A nanoscale qualitative study on the role of sodium hydrosulfide in oxidized carrollite flotation

The surface species transformation of oxidized carrollite processing with NaHS and KBX was investigated. Flotation and contact angle tests indicate that the combination of NaHS and KBX takes a better flotation performance than adding NaHS or KBX alone. Thermodynamic analysis, X-ray photoelectron spe...

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Published inInternational journal of mining science and technology Vol. 31; no. 6; pp. 1085 - 1093
Main Authors Zhao, Haiping, Ruan, Renman, Niu, Xiaopeng, Li, Li, Zhang, Enpu
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.11.2021
Elsevier
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Abstract The surface species transformation of oxidized carrollite processing with NaHS and KBX was investigated. Flotation and contact angle tests indicate that the combination of NaHS and KBX takes a better flotation performance than adding NaHS or KBX alone. Thermodynamic analysis, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) results confirm the stronger chemisorption of KBX occurs on the oxidized carrollite surface with NaHS, which is beneficial to remove the cobalt oxides, thus contributing to the superior floatability. Interestingly, less elemental sulfur was observed on the carrollite surface as the interaction of NaHS and KBX than adding NaHS alone. It suggests that elemental sulfur is not the main contributor to the restored floatability of oxidized carrollite through sulfidisation. This study provided a new perspective to correlate the surface species with xanthate adsorption and oxidized carrollite flotation through determining the various intermediate products.
AbstractList The surface species transformation of oxidized carrollite processing with NaHS and KBX was investigated. Flotation and contact angle tests indicate that the combination of NaHS and KBX takes a better flotation performance than adding NaHS or KBX alone. Thermodynamic analysis, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) results confirm the stronger chemisorption of KBX occurs on the oxidized carrollite surface with NaHS, which is beneficial to remove the cobalt oxides, thus contributing to the superior floatability. Interestingly, less elemental sulfur was observed on the carrollite surface as the interaction of NaHS and KBX than adding NaHS alone. It suggests that elemental sulfur is not the main contributor to the restored floatability of oxidized carrollite through sulfidisation. This study provided a new perspective to correlate the surface species with xanthate adsorption and oxidized carrollite flotation through determining the various intermediate products.
Author Ruan, Renman
Zhang, Enpu
Li, Li
Niu, Xiaopeng
Zhao, Haiping
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Issue 6
Keywords Chemisorption
Oxidized carrollite
Sodium hydrosulfide
Potassium butyl xanthate
Interaction
Sulfidisation
Language English
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Snippet The surface species transformation of oxidized carrollite processing with NaHS and KBX was investigated. Flotation and contact angle tests indicate that the...
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SubjectTerms Chemisorption
Interaction
Oxidized carrollite
Potassium butyl xanthate
Sodium hydrosulfide
Sulfidisation
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Title A nanoscale qualitative study on the role of sodium hydrosulfide in oxidized carrollite flotation
URI https://dx.doi.org/10.1016/j.ijmst.2021.10.008
https://doaj.org/article/00b43e78d7b441f888b946e167604ee8
Volume 31
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