Antifouling activity of marine paints: Study of erosion
It is generally agreed that the prevention of marine fouling can be achieved by coatings from which a controlled release of toxic molecules prevents the growth of adhered organisms (bacteria, algae, molluscs). Since the end of 1990s, antifouling paints have been made by the blending of polyacrylic r...
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Published in | Progress in organic coatings Vol. 60; no. 3; pp. 194 - 206 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Lausanne
Elsevier B.V
01.10.2007
Elsevier Sequoia |
Subjects | |
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Abstract | It is generally agreed that the prevention of marine fouling can be achieved by coatings from which a controlled release of toxic molecules prevents the growth of adhered organisms (bacteria, algae, molluscs). Since the end of 1990s, antifouling paints have been made by the blending of polyacrylic resins with biocides. The aim of this study was to use new polymers in order to obtain biodegradable antifouling paints with controlled release of biocide.
Polyesters, such as poly(ɛ-caprolactone), PCL, poly(lactide), PLA, and their copolymers have received much interest in environmental applications because of their biodegradability. Polyanhydrides have also been considered as useful carriers of active molecules. Two families of biodegradable binders were studied: poly(phtalic acid-
co-ricinoleic acid-
co-isophtalic acid ester anhydride) (P(PA-RA-IPA)) and poly(ɛ-caprolactone-
co-δ-valerolactone) (P(CL-VL)). Antifouling paints were formulated with these polymers and compared with commercial binders (PMMA-PBMA
+
rosin, and PMMA-TBT). Several methods have been used to investigate polymer erosion such as X-ray microanalysis (EDX), scanning electron microscopy (SEM), confocal laser scanning microscopy (CLSM), nanoindentation, and FTIR spectroscopy. We have demonstrated that the polymers undergo predominantly surface erosion for poly(ester-anhydride) and PMMA-TBT and bulk erosion for polyester and PMMA-PBMA
+
rosin. |
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AbstractList | It is generally agreed that the prevention of marine fouling can be achieved by coatings from which a controlled release of toxic molecules prevents the growth of adhered organisms (bacteria, algae, molluscs). Since the end of 1990s, antifouling paints have been made by the blending of polyacrylic resins with biocides. The aim of this study was to use new polymers in order to obtain biodegradable antifouling paints with controlled release of biocide. Polyesters, such as poly( approximately equal to -caprolactone), PCL, poly(lactide), PLA, and their copolymers have received much interest in environmental applications because of their biodegradability. Polyanhydrides have also been considered as useful carriers of active molecules. Two families of biodegradable binders were studied: poly(phtalic acid-co-ricinoleic acid-co-isophtalic acid ester anhydride) (P(PA-RA-IPA)) and poly( approximately equal to -caprolactone-co- delta -valerolactone) (P(CL-VL)). Antifouling paints were formulated with these polymers and compared with commercial binders (PMMA-PBMA+rosin, and PMMA-TBT). Several methods have been used to investigate polymer erosion such as X-ray microanalysis (EDX), scanning electron microscopy (SEM), confocal laser scanning microscopy (CLSM), nanoindentation, and FTIR spectroscopy. We have demonstrated that the polymers undergo predominantly surface erosion for poly(ester-anhydride) and PMMA-TBT and bulk erosion for polyester and PMMA-PBMA+rosin. It is generally agreed that the prevention of marine fouling can be achieved by coatings from which a controlled release of toxic molecules prevents the growth of adhered organisms (bacteria, algae, molluscs). Since the end of 1990s, antifouling paints have been made by the blending of polyacrylic resins with biocides. The aim of this study was to use new polymers in order to obtain biodegradable antifouling paints with controlled release of biocide. Polyesters, such as poly(ɛ-caprolactone), PCL, poly(lactide), PLA, and their copolymers have received much interest in environmental applications because of their biodegradability. Polyanhydrides have also been considered as useful carriers of active molecules. Two families of biodegradable binders were studied: poly(phtalic acid- co-ricinoleic acid- co-isophtalic acid ester anhydride) (P(PA-RA-IPA)) and poly(ɛ-caprolactone- co-δ-valerolactone) (P(CL-VL)). Antifouling paints were formulated with these polymers and compared with commercial binders (PMMA-PBMA + rosin, and PMMA-TBT). Several methods have been used to investigate polymer erosion such as X-ray microanalysis (EDX), scanning electron microscopy (SEM), confocal laser scanning microscopy (CLSM), nanoindentation, and FTIR spectroscopy. We have demonstrated that the polymers undergo predominantly surface erosion for poly(ester-anhydride) and PMMA-TBT and bulk erosion for polyester and PMMA-PBMA + rosin. |
Author | Linossier, Isabelle Vallée-Rehel, Karine Langlois, Valérie Faÿ, Fabienne Peron, Jean Jacques |
Author_xml | – sequence: 1 givenname: Fabienne surname: Faÿ fullname: Faÿ, Fabienne email: fabienne.fay@univ-ubs.fr organization: Laboratoire de Biotechnologie et Chimie Marine EA 3884, Université de Bretagne Sud, BP 92116, 56321 Lorient Cedex, France – sequence: 2 givenname: Isabelle surname: Linossier fullname: Linossier, Isabelle organization: Laboratoire de Biotechnologie et Chimie Marine EA 3884, Université de Bretagne Sud, BP 92116, 56321 Lorient Cedex, France – sequence: 3 givenname: Jean Jacques surname: Peron fullname: Peron, Jean Jacques organization: Laboratoire de Biotechnologie et Chimie Marine EA 3884, Université de Bretagne Sud, BP 92116, 56321 Lorient Cedex, France – sequence: 4 givenname: Valérie surname: Langlois fullname: Langlois, Valérie organization: Laboratoire de Recherche sur les Polymères UMR-CNRS 7581, 2-8 rue H Dunant, 94320 Thiais, France – sequence: 5 givenname: Karine surname: Vallée-Rehel fullname: Vallée-Rehel, Karine organization: Laboratoire de Biotechnologie et Chimie Marine EA 3884, Université de Bretagne Sud, BP 92116, 56321 Lorient Cedex, France |
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Keywords | Antifouling paint Microscopy Biodegradable polymer Biocide Controlled release Erosion Coating material Paint |
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Snippet | It is generally agreed that the prevention of marine fouling can be achieved by coatings from which a controlled release of toxic molecules prevents the growth... |
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SubjectTerms | Antifouling paint Applied sciences Biocide Biodegradable polymer Controlled release Erosion Exact sciences and technology Microscopy Mollusca Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts |
Title | Antifouling activity of marine paints: Study of erosion |
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