Unraveling the mechanism of the one-pot synthesis of exchange coupled Co-based nano-heterostructures with a high energy product
The development of reproducible protocols to synthesize hard/soft nano-heterostructures (NHSs) with tailored magnetic properties is a crucial step to define their potential application in a variety of technological areas. Thermal decomposition has proved to be an effective tool to prepare such syste...
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| Published in | Nanoscale Vol. 12; no. 26; pp. 1476 - 1486 |
|---|---|
| Main Authors | , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
14.07.2020
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| Subjects | |
| Online Access | Get full text |
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| Abstract | The development of reproducible protocols to synthesize hard/soft nano-heterostructures (NHSs) with tailored magnetic properties is a crucial step to define their potential application in a variety of technological areas. Thermal decomposition has proved to be an effective tool to prepare such systems, but it has been scarcely used so far for the synthesis of Co-based metal/ferrite NHSs, despite their intriguing physical properties. We found a new approach to prepare this kind of nanomaterial based on a simple one-pot thermal decomposition reaction of metal-oleate precursors in the high boiling solvent docosane. The obtained NHSs are characterized by the coexistence of Co metal and Co doped magnetite and are highly stable in an air atmosphere, thanks to the passivation of the metal with a very thin oxide layer. The investigation of the influence of the metal precursor composition (a mixed iron-cobalt oleate), of the ligands (oleic acid and sodium oleate) and of the reaction time on the chemical and structural characteristics of the final product, allowed us to rationalize the reaction pathway and to determine the role of each parameter. In particular, the use of sodium oleate is crucial to obtain a metal phase in the NHSs. In such a way, the one-pot approach proposed here allows the fine control of the synthesis, leading to the formation of stable, high performant, metal/ferrite NHSs with tailored magnetic properties. For instance, the room temperature maximum energy product was increased up to 19 kJ m
−3
by tuning the Co content in the metal precursor.
Cobalt-based metal/metal ferrite nano-heterostructures with a high energy product were rationally synthesized through a one-pot thermal decomposition process. |
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| AbstractList | The development of reproducible protocols to synthesize hard/soft nano-heterostructures (NHSs) with tailored magnetic properties is a crucial step to define their potential application in a variety of technological areas. Thermal decomposition has proved to be an effective tool to prepare such systems, but it has been scarcely used so far for the synthesis of Co-based metal/ferrite NHSs, despite their intriguing physical properties. We found a new approach to prepare this kind of nanomaterial based on a simple one-pot thermal decomposition reaction of metal-oleate precursors in the high boiling solvent docosane. The obtained NHSs are characterized by the coexistence of Co metal and Co doped magnetite and are highly stable in an air atmosphere, thanks to the passivation of the metal with a very thin oxide layer. The investigation of the influence of the metal precursor composition (a mixed iron-cobalt oleate), of the ligands (oleic acid and sodium oleate) and of the reaction time on the chemical and structural characteristics of the final product, allowed us to rationalize the reaction pathway and to determine the role of each parameter. In particular, the use of sodium oleate is crucial to obtain a metal phase in the NHSs. In such a way, the one-pot approach proposed here allows the fine control of the synthesis, leading to the formation of stable, high performant, metal/ferrite NHSs with tailored magnetic properties. For instance, the room temperature maximum energy product was increased up to 19 kJ m
−3
by tuning the Co content in the metal precursor.
