Universal relation between crack-growth dynamics and viscoelasticity in glass-rubber transition for filled elastomers

• Published in: Polymer (Guilford) Vol. 179; p. 121651
• Main Authors: Morishita, Yoshihiro, Tsunoda, Katsuhiko, Urayama, Kenji
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 28.09.2019
• Subjects: Crack growth; Power law relation; Viscoelasticity; Viscoelasticity; Power law relation; Crack growth
• ISSN: 0032-3861; 1873-2291
• DOI: 10.1016/j.polymer.2019.121651

The characteristic power-law relationship between crack-growth speed (v) and tearing energy (Γ), Γ ~ vα in high speed regime (typically, v/cs > 10−3 where cs is the shear wave speed), is investigated for the filled elastomers with varying systematically the material parameters. The types of rubber, the concentration of filler and cross-linker concentration are widely varied in order to change the viscoelastic spectra of the elastomers. The power-law relationship is correlated with linear viscoelastic spectra, since Γ and the relaxation modulus are similarly dependent on temperature. An universal relation is found between the exponents α and κ of the relaxation modulus G(t) ~ t−κ in the glass-rubber transition regime, independently of the material parameters. The expectations of the existing theories fail to account for the observed relation, in particular for the elastomers with high filler contents or low cross-linker concentrations. The universal α-κ relation found here will contribute to predict the crack speed in high speed regime from the linear viscoelastic spectra of the elastomers, and will give a definite basis for the theoretical development in the crack-growth dynamics of elastomers. [Display omitted] •We find a universal relation between crack-growth dynamics and viscoelasticity in glass-rubber transition.•The universal relation is not successfully explained by the existing theories.•The universal relation holds for various rubber/filler combinations, independently of material parameters.