Terminally-crosslinked poly(ether sulfone) block copolymer, as a highly selective and stable polymer electrolyte membrane for DMFC applications
The terminally-crosslinked sulfonated poly(ether sulfone) block copolymer (SPES-b) was developed for use as a proton exchange membrane in DMFC applications. The properties of the membrane prepared from SPES-b were compared with those of its non-crosslinked counterpart (SPES-bn) and Nafion®-117. The...
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| Published in | International journal of hydrogen energy Vol. 38; no. 12; pp. 5084 - 5091 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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Kidlington
Elsevier Ltd
22.04.2013
Elsevier |
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| Abstract | The terminally-crosslinked sulfonated poly(ether sulfone) block copolymer (SPES-b) was developed for use as a proton exchange membrane in DMFC applications. The properties of the membrane prepared from SPES-b were compared with those of its non-crosslinked counterpart (SPES-bn) and Nafion®-117. The membrane displayed a well-defined morphology due to phase separation between the hydrophobic and hydrophilic ionic units in the SPES-b block copolymer. The terminally-crosslinked SPES-b membrane yielded a high proton conductivity of 0.09 S/cm and a low methanol permeability of 5.3 × 10−8 cm2/s at 20 °C, and the membrane displayed excellent dimensional, mechanical, hydrolytic, and oxidative stabilities.
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► Terminally-crosslinked sulfonated poly(ether sulfone) was prepared. ► High conductivity with low methanol permeability was obtained. ► Dimensional, mechanical, and oxidative stabilities were achieved. |
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| AbstractList | The terminally-crosslinked sulfonated poly(ether sulfone) block copolymer (SPES-b) was developed for use as a proton exchange membrane in DMFC applications. The properties of the membrane prepared from SPES-b were compared with those of its non-crosslinked counterpart (SPES-bn) and Nafion®-117. The membrane displayed a well-defined morphology due to phase separation between the hydrophobic and hydrophilic ionic units in the SPES-b block copolymer. The terminally-crosslinked SPES-b membrane yielded a high proton conductivity of 0.09 S/cm and a low methanol permeability of 5.3 × 10−8 cm2/s at 20 °C, and the membrane displayed excellent dimensional, mechanical, hydrolytic, and oxidative stabilities.
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► Terminally-crosslinked sulfonated poly(ether sulfone) was prepared. ► High conductivity with low methanol permeability was obtained. ► Dimensional, mechanical, and oxidative stabilities were achieved. |
| Author | Kim, Tae-Hyun Won, Mihee Thankamony, Roshni Lilly |
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| Keywords | Proton selectivity Direct methanol fuel cell Methanol crossover Terminally-crosslinked polymer Polymer electrolytes Hydrogen Membrane Fuel cell Methanol |
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| SubjectTerms | Alternative fuels. Production and utilization Applied sciences Direct methanol fuel cell Energy Exact sciences and technology Fuels Hydrogen Methanol crossover Proton selectivity Terminally-crosslinked polymer |
| Title | Terminally-crosslinked poly(ether sulfone) block copolymer, as a highly selective and stable polymer electrolyte membrane for DMFC applications |
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