Metal telluride nanosheets by scalable solid lithiation and exfoliation
Transition metal tellurides (TMTs) have been ideal materials for exploring exotic properties in condensed-matter physics, chemistry and materials science 1 – 3 . Although TMT nanosheets have been produced by top-down exfoliation, their scale is below the gram level and requires a long processing tim...
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| Published in | Nature (London) Vol. 628; no. 8007; pp. 313 - 319 |
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| Main Authors | , , , , , , , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
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London
Nature Publishing Group UK
11.04.2024
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0028-0836 1476-4687 1476-4687 |
| DOI | 10.1038/s41586-024-07209-2 |
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| Abstract | Transition metal tellurides (TMTs) have been ideal materials for exploring exotic properties in condensed-matter physics, chemistry and materials science
1
–
3
. Although TMT nanosheets have been produced by top-down exfoliation, their scale is below the gram level and requires a long processing time, restricting their effective application from laboratory to market
4
–
8
. We report the fast and scalable synthesis of a wide variety of MTe
2
(M = Nb, Mo, W, Ta, Ti) nanosheets by the solid lithiation of bulk MTe
2
within 10 min and their subsequent hydrolysis within seconds. Using NbTe
2
as a representative, we produced more than a hundred grams (108 g) of NbTe
2
nanosheets with 3.2 nm mean thickness, 6.2 µm mean lateral size and a high yield (>80%). Several interesting quantum phenomena, such as quantum oscillations and giant magnetoresistance, were observed that are generally restricted to highly crystalline MTe
2
nanosheets. The TMT nanosheets also perform well as electrocatalysts for lithium–oxygen batteries and electrodes for microsupercapacitors (MSCs). Moreover, this synthesis method is efficient for preparing alloyed telluride, selenide and sulfide nanosheets. Our work opens new opportunities for the universal and scalable synthesis of TMT nanosheets for exploring new quantum phenomena, potential applications and commercialization.
Fast and scalable synthesis of a variety of transition metal telluride nanosheets by solid lithiation and hydrolysis is demonstrated and several interesting quantum phenomena were observed, such as quantum oscillations and giant magnetoresistance. |
|---|---|
| AbstractList | Transition metal tellurides (TMTs) have been ideal materials for exploring exotic properties in condensed-matter physics, chemistry and materials science
. Although TMT nanosheets have been produced by top-down exfoliation, their scale is below the gram level and requires a long processing time, restricting their effective application from laboratory to market
. We report the fast and scalable synthesis of a wide variety of MTe
(M = Nb, Mo, W, Ta, Ti) nanosheets by the solid lithiation of bulk MTe
within 10 min and their subsequent hydrolysis within seconds. Using NbTe
as a representative, we produced more than a hundred grams (108 g) of NbTe
nanosheets with 3.2 nm mean thickness, 6.2 µm mean lateral size and a high yield (>80%). Several interesting quantum phenomena, such as quantum oscillations and giant magnetoresistance, were observed that are generally restricted to highly crystalline MTe
nanosheets. The TMT nanosheets also perform well as electrocatalysts for lithium-oxygen batteries and electrodes for microsupercapacitors (MSCs). Moreover, this synthesis method is efficient for preparing alloyed telluride, selenide and sulfide nanosheets. Our work opens new opportunities for the universal and scalable synthesis of TMT nanosheets for exploring new quantum phenomena, potential applications and commercialization. Transition metal tellurides (TMTs) have been ideal materials for exploring exotic properties in condensed-matter physics, chemistry and materials science1-3. Although TMT nanosheets have been produced by top-down exfoliation, their scale is below the gram level and requires a long processing time, restricting their effective application from laboratory to market4-8. We report the fast and scalable synthesis of a wide variety of MTe2 (M = Nb, Mo, W, Ta, Ti) nanosheets by the solid lithiation of bulk MTe2 within 10 min and their subsequent hydrolysis within seconds. Using NbTe2 as a representative, we produced more than a hundred grams (108 g) of NbTe2 nanosheets with 3.2 nm mean thickness, 6.2 µm mean lateral size and a high yield (>80%). Several interesting quantum phenomena, such as quantum oscillations and giant magnetoresistance, were observed that are generally restricted to highly crystalline MTe2 nanosheets. The TMT nanosheets also perform well as electrocatalysts for lithium-oxygen batteries and electrodes for microsupercapacitors (MSCs). Moreover, this synthesis method is efficient for preparing alloyed telluride, selenide and sulfide nanosheets. Our work opens new opportunities for the universal and scalable synthesis of TMT nanosheets for exploring new quantum phenomena, potential applications and commercialization.Transition metal tellurides (TMTs) have been ideal materials for exploring exotic properties in condensed-matter physics, chemistry and materials science1-3. Although TMT nanosheets have been produced by top-down exfoliation, their scale is below the gram level and requires a long processing time, restricting their effective application from laboratory to market4-8. We report the fast and scalable synthesis of a wide variety of MTe2 (M = Nb, Mo, W, Ta, Ti) nanosheets by the solid lithiation of bulk MTe2 within 10 min and their subsequent hydrolysis within seconds. Using NbTe2 as a representative, we produced more than a hundred grams (108 g) of NbTe2 nanosheets with 3.2 nm mean thickness, 6.2 µm mean lateral size and a high yield (>80%). Several interesting quantum phenomena, such as quantum oscillations and giant magnetoresistance, were observed that are generally restricted to highly crystalline MTe2 nanosheets. The TMT nanosheets also perform well as electrocatalysts for lithium-oxygen batteries and electrodes for microsupercapacitors (MSCs). Moreover, this synthesis method is efficient for preparing alloyed telluride, selenide and sulfide nanosheets. Our work opens new opportunities for the universal and scalable synthesis of TMT