Cobalt-based metal/metal ferrite nano-heterostructures with a high energy product were rationally synthesized through a one-pot thermal decomposition process. The development of reproducible protocols to synthesize hard/soft nano-heterostructures (NHSs) with tailored magnetic properties is a crucial step to define their potential application in a variety of technological areas. Thermal decomposition has proved to be an effective tool to prepare such systems, but it has been scarcely used so far for the synthesis of Co-based metal/ferrite NHSs, despite their intriguing physical properties. We found a new approach to prepare this kind of nanomaterial based on a simple one-pot thermal decomposition reaction of metal-oleate precursors in the high boiling solvent docosane. The obtained NHSs are characterized by the coexistence of Co metal and Co doped magnetite and are highly stable in an air atmosphere, thanks to the passivation of the metal with a very thin oxide layer. The investigation of the influence of the metal precursor composition (a mixed iron–cobalt oleate), of the ligands (oleic acid and sodium oleate) and of the reaction time on the chemical and structural characteristics of the final product, allowed us to rationalize the reaction pathway and to determine the role of each parameter. In particular, the use of sodium oleate is crucial to obtain a metal phase in the NHSs. In such a way, the one-pot approach proposed here allows the fine control of the synthesis, leading to the formation of stable, high performant, metal/ferrite NHSs with tailored magnetic properties. For instance, the room temperature maximum energy product was increased up to 19 kJ m −3 by tuning the Co content in the metal precursor. The development of reproducible protocols to synthesize hard/soft nano-heterostructures (NHSs) with tailored magnetic properties is a crucial step to define their potential application in a variety of technological areas. Thermal decomposition has proved to be an effective tool to prepare such systems, but it has been scarcely used so far for the synthesis of Co-based metal/ferrite NHSs, despite their intriguing physical properties. We found a new approach to prepare this kind of nanomaterial based on a simple one-pot thermal decomposition reaction of metal-oleate precursors in the high boiling solvent docosane. The obtained NHSs are characterized by the coexistence of Co metal and Co doped magnetite and are highly stable in an air atmosphere, thanks to the passivation of the metal with a very thin oxide layer. The investigation of the influence of the metal precursor composition (a mixed iron–cobalt oleate), of the ligands (oleic acid and sodium oleate) and of the reaction time on the chemical and structural characteristics of the final product, allowed us to rationalize the reaction pathway and to determine the role of each parameter. In particular, the use of sodium oleate is crucial to obtain a metal phase in the NHSs. In such a way, the one-pot approach proposed here allows the fine control of the synthesis, leading to the formation of stable, high performant, metal/ferrite NHSs with tailored magnetic properties. For instance, the room temperature maximum energy product was increased up to 19 kJ m−3 by tuning the Co content in the metal precursor. The development of