Merging Organometallic Chemistry with Polyoxometalate Chemistry

• Published in: Chemistry : a European journal Vol. 6; no. 7; pp. 1184 - 1192
• Main Authors: Gouzerh, Pierre, Villanneau, Richard, Delmont, Renaud, Proust, Anna
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 03.04.2000; WILEY‐VCH Verlag
• Subjects: manganese; molybdenum; organometallic oxides; polyoxometalates; rhenium

A series of polyoxomolybdate‐incorporated organometallic complexes has been obtained by reaction of [MBr(CO)5] or solvated {M(CO)3}+ ions (M=Mn or Br) with (nBu4N)2[Mo2O7] in methanol, sometimes in the presence of triols of the type RC(CH2OH)3 (R=Me or CH2OH). Their molecular structures are related...