Phase separation of metastable CoCrFeNi high entropy alloy at intermediate temperatures

CoCrFeNi alloy is an exemplary stable base for high entropy alloys (HEAs), but its phase stability is still suspicious. Here, the CoCrFeNi HEA was firstly identified to be thermally metastable at 750°C. Composition decomposition occurred after annealed at 750°C for 800h. The minor addition of Al acc...

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Published inScripta materialia Vol. 126; pp. 15 - 19
Main Authors He, Feng, Wang, Zhijun, Wu, Qingfeng, Li, Junjie, Wang, Jincheng, Liu, C.T.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.01.2017
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Abstract CoCrFeNi alloy is an exemplary stable base for high entropy alloys (HEAs), but its phase stability is still suspicious. Here, the CoCrFeNi HEA was firstly identified to be thermally metastable at 750°C. Composition decomposition occurred after annealed at 750°C for 800h. The minor addition of Al accelerated the composition decomposition and a second fcc phase with a different lattice constant occurred in the long time annealed CoCrFeNiAl0.1 HEA. The CoCrFeNi HEA cannot be seen as stable alloys anymore and researchers should be very careful when using the current phase selection models to predict stability of HEAs at intermediate temperatures. Composition decompositon occurred in the CoCrFeNi high entropy alloy after annealed at 750°C for 800h (see (a, b)). The addition of Al accelerated the decomposition and a second fcc phase with different lattice precipitated from the CoCrFeNi base, as shown in (c and d). These results indicated that the CoCrFeNi high entropy alloy is a metastable solid solution. [Display omitted]
AbstractList CoCrFeNi alloy is an exemplary stable base for high entropy alloys (HEAs), but its phase stability is still suspicious. Here, the CoCrFeNi HEA was firstly identified to be thermally metastable at 750 degree C. Composition decomposition occurred after annealed at 750 degree C for 800h. The minor addition of Al accelerated the composition decomposition and a second fcc phase with a different lattice constant occurred in the long time annealed CoCrFeNiAl0.1 HEA. The CoCrFeNi HEA cannot be seen as stable alloys anymore and researchers should be very careful when using the current phase selection models to predict stability of HEAs at intermediate temperatures.
CoCrFeNi alloy is an exemplary stable base for high entropy alloys (HEAs), but its phase stability is still suspicious. Here, the CoCrFeNi HEA was firstly identified to be thermally metastable at 750°C. Composition decomposition occurred after annealed at 750°C for 800h. The minor addition of Al accelerated the composition decomposition and a second fcc phase with a different lattice constant occurred in the long time annealed CoCrFeNiAl0.1 HEA. The CoCrFeNi HEA cannot be seen as stable alloys anymore and researchers should be very careful when using the current phase selection models to predict stability of HEAs at intermediate temperatures. Composition decompositon occurred in the CoCrFeNi high entropy alloy after annealed at 750°C for 800h (see (a, b)). The addition of Al accelerated the decomposition and a second fcc phase with different lattice precipitated from the CoCrFeNi base, as shown in (c and d). These results indicated that the CoCrFeNi high entropy alloy is a metastable solid solution. [Display omitted]
Author Wang, Jincheng
Li, Junjie
He, Feng
Wu, Qingfeng
Liu, C.T.
Wang, Zhijun
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  organization: Center of Advanced Structural Materials, Department of Mechanical and Biomedical Engineering, College of Science and Engineering, City University of Hong Kong, Kowloon, Hong Kong, China
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Keywords High entropy alloys
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Snippet CoCrFeNi alloy is an exemplary stable base for high entropy alloys (HEAs), but its phase stability is still suspicious. Here, the CoCrFeNi HEA was firstly...
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SubjectTerms Annealing
Decomposition
Entropy
Face centered cubic lattice
Ferrous alloys
High entropy alloys
Lattice parameters
Phase separation
Phase stability
Stability
Superalloys
Title Phase separation of metastable CoCrFeNi high entropy alloy at intermediate temperatures
URI https://dx.doi.org/10.1016/j.scriptamat.2016.08.008
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Volume 126
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