Field‐Supported Single‐Molecule Magnets of Type [Co(bzimpy)X2]
Magnetic properties of pentacoordinate complexes of the type [Co(bzimpy)X2], X = Cl and Br, were investigated in DC and AC modes. The DC data shows sizeable zero‐field splitting for these complexes. The AC susceptibility data confirms slow magnetic relaxation at the applied DC field with two relaxat...
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| Published in | European journal of inorganic chemistry Vol. 2017; no. 13; pp. 1915 - 1922 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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| Abstract | Magnetic properties of pentacoordinate complexes of the type [Co(bzimpy)X2], X = Cl and Br, were investigated in DC and AC modes. The DC data shows sizeable zero‐field splitting for these complexes. The AC susceptibility data confirms slow magnetic relaxation at the applied DC field with two relaxation channels. The low‐frequency relaxation time is as slow as τLF ≈ 0.1–0.3 s for the Cl and Br complexes at T = 1.9 K.
Mononuclear pentacoordinate CoII complexes [Co(bzimpy)Cl2] and [Co(bzimpy)Br2] show a sizeable magnetic anisotropy. They display slow magnetic relaxation through two relaxation channels supported by the external magnetic field. The low‐frequency relaxation time is as slow as 0.1–0.3 s at T = 1.9 K. |
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| AbstractList | Magnetic properties of pentacoordinate complexes of the type [Co(bzimpy)X2], X = Cl and Br, were investigated in DC and AC modes. The DC data shows sizeable zero-field splitting for these complexes. The AC susceptibility data confirms slow magnetic relaxation at the applied DC field with two relaxation channels. The low-frequency relaxation time is as slow as τLF [asymptotically =] 0.1-0.3 s for the Cl and Br complexes at T = 1.9 K. Magnetic properties of pentacoordinate complexes of the type [Co(bzimpy)X2], X = Cl and Br, were investigated in DC and AC modes. The DC data shows sizeable zero‐field splitting for these complexes. The AC susceptibility data confirms slow magnetic relaxation at the applied DC field with two relaxation channels. The low‐frequency relaxation time is as slow as τLF ≈ 0.1–0.3 s for the Cl and Br complexes at T = 1.9 K. Mononuclear pentacoordinate CoII complexes [Co(bzimpy)Cl2] and [Co(bzimpy)Br2] show a sizeable magnetic anisotropy. They display slow magnetic relaxation through two relaxation channels supported by the external magnetic field. The low‐frequency relaxation time is as slow as 0.1–0.3 s at T = 1.9 K. Magnetic properties of pentacoordinate complexes of the type [Co(bzimpy)X sub(2)], X = Cl and Br, were investigated in DC and AC modes. The DC data shows sizeable zero-field splitting for these complexes. The AC susceptibility data confirms slow magnetic relaxation at the applied DC field with two relaxation channels. The low-frequency relaxation time is as slow as tau sub(LF) approximately 0.1-0.3 s for the Cl and Br complexes at T = 1.9 K. Mononuclear pentacoordinate Co super(II) complexes [Co(bzimpy)Cl sub(2)] and [Co(bzimpy)Br sub(2)] show a sizeable magnetic anisotropy. They display slow magnetic relaxation through two relaxation channels supported by the external magnetic field. The low-frequency relaxation time is as slow as 0.1-0.3 s at T = 1.9 K. Magnetic properties of pentacoordinate complexes of the type [Co(bzimpy)X 2 ], X = Cl and Br, were investigated in DC and AC modes. The DC data shows sizeable zero‐field splitting for these complexes. The AC susceptibility data confirms slow magnetic relaxation at the applied DC field with two relaxation channels. The low‐frequency relaxation time is as slow as τ LF ≈ 0.1–0.3 s for the Cl and Br complexes at T = 1.9 K. |
| Author | Boča, Roman Varga, Filip Titiš, Ján Rajnák, Cyril Moncoľ, Ján |
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| Snippet | Magnetic properties of pentacoordinate complexes of the type [Co(bzimpy)X2], X = Cl and Br, were investigated in DC and AC modes. The DC data shows sizeable... Magnetic properties of pentacoordinate complexes of the type [Co(bzimpy)X 2 ], X = Cl and Br, were investigated in DC and AC modes. The DC data shows sizeable... Magnetic properties of pentacoordinate complexes of the type [Co(bzimpy)X sub(2)], X = Cl and Br, were investigated in DC and AC modes. The DC data shows... |
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| StartPage | 1915 |
| SubjectTerms | Channels Cobalt Magnetic fields Magnetic permeability Magnetic properties Magnetic relaxation Magnets Pentacoordinate complexes Relaxation time Single‐molecule magnets Splitting Structure elucidation |
| Title | Field‐Supported Single‐Molecule Magnets of Type [Co(bzimpy)X2] |
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