MuqGmbTXqvBTKQbeIdSYkPcfdJBbRBnNYaT_rM_VRyj-xb7-ZneCWqulxv9HKzctXxRwOw3QHGuAQ
linkProvider Royal Society of Chemistry
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Mechanochemistry+-+a+new+powerful+green+approach+to+the+direct+synthesis+of+alkoxysilanes&rft.jtitle=Green+chemistry+%3A+an+international+journal+and+green+chemistry+resource+%3A+GC&rft.au=Temnikov%2C+Maxim+N&rft.au=Anisimov%2C+Anton+A&rft.au=Zhemchugov%2C+Pavel+V&rft.au=Kholodkov%2C+Dmitry+N&rft.date=2018&rft.issn=1463-9262&rft.eissn=1463-9270&rft.volume=2&rft.issue=9&rft.spage=1962&rft.epage=1969&rft_id=info:doi/10.1039%2Fc7gc03862c&rft.externalDocID=c7gc03862c
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1463-9262&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1463-9262&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1463-9262&client=summon