Synthesis and properties of bioplastics from corn starch and citric acid-epoxidized soybean oil oligomers
Citric acid-epoxidized soybean oil oligomers (CESO) were prepared and utilized to improve the properties of corn starch-based bioplastics. CESO were synthesized by controlling the stoichiometric ratio of acid equivalent weight and epoxy equivalent weight at 3:1. Starch-based bioplastics with satisfa...
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| Published in | Journal of materials research and technology Vol. 20; pp. 373 - 380 |
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| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.09.2022
Elsevier |
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| Abstract | Citric acid-epoxidized soybean oil oligomers (CESO) were prepared and utilized to improve the properties of corn starch-based bioplastics. CESO were synthesized by controlling the stoichiometric ratio of acid equivalent weight and epoxy equivalent weight at 3:1. Starch-based bioplastics with satisfactory properties were fabricated through solution casting. Analysis including FTIR, molecular distribution, and polydispersity index validated the ring opening polymerization of ESO and CA. The hydrogen bond and crosslinking interactions between CESO and starch were evidenced by the FTIR. SEM micrographs suggested that CESO exhibited better compatibility with starch than ESO. X-ray diffraction patterns of the bioplastics were changed apparently by CESO due to the crosslinking interaction. Swelling degree and opacity of the bioplastics reduced significantly after the introduction of CESO, while tensile strength increased remarkably from 5.62 to 6.93 MPa (p < 0.05). The bioplastic with 4 wt% CESO revealed the most comprehensive properties. Higher content of CESO (16 wt%) displayed poor interaction with starch and led to deteriorated properties of the bioplastics. The synthesized bioplastics exhibited enormous potential to partially replace petroleum-based plastics for various applications such as packaging. |
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| AbstractList | Citric acid-epoxidized soybean oil oligomers (CESO) were prepared and utilized to improve the properties of corn starch-based bioplastics. CESO were synthesized by controlling the stoichiometric ratio of acid equivalent weight and epoxy equivalent weight at 3:1. Starch-based bioplastics with satisfactory properties were fabricated through solution casting. Analysis including FTIR, molecular distribution, and polydispersity index validated the ring opening polymerization of ESO and CA. The hydrogen bond and crosslinking interactions between CESO and starch were evidenced by the FTIR. SEM micrographs suggested that CESO exhibited better compatibility with starch than ESO. X-ray diffraction patterns of the bioplastics were changed apparently by CESO due to the crosslinking interaction. Swelling degree and opacity of the bioplastics reduced significantly after the introduction of CESO, while tensile strength increased remarkably from 5.62 to 6.93 MPa (p < 0.05). The bioplastic with 4 wt% CESO revealed the most comprehensive properties. Higher content of CESO (16 wt%) displayed poor interaction with starch and led to deteriorated properties of the bioplastics. The synthesized bioplastics exhibited enormous potential to partially replace petroleum-based plastics for various applications such as packaging. |
| Author | Baikeli, Yiliyasi Mohammed Al-Hada, Naif Yang, Jianlei Wang, Jiyi Liu, Jing Dong, Xiaotong Xu, Shicai Ching, Yern Chee li, Zhen Chunhui li |
| Author_xml | – sequence: 1 givenname: Jianlei orcidid: 0000-0003-3957-3722 surname: Yang fullname: Yang, Jianlei email: yangjlly1985@outlook.com organization: Shandong Key Laboratory of Biophysics, Institute of Biophysics, Dezhou University, Dezhou, 253023, China – sequence: 2 givenname: Xiaotong surname: Dong fullname: Dong, Xiaotong organization: College of Physics and Electronic Information, Dezhou University, Dezhou, 253023, China – sequence: 3 givenname: Jiyi surname: Wang fullname: Wang, Jiyi organization: College of Chemistry and Chemical Engineering, Dezhou University, Dezhou, 253023, China – sequence: 4 givenname: Yern Chee surname: Ching fullname: Ching, Yern Chee organization: Department of Chemical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur, 50603, Malaysia – sequence: 5 givenname: Jing surname: Liu fullname: Liu, Jing organization: College of Medicine and Nursing, Dezhou University, Dezhou, 253023, China – sequence: 6 surname: Chunhui li fullname: Chunhui li organization: College of Chemistry and Chemical Engineering, Dezhou University, Dezhou, 253023, China – sequence: 7 givenname: Yiliyasi surname: Baikeli fullname: Baikeli, Yiliyasi organization: College of Chemistry and Chemical Engineering, Dezhou University, Dezhou, 253023, China – sequence: 8 givenname: Zhen surname: li fullname: li, Zhen organization: College of Chemistry and Chemical Engineering, Dezhou University, Dezhou, 253023, China – sequence: 9 givenname: Naif surname: Mohammed Al-Hada fullname: Mohammed Al-Hada, Naif organization: Shandong Key Laboratory of Biophysics, Institute of Biophysics, Dezhou University, Dezhou, 253023, China – sequence: 10 givenname: Shicai surname: Xu fullname: Xu, Shicai organization: Shandong Key Laboratory of Biophysics, Institute of Biophysics, Dezhou University, Dezhou, 253023, China |
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| Keywords | Packaging Compatibility Starch Bioplastic Epoxidized soybean oil Citric acid |
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| Snippet | Citric acid-epoxidized soybean oil oligomers (CESO) were prepared and utilized to improve the properties of corn starch-based bioplastics. CESO were... |
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| SubjectTerms | Bioplastic Citric acid Compatibility Epoxidized soybean oil Packaging Starch |
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| Title | Synthesis and properties of bioplastics from corn starch and citric acid-epoxidized soybean oil oligomers |
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