Contrasting thermoresponsiveness of stereoisomers of a dense 1,2,3-triazole polymer carrying amide side chains

• Published in: Polymer Chemistry Vol. 14; no. 13; pp. 1488 - 1496
• Main Authors: Okuno, Koji, Miura, Junji, Yamasaki, Shota, Nakahata, Masaki, Kamon, Yuri, Hashidzume, Akihito
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry (RSC) 28.03.2023; Royal Society of Chemistry
• Subjects: Alkynes; Aqueous solutions; Binary mixtures; Cycloaddition; Dimethyl sulfoxide; Dimethylformamide; Isomers; Isotacticity; Phase transitions; Polymer chemistry; Polymerization; Polymers; Sol-gel processes; Stereoisomerism; Syndiotacticity; Temperature

Since thermoresponsive polymers are an important class of smart polymer materials, it is an important subject of investigation to develop thermoresponsive polymers with a new polymer backbone for expanding their potential. Recently, we synthesized poly( N -ethyl- N -methyl-4-azido-5-hexynamide) (pol...