reproducible protocols to synthesize hard/soft nano-heterostructures (NHSs) with tailored magnetic properties is a crucial step to define their potential application in a variety of technological areas. Thermal decomposition has proved to be an effective tool to prepare such systems, but it has been scarcely used so far for the synthesis of Co-based metal/ferrite NHSs, despite their intriguing physical properties. We found a new approach to prepare this kind of nanomaterial based on a simple one-pot thermal decomposition reaction of metal-oleate precursors in the high boiling solvent docosane. The obtained NHSs are characterized by the coexistence of Co metal and Co doped magnetite and are highly stable in an air atmosphere, thanks to the passivation of the metal with a very thin oxide layer. The investigation of the influence of the metal precursor composition (a mixed iron-cobalt oleate), of the ligands (oleic acid and sodium oleate) and of the reaction time on the chemical and structural characteristics of the final product, allowed us to rationalize the reaction pathway and to determine the role of each parameter. In particular, the use of sodium oleate is crucial to obtain a metal phase in the NHSs. In such a way, the one-pot approach proposed here allows the fine control of the synthesis, leading to the formation of stable, high performant, metal/ferrite NHSs with tailored magnetic properties. For instance, the room temperature maximum energy product was increased up to 19 kJ m-3 by tuning the Co content in the metal precursor.The development of reproducible protocols to synthesize hard/soft nano-heterostructures (NHSs) with tailored magnetic properties is a crucial step to define their potential application in a variety of technological areas. Thermal decomposition has proved to be an effective tool to prepare such systems, but it has been scarcely used so far for the synthesis of Co-based metal/ferrite NHSs, despite their intriguing physical properties. We found a new approach to prepare this kind of nanomaterial based on a simple one-pot thermal decomposition reaction of metal-oleate precursors in the high boiling solvent docosane. The obtained NHSs are characterized by the coexistence of Co metal and Co doped magnetite and are highly stable in an air atmosphere, thanks to the passivation of the metal with a very thin oxide layer. The investigation of the influence of the metal precursor composition (a mixed iron-cobalt oleate), of the ligands (oleic acid and sodium oleate) and of the reaction time on the chemical and structural characteristics of the final product, allowed us to rationalize the reaction pathway and to determine the role of each parameter. In particular, the use of sodium oleate is crucial to obtain a metal phase in the NHSs. In such a way, the one-pot approach proposed here allows the fine control of the synthesis, leading to the formation of stable, high performant, metal/ferrite NHSs with tailored magnetic properties. For instance, the room temperature maximum energy product was increased up to 19 kJ m-3 by tuning the Co content in the metal precursor. |
| Author | Fernandez-Pacheco, Rodrigo Marquina, Clara Muzzi, Beatrice Innocenti, Claudia Ibarra, Alfonso Sangregorio, Claudio Cortigiani, Brunetto Fernández, César de Julián Petrecca, Michele Bertoni, Giovanni Ibarra, M. Ricardo Albino, Martin |
