Gas Permeation through Mechanically Resistant Self‐Standing Membranes of a Neat Amorphous Organic Cage

• Published in: Chemistry : a European journal Vol. 29; no. 56; pp. e202301437 - n/a
• Main Authors: Mobili, Riccardo, La Cognata, Sonia, Monteleone, Marcello, Longo, Mariagiulia, Fuoco, Alessio, Serapian, Stefano A., Vigani, Barbara, Milanese, Chiara, Armentano, Donatella, Jansen, Johannes C., Amendola, Valeria
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 09.10.2023
• Subjects: Cages; Chemistry; Controllability; Crystals; Gas permeation; Gas transport; Membranes; Microporosity; molecular materials; organic cages; Permeation; Polyimide resins; Polymers; Single crystals; Thin films; Transport properties; membranes; organic cages; molecular materials; gas transport; thin films

The synthesis and characterization of a novel film‐forming organic cage and of its smaller analogue are here described. While the small cage produced single crystals suitable for X‐ray diffraction studies, the large one was isolated as a dense film. Due to its remarkable film‐forming properties, thi...