Germatranes and carbagermatranes: (hetero)aryl and alkyl coupling partners in Pd-catalyzed cross-coupling reactions

• Published in: Chemical communications (Cambridge, England) Vol. 57; no. 89; pp. 11764 - 11775
• Main Authors: Xu, Meng-Yu, Xiao, Bin
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 09.11.2021
• Subjects: Aromatic compounds; Chemical reactions; Couplings; Cross coupling; cross-coupling reactions; derivatization; Germanium; Lewis bases; Nucleophiles; Organometallic compounds; Palladium; Reagents

In the past few decades, palladium-catalyzed cross-coupling reactions have taken root in the construction of a complex synthetic community. The development of organometallics has been an important objective in this field. Our group has focused on exploiting new germanium-based reagents and the corre...