Effect of aluminum addition on the surface step morphology of 4H–SiC grown from Si–Cr–C solution

• Published in: Journal of crystal growth Vol. 423; pp. 45 - 49
• Main Authors: Mitani, Takeshi, Komatsu, Naoyoshi, Takahashi, Tetsuo, Kato, Tomohisa, Harada, Shunta, Ujihara, Toru, Matsumoto, Yuji, Kurashige, Kazuhisa, Okumura, Hajime
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.08.2015
• Subjects: A1. Roughening; A1. Surface structure; A2. Growth from solution; A2. Top seeded solution growth; Aluminum; B1. Silicon carbide; Composing; Crystal defects; Crystal growth; Formations; Solvents; Surface defects; Terraces; B1. Silicon carbide; A2. Growth from solution; A1. Roughening; A1. Surface structure; A2. Top seeded solution growth
• ISSN: 0022-0248; 1873-5002
• DOI: 10.1016/j.jcrysgro.2015.04.032

For the solution growth of 4H–SiC with Si1−xCrx solvents, the change in surface step structure by 4at% Al addition to the solvent was investigated. Without Al addition, step bunching resulted in the formation of giant macrosteps with height greater than several micrometers, and trench-like surface defects formed with solvent inclusion. The edge of the giant macrosteps composing trench-like defects was faceted into low-index facet planes, (11¯0m) (m=1–4). The formation of the trench-like surface defects is considered to originate from the self-pinning of macrosteps owing to the step-faceting phenomenon, which facilitates further development of macrosteps. On the other hand, the addition of Al to the solvents significantly improved the surface roughening, and suppressed the formation of the trench-like surface defects. In this case, smaller bunched steps with heights from several nanometers to about 10nm formed on the terraces of the macrosteps, while regularly arranged trains of unit-cell-size steps formed on the terrace of macrosteps in growth without Al addition. The decrease in step stiffness might be a possible cause for the formation of the smaller bunched steps on the terrace in growth with Al addition. •Giant macrosteps faceted into stable off-angle (11¯0m) (m=1–4) planes.•Step faceting and 2D nucleation cause formation of trench-like surface defects.•Addition of Al to SiCr solvents suppresses formation of surface defects.•Addition of Al induces instability of trains of unit-cell-size steps on terraces.