Modifier coordination and phosphate glass networks
The addition of up to ∼16 mol% Cs 2O to vitreous P 2O 5 reduces the glass transition temperature ( T g) by 150 K, whereas further additions up to 60 mol% increases T g by ∼20 K. 31P magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectra indicate that the phosphate network is progressive...
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Published in | Journal of non-crystalline solids Vol. 274; no. 1; pp. 9 - 16 |
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Main Authors | , , |
Format | Journal Article Conference Proceeding |
Language | English |
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Elsevier B.V
2000
Elsevier |
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Abstract | The addition of up to ∼16 mol% Cs
2O to vitreous P
2O
5 reduces the glass transition temperature (
T
g) by 150 K, whereas further additions up to 60 mol% increases
T
g by ∼20 K.
31P magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectra indicate that the phosphate network is progressively depolymerized over the entire range of compositions. The property trend is explained by a transition in the Cs
+ coordination environment, from isolated Cs-polyhedra below ∼16 mol% Cs
2O to a corner-sharing Cs-polyhedral sub-structure in the glasses with greater Cs
2O contents. This ‘modifier transition’ does not occur in Al phosphate glasses.
27Al MAS NMR spectra indicate that the average Al coordination number decreases with increasing Al
2O
3 content to avoid the formation of Al–O–Al bonds in these binary phosphate glasses. |
---|---|
AbstractList | The addition of up to 16 mol% Cs2O to vitreous P2O5 reduces the Tg by 150 K, whereas further additions up to 60 mol% increases Tg by 20 K. 31P MAS NMR spectra indicate that the phosphate network is progressively depolymerized over the entire range of compositions. The property trend is explained by a transition in the Cs+ coordination environment, from isolated Cs polyhedra below 16 mol% Cs2O to a corner-sharing Cs polyhedral substructure in the glasses with greater Cs2O contents. This modifier transition does not occur in Al phosphate glasses. 27Al MAS NMR spectra indicate that the average Al coordination number decreases with increasing Al2O3 content to avoid the formation of Al-O-Al bonds in these binary phosphate glasses. 30 refs. The addition of up to ∼16 mol% Cs 2O to vitreous P 2O 5 reduces the glass transition temperature ( T g) by 150 K, whereas further additions up to 60 mol% increases T g by ∼20 K. 31P magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectra indicate that the phosphate network is progressively depolymerized over the entire range of compositions. The property trend is explained by a transition in the Cs + coordination environment, from isolated Cs-polyhedra below ∼16 mol% Cs 2O to a corner-sharing Cs-polyhedral sub-structure in the glasses with greater Cs 2O contents. This ‘modifier transition’ does not occur in Al phosphate glasses. 27Al MAS NMR spectra indicate that the average Al coordination number decreases with increasing Al 2O 3 content to avoid the formation of Al–O–Al bonds in these binary phosphate glasses. |
Author | Brow, R.K Click, C.A Alam, T.M |
Author_xml | – sequence: 1 givenname: R.K surname: Brow fullname: Brow, R.K email: brow@umr.edu organization: Ceramic Engineering Department, University of Missouri-Rolla, 222 McNutt Hall, Rolla, MO 65409, USA – sequence: 2 givenname: C.A surname: Click fullname: Click, C.A organization: Ceramic Engineering Department, University of Missouri-Rolla, 222 McNutt Hall, Rolla, MO 65409, USA – sequence: 3 givenname: T.M surname: Alam fullname: Alam, T.M organization: Organic Materials Department, Sandia National Laboratories, Albuquerque, NM 87185, USA |
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Keywords | M107 P147 G188 Network structure Coordination number Cesium oxides Ternary compounds Composition effect Binary systems Glass structure Phosphate glass Experimental study Structural models Magic angle NMR Sublattices Glass transformations Chemical bonds Aluminium oxides |
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Snippet | The addition of up to ∼16 mol% Cs
2O to vitreous P
2O
5 reduces the glass transition temperature (
T
g) by 150 K, whereas further additions up to 60 mol%... The addition of up to 16 mol% Cs2O to vitreous P2O5 reduces the Tg by 150 K, whereas further additions up to 60 mol% increases Tg by 20 K. 31P MAS NMR spectra... |
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SubjectTerms | Condensed matter: structure, mechanical and thermal properties Disordered solids Exact sciences and technology Glasses Physics Structure of solids and liquids; crystallography |
Title | Modifier coordination and phosphate glass networks |
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