Discrimination of the Enantiotopic Faces of Structurally Unbiased Carbenium Ions Employing a Cyclohexadiene‐Based Chiral Hydride Source - Wolff, Benedikt; Qu, Zheng‐Wang; Grimme, Stefan; Oestreich, Martin (Angewandte Chemie International Edition, 2023)
Keywords: Alkenes; Cationic Reactions; Chemistry; Chemistry, Multidisciplinary; Density Functional Calculations; Enantiomers; Hydrides; Hydrogen bonds; Hydrogenation; Ions; Physical Sciences; Reaction mechanisms; Reduction; Science & Technology; Stereoselectivity; Styrenes; Alkenes; CARBOCATIONS; CYCLOHEXA-1,4-DIENES; ALKYLATION; B(C6F5)-CATALYZED TRANSFER; Hydrogenation; Cationic Reactions; Stereoselectivity; Density Functional Calculations; INTERMOLECULAR REACTIONS; DIHYDROGEN; 4+2 CYCLOADDITION; BASIS-SETS; S(N)1-TYPE REACTIONS