Modeling for design and operation of high-pressure membrane contactors in natural gas sweetening

• Published in: Chemical engineering research & design Vol. 132; pp. 1005 - 1019
• Main Authors: Quek, Ven Chian, Shah, Nilay, Chachuat, Benoît
• Format: Journal Article
• Language: English
• Published: Rugby Elsevier B.V 01.04.2018; Elsevier Science Ltd
• Subjects: Absorbers (equipment); Absorption; Carbon dioxide; Contactors; Energy consumption; Experimental validation; Fluxes; Fossil fuels; Heat of reaction; High-pressure operation; Hollow fiber membranes; Mass transfer; Mathematical models; Membrane contactor; Membrane partial wetting; Membrane reactors; Methane; Model testing; Model-based analysis; Natural gas; Natural gas sweetening; Parametric analysis; Predictions; Size distribution; Natural gas sweetening; Model-based analysis; Experimental validation; Membrane contactor; Membrane partial wetting; High-pressure operation
• ISSN: 0263-8762; 1744-3563
• DOI: 10.1016/j.cherd.2018.01.033

•Development of a mathematical model for quantitative predictions in high-pressure contactors under partial wetting.•Prediction of the degree of membrane wetting using the pore-size distribution.•Experimental verification of the model with both lab-scale and pilot-scale plant data.•Model-based assessment of module orientation on high-pressure MBC performance. Over the past decade, membrane contactors (MBC) for CO2 absorption have been widely recognized for their large intensification potential compared to conventional absorption towers. MBC technology uses microporous hollow-fiber membranes to enable effective gas and liquid mass transfer, without the two phases dispersing into each other. The main contribution of this paper is the development and verification of a predictive mathematical model of high-pressure MBC for natural gas sweetening applications, based on which model-based parametric analysis and optimization can be conducted. The model builds upon insight from previous modeling studies by combining 1-d and 2-d mass-balance equations to predict the CO2 absorption flux, whereby the degree of membrane wetting itself is calculated from the knowledge of the membrane pore-size distribution. The predictive capability of the model is tested for both lab-scale and pilot-scale MBC modules, showing a close agreement of the predictions with measured CO2 absorption fluxes at various gas and liquid flowrates, subject to a temperature correction to account for the heat of reaction in the liquid phase. The results of a model-based analysis confirm the advantages of pressurized MBC operation in terms of CO2 removal efficiency. Finally, a comparison between vertical and horizontal modes of operation shows that the CO2 removal efficiency in the latter can be vastly superior as it is not subject to the liquid static head and remediation strategies are discussed.