Tunable Fluorene-Based Dynamers through Constitutional Dynamic Chemistry

• Published in: Chemistry : a European journal Vol. 12; no. 6; pp. 1723 - 1735
• Main Authors: Giuseppone, Nicolas, Fuks, Gad, Lehn, Jean-Marie
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 08.02.2006; WILEY‐VCH Verlag; Wiley; Wiley-VCH Verlag
• Subjects: Chemical Sciences; Chemistry; Chemistry, Multidisciplinary; dynamic combinatorial chemistry; molecular diversity; Physical Sciences; polymers; Science & Technology; stimuli-responsive systems; tunable functional materials; POLYFLUORENE DERIVATIVES; COVALENT; VIRTUAL COMBINATORIAL LIBRARIES; molecular diversity; SELF-ORGANIZATION; ELECTROLUMINESCENCE; EVOLUTION; CONJUGATED POLYMERS; COMPONENT EXCHANGE; dynamic combinatorial chemistry; stimuli-responsive systems; DIVERSITY; polymers; tunable functional materials; SELECTION

Dynamic covalent iminofluorene‐based oligomers and polymers have been generated. They undergo constitutional recomposition under the effect of two parameters, acidity and ZnII metal ions. As a result, marked changes in physical properties take place. The results illustrate the response of such a dyn...