Development of strong and ductile metastable face-centered cubic single-phase high-entropy alloys
Face-centered cubic (fcc)-phase high-entropy alloys (HEAs) have attracted much academic interest, with the stacking fault energy (SFE) playing an important role in regulating their mechanical behaviors. Here, we revealed the principles for regulating both the elastic and plastic behaviors by composi...
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| Published in | Acta materialia Vol. 181; pp. 318 - 330 |
|---|---|
| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Ltd
01.12.2019
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Face-centered cubic (fcc)-phase high-entropy alloys (HEAs) have attracted much academic interest, with the stacking fault energy (SFE) playing an important role in regulating their mechanical behaviors. Here, we revealed the principles for regulating both the elastic and plastic behaviors by composition modification and Mo addition in an fcc-phase quaternary CoCrFeNi system with the assistance of ab initio and thermodynamics calculations. An increase in Co content and a decrease in Fe and Ni contents reduced the fcc phase stability and SFE, but enhanced the elastic modulus, anisotropy, and lattice friction stress. A minor substitution of Co by Mo increased the lattice constant, but decreased the SFE and elastic modulus. Based on these findings, we developed a series of strong and ductile metastable fcc-phase CoxCr25(FeNi)70-xMo5 (x = 30, 40, 50) HEAs with mechanical properties superior to those of the CoCrFeNi HEAs. The careful investigation revealed that the enhanced mechanical properties are due to the Mo-addition-induced strengthening accompanied with a low-SFE-induced restriction of planar behavior of dislocations, mechanical twinning, and strain-induced martensitic transformation. The findings shed light on the development of high-performance HEAs.
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| AbstractList | Face-centered cubic (fcc)-phase high-entropy alloys (HEAs) have attracted much academic interest, with the stacking fault energy (SFE) playing an important role in regulating their mechanical behaviors. Here, we revealed the principles for regulating both the elastic and plastic behaviors by composition modification and Mo addition in an fcc-phase quaternary CoCrFeNi system with the assistance of ab initio and thermodynamics calculations. An increase in Co content and a decrease in Fe and Ni contents reduced the fcc phase stability and SFE, but enhanced the elastic modulus, anisotropy, and lattice friction stress. A minor substitution of Co by Mo increased the lattice constant, but decreased the SFE and elastic modulus. Based on these findings, we developed a series of strong and ductile metastable fcc-phase CoxCr25(FeNi)(70-x)Mo-5 (x = 30, 40, 50) HEAs with mechanical properties superior to those of the CoCrFeNi HEM. The careful investigation revealed that the enhanced mechanical properties are due to the Mo-addition-induced strengthening accompanied with a low-SFE-induced restriction of planar behavior of dislocations, mechanical twinning, and strain-induced martensitic transformation. The findings shed light on the development of high-performance HEAs. Face-centered cubic (fcc)-phase high-entropy alloys (HEAs) have attracted much academic interest, with the stacking fault energy (SFE) playing an important role in regulating their mechanical behaviors. Here, we revealed the principles for regulating both the elastic and plastic behaviors by composition modification and Mo addition in an fcc-phase quaternary CoCrFeNi system with the assistance of ab initio and thermodynamics calculations. An increase in Co content and a decrease in Fe and Ni contents reduced the fcc phase stability and SFE, but enhanced the elastic modulus, anisotropy, and lattice friction stress. A minor substitution of Co by Mo increased the lattice constant, but decreased the SFE and elastic modulus. Based on these findings, we developed a series of strong and ductile metastable fcc-phase CoxCr25(FeNi)70-xMo5 (x = 30, 40, 50) HEAs with mechanical properties superior to those of the CoCrFeNi HEAs. The careful investigation revealed that the enhanced mechanical properties are due to the Mo-addition-induced strengthening accompanied with a low-SFE-induced restriction of planar behavior of dislocations, mechanical twinning, and strain-induced martensitic transformation. The findings shed light on the development of high-performance HEAs. [Display omitted] |
| Author | Jiang, Jing Li, Xiaoqing Wei, Daixiu Choi, Won-Mi Kato, Hidemi Schönecker, Stephan Lee, Byeong-Joo Kim, Hyoung Seop Chiba, Akihiko |
| Author_xml | – sequence: 1 givenname: Daixiu orcidid: 0000-0003-0264-462X surname: Wei fullname: Wei, Daixiu email: wei1987xiu@imr.tohoku.ac.jp organization: Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai, Miyagi 980-8577, Japan – sequence: 2 givenname: Xiaoqing surname: Li fullname: Li, Xiaoqing email: xiaoqli@kth.se organization: Department of Materials Science and Engineering, KTH - Royal Institute of Technology, 10044 Stockholm, Sweden – sequence: 3 givenname: Stephan surname: Schönecker fullname: Schönecker, Stephan organization: Department of Materials Science and Engineering, KTH - Royal Institute of Technology, 10044 Stockholm, Sweden – sequence: 4 givenname: Jing surname: Jiang fullname: Jiang, Jing organization: Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai, Miyagi 980-8577, Japan – sequence: 5 givenname: Won-Mi surname: Choi fullname: Choi, Won-Mi organization: Department of Materials Science and Engineering, Pohang University of Science and Technology (POSTEC), Pohang 37673, Republic of Korea – sequence: 6 givenname: Byeong-Joo orcidid: 0000-0001-6263-7996 surname: Lee fullname: Lee, Byeong-Joo organization: Department of Materials Science and Engineering, Pohang University of Science and Technology (POSTEC), Pohang 37673, Republic of Korea – sequence: 7 givenname: Hyoung Seop orcidid: 0000-0002-3155-583X surname: Kim fullname: Kim, Hyoung Seop organization: Department of Materials Science and Engineering, Pohang University of Science and Technology (POSTEC), Pohang 37673, Republic of Korea – sequence: 8 givenname: Akihiko surname: Chiba fullname: Chiba, Akihiko organization: Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai, Miyagi 980-8577, Japan – sequence: 9 givenname: Hidemi surname: Kato fullname: Kato, Hidemi organization: Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai, Miyagi 980-8577, Japan |
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| Snippet | Face-centered cubic (fcc)-phase high-entropy alloys (HEAs) have attracted much academic interest, with the stacking fault energy (SFE) playing an important... |
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| SubjectTerms | High-entropy alloy Martensitic transformation Metastable Stacking fault energy Twinning |
| Title | Development of strong and ductile metastable face-centered cubic single-phase high-entropy alloys |
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