| AuthorAffiliation | ICCOM - CNR Dpto. de Física de la Materia Condensada University of Siena 1240 CNR - Istituto Nanoscienze Universidad de Zaragoza Laboratorio de Microscopias Avanzadas (LMA) Dept. of Biotechnology Chemistry and Pharmacy Dept. of Chemistry "U. Schiff" IMEM - CNR Instituto de Nanociencia de Aragón (INA) University of Florence and INSTM Instituto de Ciencia de Materiales de Aragón (ICMA) Consejo Superior de Investigaciones Científicas (CSIC)-Universidad de Zaragoza |
| AuthorAffiliation_xml | – name: Consejo Superior de Investigaciones Científicas (CSIC)-Universidad de Zaragoza – name: Dept. of Biotechnology – name: Laboratorio de Microscopias Avanzadas (LMA) – name: Chemistry and Pharmacy – name: University of Siena 1240 – name: ICCOM - CNR – name: Instituto de Ciencia de Materiales de Aragón (ICMA) – name: IMEM - CNR – name: Dpto. de Física de la Materia Condensada – name: Universidad de Zaragoza – name: Instituto de Nanociencia de Aragón (INA) – name: Dept. of Chemistry "U. Schiff" – name: CNR - Istituto Nanoscienze – name: University of Florence and INSTM |
| Author_xml | – sequence: 1 givenname: Beatrice surname: Muzzi fullname: Muzzi, Beatrice – sequence: 2 givenname: Martin surname: Albino fullname: Albino, Martin – sequence: 3 givenname: Claudia surname: Innocenti fullname: Innocenti, Claudia – sequence: 4 givenname: Michele surname: Petrecca fullname: Petrecca, Michele – sequence: 5 givenname: Brunetto surname: Cortigiani fullname: Cortigiani, Brunetto – sequence: 6 givenname: César de Julián surname: Fernández fullname: Fernández, César de Julián – sequence: 7 givenname: Giovanni surname: Bertoni fullname: Bertoni, Giovanni – sequence: 8 givenname: Rodrigo surname: Fernandez-Pacheco fullname: Fernandez-Pacheco, Rodrigo – sequence: 9 givenname: Alfonso surname: Ibarra fullname: Ibarra, Alfonso – sequence: 10 givenname: Clara surname: Marquina fullname: Marquina, Clara – sequence: 11 givenname: M. Ricardo surname: Ibarra fullname: Ibarra, M. Ricardo – sequence: 12 givenname: Claudio surname: Sangregorio fullname: Sangregorio, Claudio |
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| Cites_doi | 10.1103/PhysRevB.73.094406 10.1039/C6RA12072E 10.1021/cm502269s 10.1002/smll.201501382 10.2320/matertrans.M2012151 10.1051/anphys/192910120279 10.1039/C8NJ02177E 10.1002/pssa.2210960226 10.1002/chem.201702248 10.1039/c1cc13204k 10.1038/nature01208 10.1038/144327b0 10.1016/j.biomaterials.2014.04.063 10.1021/nl500904a 10.1103/PhysRevB.5.4709 10.1109/TMAG.2011.2157994 10.1021/acs.chemmater.6b00623 10.1021/jp982755m 10.1016/j.jmmm.2012.03.034 10.1063/1.1362333 10.1016/S0926-860X(03)00324-7 10.1109/20.102931 10.1016/j.ultramic.2008.01.004 10.1016/j.jmmm.2014.10.082 10.1039/C8CE00875B 10.1021/jp9051243 10.1021/ja0692478 10.1007/s10562-005-0002-x 10.1063/1.1392308 10.1016/j.ceramint.2016.01.044 10.1002/anie.200603148 10.1006/jcat.1999.2665 10.1002/aelm.201500365 10.1016/j.apsusc.2010.07.086 10.1016/j.jmmm.2007.02.040 10.1063/1.1984606 10.1021/jp300806j 10.1016/j.matlet.2009.12.036 10.1021/acs.chemmater.5b00944 10.1039/C5NR02969D 10.1021/acs.chemmater.5b01034 10.3390/nano8110881 10.1021/ja0708969 10.1111/jiec.12237 10.1063/1.4902351 10.1039/C4TC02889A 10.1021/acsnano.9b01281 10.1002/cmmi.1673 10.3762/bjnano.3.9 10.1002/adma.201002180 10.1021/ja074458d 10.1016/j.elspec.2015.02.006 10.1016/j.jmmm.2005.01.037 10.1016/j.apsusc.2014.02.006 10.1021/nn500454n 10.1103/PhysRev.102.1413 |