nanosheets for exploring new quantum phenomena, potential applications and commercialization. Transition metal tellurides (TMTs) have been ideal materials for exploring exotic properties in condensed-matter physics, chemistry and materials science 1 – 3 . Although TMT nanosheets have been produced by top-down exfoliation, their scale is below the gram level and requires a long processing time, restricting their effective application from laboratory to market 4 – 8 . We report the fast and scalable synthesis of a wide variety of MTe 2 (M = Nb, Mo, W, Ta, Ti) nanosheets by the solid lithiation of bulk MTe 2 within 10 min and their subsequent hydrolysis within seconds. Using NbTe 2 as a representative, we produced more than a hundred grams (108 g) of NbTe 2 nanosheets with 3.2 nm mean thickness, 6.2 µm mean lateral size and a high yield (>80%). Several interesting quantum phenomena, such as quantum oscillations and giant magnetoresistance, were observed that are generally restricted to highly crystalline MTe 2 nanosheets. The TMT nanosheets also perform well as electrocatalysts for lithium–oxygen batteries and electrodes for microsupercapacitors (MSCs). Moreover, this synthesis method is efficient for preparing alloyed telluride, selenide and sulfide nanosheets. Our work opens new opportunities for the universal and scalable synthesis of TMT nanosheets for exploring new quantum phenomena, potential applications and commercialization. Fast and scalable synthesis of a variety of transition metal telluride nanosheets by solid lithiation and hydrolysis is demonstrated and several interesting quantum phenomena were observed, such as quantum oscillations and giant magnetoresistance. |
| Author | Wu, Zhong-Shuai Cheng, Hui-Ming Wang, Sen Sun, Dong-Ming Kang, Ning Ding, Yajun Feng, Shun Fu, Yunqi Zheng, Shuanghao Guo, Zhuobin Zeng, Huidan Jia, Qingchao Mi, Jinxing Das, Pratteek Li, Mingrun Yang, Zixuan Zhang, Liangzhu Bi, Zhihong Ma, Jiaxin |
| Author_xml | – sequence: 1 givenname: Liangzhu orcidid: 0000-0002-7968-6847 surname: Zhang fullname: Zhang, Liangzhu organization: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai Electronic Chemicals innovation Institute, East China University of science and Technology – sequence: 2 givenname: Zixuan surname: Yang fullname: Yang, Zixuan organization: Key Laboratory for the Physics and Chemistry of Nanodevices and Center for Carbon-based Electronics, School of Electronics, Peking University – sequence: 3 givenname: Shun surname: Feng fullname: Feng, Shun organization: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences – sequence: 4 givenname: Zhuobin surname: Guo fullname: Guo, Zhuobin organization: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, University of Chinese Academy of Sciences – sequence: 5 givenname: Qingchao surname: Jia fullname: Jia, Qingchao organization: School of Materials Science and Engineering, East China University of Science and Technology, Shanghai Electronic Chemicals innovation Institute, East China University of science and Technology – sequence: 6 givenname: Huidan surname: Zeng fullname: Zeng, Huidan organization: School of Materials Science and Engineering, East China University of Science and Technology, Shanghai Electronic Chemicals innovation Institute, East China University of science and Technology – sequence: 7 givenname: Yajun surname: Ding fullname: Ding, Yajun organization: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences – sequence: 8 givenname: Pratteek surname: Das fullname: Das, Pratteek organization: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences – sequence: 9 givenname: Zhihong surname: Bi fullname: Bi, Zhihong organization: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, University of Chinese Academy of Sciences – sequence: 10 givenname: Jiaxin surname: Ma fullname: Ma, Jiaxin organization: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences – sequence: 11 givenname: Yunqi surname: Fu fullname: Fu, Yunqi organization: Key Laboratory for the Physics and Chemistry of Nanodevices and Center for Carbon-based Electronics, School of Electronics, Peking University – sequence: 12 givenname: Sen surname: Wang fullname: Wang, Sen organization: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences – sequence: 13 givenname: Jinxing surname: Mi fullname: Mi, Jinxing organization: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences – sequence: 14 givenname: Shuanghao surname: Zheng fullname: Zheng, Shuanghao organization: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, Chinese Academy of Sciences – sequence: 15 givenname: Mingrun surname: Li fullname: Li, Mingrun organization: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences – sequence: 16 givenname: Dong-Ming orcidid: 0000-0003-1552-7940 surname: Sun fullname: Sun, Dong-Ming organization: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences – sequence: 17 givenname: Ning orcidid: 0000-0003-4478-8402 surname: Kang fullname: Kang, Ning email: nkang@pku.edu.cn organization: Key Laboratory for the Physics and Chemistry of Nanodevices and Center for Carbon-based Electronics, School of Electronics, Peking University – sequence: 18 givenname: Zhong-Shuai orcidid: 0000-0003-1851-4803 surname: Wu fullname: Wu, Zhong-Shuai email: wuzs@dicp.ac.cn organization: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, Chinese Academy of Sciences – sequence: 19 givenname: Hui-Ming orcidid: 0000-0002-5387-4241 surname: Cheng fullname: Cheng, Hui-Ming email: hm.cheng@siat.ac.cn organization: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Faculty of Materials Science and Energy Engineering, Shenzhen University of Advanced Technology |
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| Snippet | Transition metal tellurides (TMTs) have been ideal materials for exploring exotic properties in condensed-matter physics, chemistry and materials science
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3... Transition metal tellurides (TMTs) have been ideal materials for exploring exotic properties in condensed-matter physics, chemistry and materials science .... Transition metal tellurides (TMTs) have been ideal materials for exploring exotic properties in condensed-matter physics, chemistry and materials science1-3.... |
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| Title | Metal telluride nanosheets by scalable solid lithiation and exfoliation |
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