Characterization and optimization of waste-derived biodiesel utilizing CNT/MgO nanocomposite and water emulsion for enhanced performance and emission metrics
Efficiently managing agricultural plant residues is a growing concern, leading to a focus on converting waste materials into valuable resources. The Rutaceae family, especially Citrus maxima peel oil (CMPO), has potential for biofuel production, but research on its use remains limited, especially in...
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Published in | Case studies in thermal engineering Vol. 55; p. 104173 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier Ltd
01.03.2024
Elsevier |
Subjects | |
Online Access | Get full text |
ISSN | 2214-157X 2214-157X |
DOI | 10.1016/j.csite.2024.104173 |
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Abstract | Efficiently managing agricultural plant residues is a growing concern, leading to a focus on converting waste materials into valuable resources. The Rutaceae family, especially Citrus maxima peel oil (CMPO), has potential for biofuel production, but research on its use remains limited, especially in terms of fuel modification. This study aims to extract biofuel from Citrus maxima peel and characterize its chemical components. To enhance efficiency and align with environmental goals, the study suggests integrating water and a nanocomposite into CMPO. An eco-friendly method was employed to synthesize a carbon nanotube (CNT)-induced magnesium oxide (MgO) nanocomposite that was extensively characterized. Fuel combinations were derived using a Box-Behnken design matrix, and optimization followed, emphasizing performance and emission parameters. Analysis of the elemental composition and free fatty acid profile of extracted CMPO highlights its potential as an alternative fuel. Optimal concentrations of CMPO, water, and nanocomposite in diesel fuel were found to be 27.6%, 12.2%, and 64.9 ppm, respectively. Confirmation tests validated improved performance and emission outcomes under these optimal conditions. Projected performance and emission parameters closely align with experimental findings. The proposed fuel combination is expected to achieve a significant 40% reduction in the demand for petroleum derivatives.
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AbstractList | Efficiently managing agricultural plant residues is a growing concern, leading to a focus on converting waste materials into valuable resources. The Rutaceae family, especially Citrus maxima peel oil (CMPO), has potential for biofuel production, but research on its use remains limited, especially in terms of fuel modification. This study aims to extract biofuel from Citrus maxima peel and characterize its chemical components. To enhance efficiency and align with environmental goals, the study suggests integrating water and a nanocomposite into CMPO. An eco-friendly method was employed to synthesize a carbon nanotube (CNT)-induced magnesium oxide (MgO) nanocomposite that was extensively characterized. Fuel combinations were derived using a Box-Behnken design matrix, and optimization followed, emphasizing performance and emission parameters. Analysis of the elemental composition and free fatty acid profile of extracted CMPO highlights its potential as an alternative fuel. Optimal concentrations of CMPO, water, and nanocomposite in diesel fuel were found to be 27.6%, 12.2%, and 64.9 ppm, respectively. Confirmation tests validated improved performance and emission outcomes under these optimal conditions. Projected performance and emission parameters closely align with experimental findings. The proposed fuel combination is expected to achieve a significant 40% reduction in the demand for petroleum derivatives. Efficiently managing agricultural plant residues is a growing concern, leading to a focus on converting waste materials into valuable resources. The Rutaceae family, especially Citrus maxima peel oil (CMPO), has potential for biofuel production, but research on its use remains limited, especially in terms of fuel modification. This study aims to extract biofuel from Citrus maxima peel and characterize its chemical components. To enhance efficiency and align with environmental goals, the study suggests integrating water and a nanocomposite into CMPO. An eco-friendly method was employed to synthesize a carbon nanotube (CNT)-induced magnesium oxide (MgO) nanocomposite that was extensively characterized. Fuel combinations were derived using a Box-Behnken design matrix, and optimization followed, emphasizing performance and emission parameters. Analysis of the elemental composition and free fatty acid profile of extracted CMPO highlights its potential as an alternative fuel. Optimal concentrations of CMPO, water, and nanocomposite in diesel fuel were found to be 27.6%, 12.2%, and 64.9 ppm, respectively. Confirmation tests validated improved performance and emission outcomes under these optimal conditions. Projected performance and emission parameters closely align with experimental findings. The proposed fuel combination is expected to achieve a significant 40% reduction in the demand for petroleum derivatives. [Display omitted] |
ArticleNumber | 104173 |
Author | Kandasamy, Muralidharan Devarajan, Yuvarajan Ramalingam, Krishnamoorthy Chandran, Davannendran Vellaiyan, Suresh Raviadaran, Revathi |
Author_xml | – sequence: 1 givenname: Suresh orcidid: 0000-0003-0742-5557 surname: Vellaiyan fullname: Vellaiyan, Suresh email: suresh.vellaiyan@gmail.com organization: Department of Sustainable Engineering, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Chennai, Tamilnadu, India – sequence: 2 givenname: Muralidharan orcidid: 0000-0001-5539-4439 surname: Kandasamy fullname: Kandasamy, Muralidharan organization: Department of Mechanical Engineering, Sona College of Technology, Salem, Tamilnadu, India – sequence: 3 givenname: Davannendran orcidid: 0000-0002-8633-0435 surname: Chandran fullname: Chandran, Davannendran email: davannendran@utp.edu.my organization: Department of Mechanical Engineering, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak, Malaysia – sequence: 4 givenname: Revathi surname: Raviadaran fullname: Raviadaran, Revathi organization: HICoE-Centre for Biofuel and Biochemical Research, Institute of Self-Sustainable Building, Department of Chemical Engineering, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak Darul Ridzuan, Malaysia – sequence: 5 givenname: Krishnamoorthy surname: Ramalingam fullname: Ramalingam, Krishnamoorthy organization: Department of Mechanical Engineering, CK College of Engineering and Technology, Cuddalore, Tamilnadu, India – sequence: 6 givenname: Yuvarajan surname: Devarajan fullname: Devarajan, Yuvarajan organization: Department of Mechanical Engineering, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Chennai, Tamilnadu, India |
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Keywords | Water emulsion Composite nanoparticle Response surface methodology Performance and emission assessment Citrus maxima peel oil |
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Title | Characterization and optimization of waste-derived biodiesel utilizing CNT/MgO nanocomposite and water emulsion for enhanced performance and emission metrics |
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