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| References | Sugimoto (D0NR01361G-(cit60)/*[position()=1]) 2001 Abellan (D0NR01361G-(cit36)/*[position()=1]) 1986; 96 Gutfleisch (D0NR01361G-(cit6)/*[position()=1]) 2011; 23 Zeng (D0NR01361G-(cit2)/*[position()=1]) 2002; 420 Bertoni (D0NR01361G-(cit30)/*[position()=1]) 2008; 108 Dobbrow (D0NR01361G-(cit45)/*[position()=1]) 2012; 3 Muro-Cruces (D0NR01361G-(cit57)/*[position()=1]) 2019; 13 Kneller (D0NR01361G-(cit3)/*[position()=1]) 1991; 27 Bao (D0NR01361G-(cit49)/*[position()=1]) 2007; 129 Verwey (D0NR01361G-(cit35)/*[position()=1]) 1939; 144 Luborsky (D0NR01361G-(cit42)/*[position()=1]) 1960; 31 Lottini (D0NR01361G-(cit50)/*[position()=1]) 2016; 28 Kovalenko (D0NR01361G-(cit51)/*[position()=1]) 2007; 129 Ghidini (D0NR01361G-(cit41)/*[position()=1]) 2007; 316 Leite (D0NR01361G-(cit43)/*[position()=1]) 2012; 324 Chen (D0NR01361G-(cit46)/*[position()=1]) 2015; 7 Wang (D0NR01361G-(cit55)/*[position()=1]) 2006; 107 Quesada (D0NR01361G-(cit26)/*[position()=1]) 2016; 2 Cotin (D0NR01361G-(cit27)/*[position()=1]) 2018; 8 Baaziz (D0NR01361G-(cit48)/*[position()=1]) 2014; 26 Chaubey (D0NR01361G-(cit16)/*[position()=1]) 2007; 129 Biesinger (D0NR01361G-(cit31)/*[position()=1]) 2010; 257 Pinna (D0NR01361G-(cit59)/*[position()=1]) 2008 Sort (D0NR01361G-(cit5)/*[position()=1]) 2001; 79 Zhou (D0NR01361G-(cit21)/*[position()=1]) 2014; 35 King (D0NR01361G-(cit8)/*[position()=1]) 2016; 50 Kemp (D0NR01361G-(cit58)/*[position()=1]) 2016; 6 Coey (D0NR01361G-(cit7)/*[position()=1]) 2010 Moya (D0NR01361G-(cit47)/*[position()=1]) 2015; 3 Zhao (D0NR01361G-(cit18)/*[position()=1]) 2010; 64 Jimenez-Villacorta (D0NR01361G-(cit4)/*[position()=1]) 2014 Kang (D0NR01361G-(cit54)/*[position()=1]) 2003; 251 Aslibeiki (D0NR01361G-(cit17)/*[position()=1]) 2016; 42 Jung (D0NR01361G-(cit23)/*[position()=1]) 2015; 11 Pugh (D0NR01361G-(cit38)/*[position()=1]) 2011; 47 Fantechi (D0NR01361G-(cit12)/*[position()=1]) 2015; 380 Wang (D0NR01361G-(cit52)/*[position()=1]) 2009 Meiklejohn (D0NR01361G-(cit1)/*[position()=1]) 1956; 102 Fantechi (D0NR01361G-(cit24)/*[position()=1]) 2014; 8 Baaziz (D0NR01361G-(cit28)/*[position()=1]) 2018; 20 Shirley (D0NR01361G-(cit29)/*[position()=1]) 1972; 5 Zhou (D0NR01361G-(cit53)/*[position()=1]) 2015; 27 Asti (D0NR01361G-(cit40)/*[position()=1]) 2006; 73 Wang (D0NR01361G-(cit32)/*[position()=1]) 2012; 53 Wilson (D0NR01361G-(cit33)/*[position()=1]) 2014; 303 Thormählen (D0NR01361G-(cit56)/*[position()=1]) 1999; 188 Fantechi (D0NR01361G-(cit13)/*[position()=1]) 2012; 116 Petit (D0NR01361G-(cit14)/*[position()=1]) 1999; 103 Quesada (D0NR01361G-(cit19)/*[position()=1]) 2014; 105 Park (D0NR01361G-(cit61)/*[position()=1]) 2007; 46 Aghavnian (D0NR01361G-(cit34)/*[position()=1]) 2016; 202 Nassar (D0NR01361G-(cit9)/*[position()=1]) 2015; 19 Wu (D0NR01361G-(cit22)/*[position()=1]) 2014; 14 López-Ortega (D0NR01361G-(cit11)/*[position()=1]) 2015; 27 Nakhjavan (D0NR01361G-(cit20)/*[position()=1]) 2011; 47 Orlando (D0NR01361G-(cit37)/*[position()=1]) 2016; 11 Kumar (D0NR01361G-(cit44)/*[position()=1]) 2018; 42 Puntes (D0NR01361G-(cit15)/*[position()=1]) 2001; 78 Ortega (D0NR01361G-(cit25)/*[position()=1]) 2017; 23 Bao (D0NR01361G-(cit39)/*[position()=1]) 2005; 293 Weiss (D0NR01361G-(cit10)/*[position()=1]) 1929; 10 |
