A nanoscale qualitative study on the role of sodium hydrosulfide in oxidized carrollite flotation
The surface species transformation of oxidized carrollite processing with NaHS and KBX was investigated. Flotation and contact angle tests indicate that the combination of NaHS and KBX takes a better flotation performance than adding NaHS or KBX alone. Thermodynamic analysis, X-ray photoelectron spe...
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Published in | International journal of mining science and technology Vol. 31; no. 6; pp. 1085 - 1093 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
01.11.2021
Elsevier |
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Abstract | The surface species transformation of oxidized carrollite processing with NaHS and KBX was investigated. Flotation and contact angle tests indicate that the combination of NaHS and KBX takes a better flotation performance than adding NaHS or KBX alone. Thermodynamic analysis, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) results confirm the stronger chemisorption of KBX occurs on the oxidized carrollite surface with NaHS, which is beneficial to remove the cobalt oxides, thus contributing to the superior floatability. Interestingly, less elemental sulfur was observed on the carrollite surface as the interaction of NaHS and KBX than adding NaHS alone. It suggests that elemental sulfur is not the main contributor to the restored floatability of oxidized carrollite through sulfidisation. This study provided a new perspective to correlate the surface species with xanthate adsorption and oxidized carrollite flotation through determining the various intermediate products. |
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AbstractList | The surface species transformation of oxidized carrollite processing with NaHS and KBX was investigated. Flotation and contact angle tests indicate that the combination of NaHS and KBX takes a better flotation performance than adding NaHS or KBX alone. Thermodynamic analysis, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) results confirm the stronger chemisorption of KBX occurs on the oxidized carrollite surface with NaHS, which is beneficial to remove the cobalt oxides, thus contributing to the superior floatability. Interestingly, less elemental sulfur was observed on the carrollite surface as the interaction of NaHS and KBX than adding NaHS alone. It suggests that elemental sulfur is not the main contributor to the restored floatability of oxidized carrollite through sulfidisation. This study provided a new perspective to correlate the surface species with xanthate adsorption and oxidized carrollite flotation through determining the various intermediate products. |
Author | Ruan, Renman Zhang, Enpu Li, Li Niu, Xiaopeng Zhao, Haiping |
Author_xml | – sequence: 1 givenname: Haiping surname: Zhao fullname: Zhao, Haiping organization: CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China – sequence: 2 givenname: Renman surname: Ruan fullname: Ruan, Renman email: rmruan@ipe.ac.cn organization: CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China – sequence: 3 givenname: Xiaopeng surname: Niu fullname: Niu, Xiaopeng organization: CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China – sequence: 4 givenname: Li surname: Li fullname: Li, Li organization: CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China – sequence: 5 givenname: Enpu surname: Zhang fullname: Zhang, Enpu organization: Wanbao Mining LTD, Beijing 100053, China |
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Keywords | Chemisorption Oxidized carrollite Sodium hydrosulfide Potassium butyl xanthate Interaction Sulfidisation |
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