Estimates of Internal Pressure and Molar Refraction of Imidazolium Based Ionic Liquids as a Function of Temperature

Estimates of the internal pressure ( ∂ U / ∂ V ) T of the ionic liquids (ILs) 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF 4 ], 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF 6 ], and 1-methyl-3-octylimidazolium tetrafluoroborate [OMIM][BF 4 ] were made from experimentally dete...

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Published in	Journal of solution chemistry Vol. 37; no. 2; pp. 203 - 214
Main Author	Kumar, Arvind
Format	Journal Article
Language	English
Published	Boston Springer US 01.02.2008 Springer
Subjects	Chemistry Chemistry and Materials Science Condensed Matter Physics Exact sciences and technology General and physical chemistry Geochemistry Industrial Chemistry/Chemical Engineering Inorganic Chemistry Oceanography Physical Chemistry Solutions Ionic liquids Speed of sound Density Refractive index Internal pressure Speed Speed of sound; Refractive index; Internal pressure Molar refraction Pressure Ionic liquid
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Abstract	Estimates of the internal pressure ( ∂ U / ∂ V ) T of the ionic liquids (ILs) 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF 4 ], 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF 6 ], and 1-methyl-3-octylimidazolium tetrafluoroborate [OMIM][BF 4 ] were made from experimentally determined densities and speeds of sound in the temperature range 283.15 to 343.15 K. Values ( ∂ U / ∂ V ) T for all the ILs studied are higher than those of water and molecular organic liquids. We also measured the refractive indices n D in the temperature range 288.15 to 343.15 K and estimated the molar refraction R M . Refractive indices of ILs were also higher than those of normal organic liquids but were comparable to those of long hydrocarbon chain organic solvents.
AbstractList	Estimates of the internal pressure ( ∂ U / ∂ V ) T of the ionic liquids (ILs) 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF 4 ], 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF 6 ], and 1-methyl-3-octylimidazolium tetrafluoroborate [OMIM][BF 4 ] were made from experimentally determined densities and speeds of sound in the temperature range 283.15 to 343.15 K. Values ( ∂ U / ∂ V ) T for all the ILs studied are higher than those of water and molecular organic liquids. We also measured the refractive indices n D in the temperature range 288.15 to 343.15 K and estimated the molar refraction R M . Refractive indices of ILs were also higher than those of normal organic liquids but were comparable to those of long hydrocarbon chain organic solvents. Estimates of the internal pressure ({partial differential} U/{partial differential} V) T of the ionic liquids (ILs) 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF4], 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF6], and 1-methyl-3-octylimidazolium tetrafluoroborate [OMIM][BF4] were made from experimentally determined densities and speeds of sound in the temperature range 283.15 to 343.15 K. Values ({partial differential} U/{partial differential} V) T for all the ILs studied are higher than those of water and molecular organic liquids. We also measured the refractive indices n D in the temperature range 288.15 to 343.15 K and estimated the molar refraction R M. Refractive indices of ILs were also higher than those of normal organic liquids but were comparable to those of long hydrocarbon chain organic solvents.
Author	Kumar, Arvind
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Keywords	Ionic liquids Speed of sound Density Refractive index Internal pressure Speed Speed of sound; Refractive index; Internal pressure Molar refraction Pressure Ionic liquid
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Snippet	Estimates of the internal pressure ( ∂ U / ∂ V ) T of the ionic liquids (ILs) 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF 4 ],... Estimates of the internal pressure ({partial differential} U/{partial differential} V) T of the ionic liquids (ILs) 1-butyl-3-methylimidazolium...
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Title	Estimates of Internal Pressure and Molar Refraction of Imidazolium Based Ionic Liquids as a Function of Temperature
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