(Nitrito-O,O')bis(triphenylphosphine)-copper(I), (PPh3)2Cu(NO2-O,O')

Symmetric binding of nitrite via both O atoms to CuI [Cu--O = 2.191 (4) A] was observed. The copper coordination geometry is significantly distorted from tetrahedral, as evidenced by the angles P--Cu--P [127.75 (7) degrees] and O--Cu--O [56.7 (2) degrees].

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Bibliographic Details
Published inActa crystallographica. Section C, Crystal structure communications Vol. 51 ( Pt 2); p. 215
Main Authors Halfen, J A, Tolman, W B
Format Journal Article
LanguageEnglish
Published United States 15.02.1995
Subjects
Crystallography, X-Ray
Models, Molecular
Organometallic Compounds - chemistry
Organophosphorus Compounds - chemistry
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Summary:Symmetric binding of nitrite via both O atoms to CuI [Cu--O = 2.191 (4) A] was observed. The copper coordination geometry is significantly distorted from tetrahedral, as evidenced by the angles P--Cu--P [127.75 (7) degrees] and O--Cu--O [56.7 (2) degrees].
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270194008991