Radiation-induced solute segregation in metallic alloys

•The history of RIS is covered in great detail, both experimentally and theoretically.•We emphasize advances in understanding diffusion in concentrated solid solutions.•We highlight GB structure and its detailed relationship to point-defect sink strength.•The impact of APT on evaluating and modeling...

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Published inCurrent opinion in solid state & materials science Vol. 20; no. 3; pp. 115 - 139
Main Authors Ardell, Alan J., Bellon, Pascal
Format Journal Article
LanguageEnglish
Published United Kingdom Elsevier Ltd 01.06.2016
Elsevier
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Abstract •The history of RIS is covered in great detail, both experimentally and theoretically.•We emphasize advances in understanding diffusion in concentrated solid solutions.•We highlight GB structure and its detailed relationship to point-defect sink strength.•The impact of APT on evaluating and modeling RIS at GBs and dislocations is featured.•We spotlight the role of self-organization on defect-formation involving RIS. The subject of radiation-induced solute segregation (RIS) in metallic alloys is reviewed. RIS manifests itself in several different ways, including diffusion to point-defect sinks (dislocations, grain boundaries, voids, etc.), which can induce precipitation in undersaturated alloys, as well as self-organization of solute clusters and precipitation in defect-free material. Diffusion in dilute and concentrated alloys is highlighted, as are theories of RIS that include new ideas on diffusion of complexes involving coupling between fluxes of point defects and of solute atoms. Many important experimental observations are presented, including up-to-date findings using atom-probe tomography, with special emphasis on solute segregation in austenitic and ferritic steels. Results from computational modeling and theory are also presented and discussed in light of experimental findings. Examples illustrating the factors affecting RIS are shown and some important outstanding issues that impact the current understanding of RIS are described and discussed.
AbstractList •The history of RIS is covered in great detail, both experimentally and theoretically.•We emphasize advances in understanding diffusion in concentrated solid solutions.•We highlight GB structure and its detailed relationship to point-defect sink strength.•The impact of APT on evaluating and modeling RIS at GBs and dislocations is featured.•We spotlight the role of self-organization on defect-formation involving RIS. The subject of radiation-induced solute segregation (RIS) in metallic alloys is reviewed. RIS manifests itself in several different ways, including diffusion to point-defect sinks (dislocations, grain boundaries, voids, etc.), which can induce precipitation in undersaturated alloys, as well as self-organization of solute clusters and precipitation in defect-free material. Diffusion in dilute and concentrated alloys is highlighted, as are theories of RIS that include new ideas on diffusion of complexes involving coupling between fluxes of point defects and of solute atoms. Many important experimental observations are presented, including up-to-date findings using atom-probe tomography, with special emphasis on solute segregation in austenitic and ferritic steels. Results from computational modeling and theory are also presented and discussed in light of experimental findings. Examples illustrating the factors affecting RIS are shown and some important outstanding issues that impact the current understanding of RIS are described and discussed.
The subject of radiation-induced solute segregation (RIS) in metallic alloys is reviewed. RIS manifests itself in several different ways, including diffusion to point-defect sinks (dislocations, grain boundaries, voids, etc.), which can induce precipitation in undersaturated alloys, as well as self-organization of solute clusters and precipitation in defect-free material. Diffusion in dilute and concentrated alloys is highlighted, as are theories of RIS that include new ideas on diffusion of complexes involving coupling between fluxes of point defects and of solute atoms. Many important experimental observations are presented, including up-to-date findings using atom-probe tomography, with special emphasis on solute segregation in austenitic and ferritic steels. Results from computational modeling and theory are also presented and discussed in light of experimental findings. Examples illustrating the factors affecting RIS are shown and some important outstanding issues that impact the current understanding of RIS are described and discussed.
Author Bellon, Pascal
Ardell, Alan J.
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Keywords Rate-theory kinetics
Computational modeling
Solute segregation
Austenitic and ferritic stainless steels
Diffusion
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Radiation damage
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Snippet •The history of RIS is covered in great detail, both experimentally and theoretically.•We emphasize advances in understanding diffusion in concentrated solid...
The subject of radiation-induced solute segregation (RIS) in metallic alloys is reviewed. RIS manifests itself in several different ways, including diffusion...
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SubjectTerms Alloys
Austenitic and ferritic stainless steels
Clustering
Computational modeling
Diffusion
Dislocations
Grain boundaries
Materials science
Mathematical models
Precipitation (chemistry)
Radiation damage
Rate-theory kinetics
Segregations
Solute segregation
Title Radiation-induced solute segregation in metallic alloys
URI https://dx.doi.org/10.1016/j.cossms.2015.11.001
https://www.proquest.com/docview/1825516972
https://www.osti.gov/biblio/1256143
Volume 20
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