| References_xml | – issn: 2016 issue: 50 end-page: 19-46 publication-title: Handbook on the Physics and Chemistry of Rare Earths doi: King Eggert Gschneidner – issn: 2010 publication-title: Magnetism and Magnetic Materials doi: Coey – issn: 2014 end-page: 160-189 publication-title: Nanomagnetism doi: Jimenez-Villacorta Lewis – issn: 2001 publication-title: Monodispersed Particles doi: Sugimoto – issn: 2008 publication-title: Advanced Wet-Chemical Synthetic Approaches to Inorganic Nanostructures doi: Pinna Kamaoui – volume: 73 start-page: 094406 year: 2006 ident: D0NR01361G-(cit40)/*[position()=1] publication-title: Phys. Rev. B: Condens. Matter Mater. Phys. doi: 10.1103/PhysRevB.73.094406 – volume: 6 start-page: 77452 year: 2016 ident: D0NR01361G-(cit58)/*[position()=1] publication-title: RSC Adv. doi: 10.1039/C6RA12072E – volume: 26 start-page: 5063 year: 2014 ident: D0NR01361G-(cit48)/*[position()=1] publication-title: Chem. Mater. doi: 10.1021/cm502269s – volume: 11 start-page: 4976 year: 2015 ident: D0NR01361G-(cit23)/*[position()=1] publication-title: Small doi: 10.1002/smll.201501382 – volume: 53 start-page: 1586 year: 2012 ident: D0NR01361G-(cit32)/*[position()=1] publication-title: Mater. Trans. doi: 10.2320/matertrans.M2012151 – volume: 10 start-page: 279 year: 1929 ident: D0NR01361G-(cit10)/*[position()=1] publication-title: Ann. Phys. doi: 10.1051/anphys/192910120279 – volume: 42 start-page: 15793 year: 2018 ident: D0NR01361G-(cit44)/*[position()=1] publication-title: New J. Chem. doi: 10.1039/C8NJ02177E – volume: 96 start-page: 581 year: 1986 ident: D0NR01361G-(cit36)/*[position()=1] publication-title: Phys. Status Solidi doi: 10.1002/pssa.2210960226 – volume: 23 start-page: 12443 year: 2017 ident: D0NR01361G-(cit25)/*[position()=1] publication-title: Chem. – Eur. J. doi: 10.1002/chem.201702248 – volume: 47 start-page: 8898 year: 2011 ident: D0NR01361G-(cit20)/*[position()=1] publication-title: Chem. Commun. doi: 10.1039/c1cc13204k – volume: 420 start-page: 395 year: 2002 ident: D0NR01361G-(cit2)/*[position()=1] publication-title: Nature doi: 10.1038/nature01208 – volume: 144 start-page: 327 year: 1939 ident: D0NR01361G-(cit35)/*[position()=1] publication-title: Nature doi: 10.1038/144327b0 – volume: 35 start-page: 7470 year: 2014 ident: D0NR01361G-(cit21)/*[position()=1] publication-title: Biomaterials doi: 10.1016/j.biomaterials.2014.04.063 – volume: 14 start-page: 3395 year: 2014 ident: D0NR01361G-(cit22)/*[position()=1] publication-title: Nano Lett. doi: 10.1021/nl500904a – volume: 5 start-page: 4709 year: 1972 ident: D0NR01361G-(cit29)/*[position()=1] publication-title: Phys. Rev. B: Solid State doi: 10.1103/PhysRevB.5.4709 – volume: 47 start-page: 4100 year: 2011 ident: D0NR01361G-(cit38)/*[position()=1] publication-title: IEEE Trans. Magn. doi: 10.1109/TMAG.2011.2157994 – volume: 28 start-page: 4214 year: 2016 ident: D0NR01361G-(cit50)/*[position()=1] publication-title: Chem. Mater. doi: 10.1021/acs.chemmater.6b00623 – volume: 103 start-page: 1805 year: 1999 ident: D0NR01361G-(cit14)/*[position()=1] publication-title: J. Phys. Chem. B doi: 10.1021/jp982755m – volume: 324 start-page: 2711 year: 2012 ident: D0NR01361G-(cit43)/*[position()=1] publication-title: J. Magn. Magn. Mater. doi: 10.1016/j.jmmm.2012.03.034 – volume: 78 start-page: 2187 year: 2001 ident: D0NR01361G-(cit15)/*[position()=1] publication-title: Appl. Phys. Lett. doi: 10.1063/1.1362333 – volume-title: Nanomagnetism year: 2014 ident: D0NR01361G-(cit4)/*[position()=1] – volume: 251 start-page: 143 year: 2003 ident: D0NR01361G-(cit54)/*[position()=1] publication-title: Appl. Catal., A doi: 10.1016/S0926-860X(03)00324-7 – volume-title: Magnetism and Magnetic Materials year: 2010 ident: D0NR01361G-(cit7)/*[position()=1] – volume: 27 start-page: 3588 year: 1991 ident: D0NR01361G-(cit3)/*[position()=1] publication-title: IEEE Trans. Magn. doi: 10.1109/20.102931 – volume: 108 start-page: 782 year: 2008 ident: D0NR01361G-(cit30)/*[position()=1] publication-title: Ultramicroscopy doi: 10.1016/j.ultramic.2008.01.004 – volume: 380 start-page: 365 year: 2015 ident: D0NR01361G-(cit12)/*[position()=1] publication-title: J. Magn. Magn. Mater. doi: 10.1016/j.jmmm.2014.10.082 – volume: 20 start-page: 7206 year: 2018 ident: D0NR01361G-(cit28)/*[position()=1] publication-title: CrystEngComm doi: 10.1039/C8CE00875B – start-page: 15914 year: 2009 ident: D0NR01361G-(cit52)/*[position()=1] publication-title: J. Phys. Chem. C doi: 10.1021/jp9051243 – volume: 129 start-page: 6352 year: 2007 ident: D0NR01361G-(cit51)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0692478 – volume: 107 start-page: 223 year: 2006 ident: D0NR01361G-(cit55)/*[position()=1] publication-title: Catal. Lett. doi: 10.1007/s10562-005-0002-x – volume: 79 start-page: 1142 year: 2001 ident: D0NR01361G-(cit5)/*[position()=1] publication-title: Appl. Phys. Lett. doi: 10.1063/1.1392308 – volume: 42 start-page: 6413 year: 2016 ident: D0NR01361G-(cit17)/*[position()=1] publication-title: Ceram. Int. doi: 10.1016/j.ceramint.2016.01.044 – volume: 46 start-page: 4630 year: 2007 ident: D0NR01361G-(cit61)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200603148 – volume: 188 start-page: 300 year: 1999 ident: D0NR01361G-(cit56)/*[position()=1] publication-title: J. Catal. doi: 10.1006/jcat.1999.2665 – volume: 2 start-page: 1500365 year: 2016 ident: D0NR01361G-(cit26)/*[position()=1] publication-title: Adv. Electron. Mater. doi: 10.1002/aelm.201500365 – volume: 257 start-page: 887 year: 2010 ident: D0NR01361G-(cit31)/*[position()=1] publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2010.07.086 – volume: 316 start-page: 159 year: 2007 ident: D0NR01361G-(cit41)/*[position()=1] publication-title: J. Magn. Magn. Mater. doi: 10.1016/j.jmmm.2007.02.040 – volume: 31 start-page: S68 year: 1960 ident: D0NR01361G-(cit42)/*[position()=1] publication-title: J. Appl. Phys. doi: 10.1063/1.1984606 – volume: 116 start-page: 8261 year: 2012 ident: D0NR01361G-(cit13)/*[position()=1] publication-title: J. Phys. Chem. C doi: 10.1021/jp300806j – volume: 64 start-page: 677 year: 2010 ident: D0NR01361G-(cit18)/*[position()=1] publication-title: Mater. Lett. doi: 10.1016/j.matlet.2009.12.036 – volume: 27 start-page: 3505 year: 2015 ident: D0NR01361G-(cit53)/*[position()=1] publication-title: Chem. Mater. doi: 10.1021/acs.chemmater.5b00944 – volume: 7 start-page: 14332 year: 2015 ident: D0NR01361G-(cit46)/*[position()=1] publication-title: Nanoscale doi: 10.1039/C5NR02969D – volume: 50 volume-title: Handbook on the Physics and Chemistry