Super-hydrophobicity of multi-walled carbon nanotubes treated by a glow discharge

Super-hydrophobic carbon nanotubes (CNTs) were prepared by employing tetrafluoromethane (CF 4) glow discharge plasma at low pressure to provide roughness and fluorination in CNT powders. The water droplet falling freely on the super-hydrophobic CNT powders bounced dynamically and then a contact angl...

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Published inSurface & coatings technology Vol. 201; no. 9; pp. 5025 - 5029
Main Authors Hong, Yong Cheol, Shin, Dong Hun, Uhm, Han Sup
Format Journal Article Conference Proceeding
LanguageEnglish
Published Lausanne Elsevier B.V 26.02.2007
Elsevier
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Abstract Super-hydrophobic carbon nanotubes (CNTs) were prepared by employing tetrafluoromethane (CF 4) glow discharge plasma at low pressure to provide roughness and fluorination in CNT powders. The water droplet falling freely on the super-hydrophobic CNT powders bounced dynamically and then a contact angle (CA) was about 165° in static state, while the droplet falling freely on the untreated CNT powders was immediately absorbed. From the experimental results of SEM, TEM and XPS, the super-hydrophobicity of the CNT powders was resulted from the combined effects of the chemical modification of the surfaces and surface roughness.
AbstractList Super-hydrophobic carbon nanotubes (CNTs) were prepared by employing tetrafluoromethane (CF4) glow discharge plasma at low pressure to provide roughness and fluorination in CNT powders. The water droplet falling freely on the super-hydrophobic CNT powders bounced dynamically and then a contact angle (CA) was about 165 deg in static state, while the droplet falling freely on the untreated CNT powders was immediately absorbed. From the experimental results of SEM, TEM and XPS, the super-hydrophobicity of the CNT powders was resulted from the combined effects of the chemical modification of the surfaces and surface roughness.
Super-hydrophobic carbon nanotubes (CNTs) were prepared by employing tetrafluoromethane (CF 4) glow discharge plasma at low pressure to provide roughness and fluorination in CNT powders. The water droplet falling freely on the super-hydrophobic CNT powders bounced dynamically and then a contact angle (CA) was about 165° in static state, while the droplet falling freely on the untreated CNT powders was immediately absorbed. From the experimental results of SEM, TEM and XPS, the super-hydrophobicity of the CNT powders was resulted from the combined effects of the chemical modification of the surfaces and surface roughness.
Author Hong, Yong Cheol
Uhm, Han Sup
Shin, Dong Hun
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10.1038/nmat856
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Issue 9
Keywords 68.08.Bc
52.50.Dg
81.07De
Glow discharge
CNT
CF 4
Super-hydrophobicity
Contact angle
81.20Ev
Plasma
52.50.Dg; 68.08.Bc; 81.07De; 81.20Ev
Carbon nanotubes
Surface treatments
Super-hydrophobicity; CNT; Contact angle; Glow discharge; CF4
Glow discharges
Language English
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Snippet Super-hydrophobic carbon nanotubes (CNTs) were prepared by employing tetrafluoromethane (CF 4) glow discharge plasma at low pressure to provide roughness and...
Super-hydrophobic carbon nanotubes (CNTs) were prepared by employing tetrafluoromethane (CF4) glow discharge plasma at low pressure to provide roughness and...
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SubjectTerms CF 4
CNT
Contact angle
Cross-disciplinary physics: materials science; rheology
Exact sciences and technology
Glow discharge
Materials science
Other topics in materials science
Physics
Super-hydrophobicity
Title Super-hydrophobicity of multi-walled carbon nanotubes treated by a glow discharge
URI https://dx.doi.org/10.1016/j.surfcoat.2006.07.108
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