Single Crystals Heterogeneity Impacts the Intrinsic and Extrinsic Properties of Metal–Organic Frameworks
At present, an enormous characterization gap exists between the study of the crystal structure of a material and its bulk properties. Individual particles falling within this gap cannot be fully characterized in a correlative manner by current methods. The authors address this problem by exploiting...
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| Published in | Advanced materials (Weinheim) Vol. 34; no. 3; pp. e2104530 - n/a |
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| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
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01.01.2022
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| Abstract | At present, an enormous characterization gap exists between the study of the crystal structure of a material and its bulk properties. Individual particles falling within this gap cannot be fully characterized in a correlative manner by current methods. The authors address this problem by exploiting the noninvasive nature of optical microscopy and spectroscopy for the correlative analysis of metal‐organic framework particles in situ. They probe the intrinsic as well as extrinsic properties in a correlated manner. The authors show that the crystal shape of MIL‐88A strongly impacts its optical absorption. Furthermore, the question of how homogeneously water is distributed and adsorbed within one of the most promising materials for harvesting water from humid air, MOF‐801, is addressed. The results demonstrate the considerable importance of the particle level and how it can affect the property of the material.
The influence of heterogeneities in metal–organic frameworks (MOFs) can be enormous at the single‐particle level but is often neglected in characterization due to the lack of microscopes capable of correlated studies on the same crystals. The authors present an analysis platform for correlated, in situ spectroscopy and imaging named MOSAIC, and unveil new heterogeneity–property relations for two important MOF systems. |
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| AbstractList | Abstract
At present, an enormous characterization gap exists between the study of the crystal structure of a material and its bulk properties. Individual particles falling within this gap cannot be fully characterized in a correlative manner by current methods. The authors address this problem by exploiting the noninvasive nature of optical microscopy and spectroscopy for the correlative analysis of metal‐organic framework particles in situ. They probe the intrinsic as well as extrinsic properties in a correlated manner. The authors show that the crystal shape of MIL‐88A strongly impacts its optical absorption. Furthermore, the question of how homogeneously water is distributed and adsorbed within one of the most promising materials for harvesting water from humid air, MOF‐801, is addressed. The results demonstrate the considerable importance of the particle level and how it can affect the property of the material. At present, an enormous characterization gap exists between the study of the crystal structure of a material and its bulk properties. Individual particles falling within this gap cannot be fully characterized in a correlative manner by current methods. The authors address this problem by exploiting the noninvasive nature of optical microscopy and spectroscopy for the correlative analysis of metal-organic framework particles in situ. They probe the intrinsic as well as extrinsic properties in a correlated manner. The authors show that the crystal shape of MIL-88A strongly impacts its optical absorption. Furthermore, the question of how homogeneously water is distributed and adsorbed within one of the most promising materials for harvesting water from humid air, MOF-801, is addressed. The results demonstrate the considerable importance of the particle level and how it can affect the property of the material. At present, an enormous characterization gap exists between the study of the crystal structure of a material and its bulk properties. Individual particles falling within this gap cannot be fully characterized in a correlative manner by current methods. The authors address this problem by exploiting the noninvasive nature of optical microscopy and spectroscopy for the correlative analysis of metal‐organic framework particles in situ. They probe the intrinsic as well as extrinsic properties in a correlated manner. The authors show that the crystal shape of MIL‐88A strongly impacts its optical absorption. Furthermore, the question of how homogeneously water is distributed and adsorbed within one of the most promising materials for harvesting water from humid air, MOF‐801, is addressed. The results demonstrate the considerable importance of the particle level and how it can affect the property of the material. The influence of heterogeneities in metal–organic frameworks (MOFs) can be enormous at the single‐particle level but is often neglected in characterization due to the lack of microscopes capable of correlated studies on the same crystals. The authors present an analysis platform for correlated, in situ spectroscopy and imaging named MOSAIC, and unveil new heterogeneity–property relations for two important MOF systems. |
| Author | Ji, Zhe Zaytseva, Irina Wang, Haoze Yaghi, Omar Hirschle, Patrick Wuttke, Stefan Ploetz, Evelyn Fuchs, Adrian Mannhardt, Petra |
| Author_xml | – sequence: 1 givenname: Adrian surname: Fuchs fullname: Fuchs, Adrian organization: LMU Munich – sequence: 2 givenname: Petra surname: Mannhardt fullname: Mannhardt, Petra organization: LMU Munich – sequence: 3 givenname: Patrick surname: Hirschle fullname: Hirschle, Patrick organization: LMU Munich – sequence: 4 givenname: Haoze orcidid: 0000-0002-6961-6554 surname: Wang fullname: Wang, Haoze organization: and Berkeley Global Science Institute – sequence: 5 givenname: Irina orcidid: 0000-0001-6949-756X surname: Zaytseva fullname: Zaytseva, Irina organization: LMU Munich – sequence: 6 givenname: Zhe orcidid: 0000-0002-8532-333X surname: Ji fullname: Ji, Zhe organization: Department of Chemistry, Stanford University – sequence: 7 givenname: Omar orcidid: 0000-0002-5611-3325 surname: Yaghi fullname: Yaghi, Omar organization: King Abdulaziz City for Science and Technology – sequence: 8 givenname: Stefan orcidid: 0000-0002-6344-5782 surname: Wuttke fullname: Wuttke, Stefan email: stefan.wuttke@bcmaterials.net organization: Basque Foundation for Science – sequence: 9 givenname: Evelyn orcidid: 0000-0003-0922-875X surname: Ploetz fullname: Ploetz, Evelyn email: evelyn.ploetz@lmu.de organization: LMU Munich |
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| Snippet | At present, an enormous characterization gap exists between the study of the crystal structure of a material and its bulk properties. Individual particles... Abstract At present, an enormous characterization gap exists between the study of the crystal structure of a material and its bulk properties. Individual... |
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| SubjectTerms | Crystal structure Heterogeneity Materials science Metal-organic frameworks metal–organic framework crystals nonlinear imaging Optical microscopy particle level Single crystals spectroscopy |
| Title | Single Crystals Heterogeneity Impacts the Intrinsic and Extrinsic Properties of Metal–Organic Frameworks |
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