of Rare Earths year: 2016 ident: D0NR01361G-(cit8)/*[position()=1] – volume: 27 start-page: 4048 year: 2015 ident: D0NR01361G-(cit11)/*[position()=1] publication-title: Chem. Mater. doi: 10.1021/acs.chemmater.5b01034 – volume: 8 start-page: 881 year: 2018 ident: D0NR01361G-(cit27)/*[position()=1] publication-title: Nanomaterials doi: 10.3390/nano8110881 – volume: 129 start-page: 7214 year: 2007 ident: D0NR01361G-(cit16)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0708969 – volume: 19 start-page: 1044 year: 2015 ident: D0NR01361G-(cit9)/*[position()=1] publication-title: J. Ind. Ecol. doi: 10.1111/jiec.12237 – volume: 105 start-page: 202405 year: 2014 ident: D0NR01361G-(cit19)/*[position()=1] publication-title: Appl. Phys. Lett. doi: 10.1063/1.4902351 – volume: 3 start-page: 4522 year: 2015 ident: D0NR01361G-(cit47)/*[position()=1] publication-title: J. Mater. Chem. C doi: 10.1039/C4TC02889A – volume: 13 start-page: 7716 year: 2019 ident: D0NR01361G-(cit57)/*[position()=1] publication-title: ACS Nano doi: 10.1021/acsnano.9b01281 – volume: 11 start-page: 139 year: 2016 ident: D0NR01361G-(cit37)/*[position()=1] publication-title: Contrast Media Mol. Imaging doi: 10.1002/cmmi.1673 – volume: 3 start-page: 75 year: 2012 ident: D0NR01361G-(cit45)/*[position()=1] publication-title: Beilstein J. Nanotechnol. doi: 10.3762/bjnano.3.9 – volume: 23 start-page: 821 year: 2011 ident: D0NR01361G-(cit6)/*[position()=1] publication-title: Adv. Mater. doi: 10.1002/adma.201002180 – volume: 129 start-page: 12374 year: 2007 ident: D0NR01361G-(cit49)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja074458d – volume: 202 start-page: 16 year: 2016 ident: D0NR01361G-(cit34)/*[position()=1] publication-title: J. Electron Spectrosc. Relat. Phenom. doi: 10.1016/j.elspec.2015.02.006 – volume: 293 start-page: 15 year: 2005 ident: D0NR01361G-(cit39)/*[position()=1] publication-title: J. Magn. Magn. Mater. doi: 10.1016/j.jmmm.2005.01.037 – volume-title: Monodispersed Particles year: 2001 ident: D0NR01361G-(cit60)/*[position()=1] – volume-title: Advanced Wet-Chemical Synthetic Approaches to Inorganic Nanostructures year: 2008 ident: D0NR01361G-(cit59)/*[position()=1] – volume: 303 start-page: 6 year: 2014 ident: D0NR01361G-(cit33)/*[position()=1] publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2014.02.006 – volume: 8 start-page: 4705 year: 2014 ident: D0NR01361G-(cit24)/*[position()=1] publication-title: ACS Nano doi: 10.1021/nn500454n – volume: 102 start-page: 1413 year: 1956 ident: D0NR01361G-(cit1)/*[position()=1] publication-title: Phys. Rev. doi: 10.1103/PhysRev.102.1413 |
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| Snippet | The development of reproducible protocols to synthesize hard/soft nano-heterostructures (NHSs) with tailored magnetic properties is a crucial step to define... |
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| SubjectTerms | Decomposition reactions Eels Ferrites Heterostructures Magnetic measurement Magnetic properties Nanomaterials Oleic acid Physical properties Precursors Reaction time Room temperature Synthesis System effectiveness Thermal decomposition |
| Title | Unraveling the mechanism of the one-pot synthesis of exchange coupled Co-based nano-heterostructures with a high energy product |
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