Rotating ring-disc electrode (RRDE) investigation of borohydride electro-oxidation

• Published in: Journal of power sources Vol. 182; no. 1; pp. 106 - 111
• Main Authors: Krishnan, Palanichamy, Yang, Tae-Hyun, Advani, Suresh G., Prasad, Ajay K.
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 15.07.2008; Elsevier Sequoia
• Subjects: Applied sciences; Borohydride; Borohydrides; Chronoamperometry; Direct borohydride fuel cell; Discs; Disks; Electro-oxidation; Electrodes; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; Gold; Oxidation; Rotating; RRDE; Borohydride; Chronoamperometry; Electro-oxidation; RRDE; Direct borohydride fuel cell; Gold; Rotating ring; Stability; Hydrogen; Voltammetry; Oxidation; Direct borohydride fuel cell;Electro-oxidation;RRDE;Borohydride;Chronoamperometry; Hydroborates; Fuel cell; Anodic polarization
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2008.03.064

Rotating ring-disc electrode (RRDE) voltammetry is applied for the in situ determination of hydroxy borohydride (BH 3(OH) −) formation during borohydride (BH 4 −) electro-oxidation on a gold (Au) electrode in 6.0 M NaOH solution. The BH 3(OH) − is detected at the ring electrode due to its further oxidation to BH 2(OH) 2 − by maintaining its potential in the range of −0.800 to −0.600 V vs. normal hydrogen electrode (NHE) while oxidizing BH 4 − on the disc electrode. The study reveals that the generation of BH 3(OH) − increases if the anodic polarization of the disc electrode is increased. The RRDE ring-shielding experiments show that the electro-oxidation of BH 4 − occurs over a wide potential range of −0.500 to 0.400 V on the Au electrode under hydrodynamic conditions. Chronoamperometry is also used to study the BH 3(OH) − oxidation in the potential range of −0.800 to −0.600 V with 0.33 M NaBH 4 in three different buffer solutions of pH 10.2, 11.0 and 11.70, respectively. The chronoamperometric studies indicate that the formation and stability of BH 3(OH) − depends on the pH value.