Optical properties of zinc lead tellurite glasses

•Tellurite glass systems in the form of [ZnO]x [(TeO2)0.7-(PbO)0.3]1-x with x = 0.15, 0.17, 0.20, 0.22 and 0.25 mol% were prepared using the melt quenching technique.•FTIR and UV spectra were recorded at 280–4000 cm−1 and 200–800 nm, respectively.•XRD of the prepared samples have been measured for a...

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Published inResults in physics Vol. 9; pp. 1371 - 1376
Main Authors Alazoumi, Salah Hassan, Aziz, Sidek Abdul, El-Mallawany, R., Aliyu, Umar Sa'ad, Kamari, Halimah Mohamed, Zaid, Mohd Hafiz Mohd Mohd, Matori, Khamirul Amin, Ushah, Abdulbaset
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LanguageEnglish
Published Elsevier B.V 01.06.2018
Elsevier
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Abstract •Tellurite glass systems in the form of [ZnO]x [(TeO2)0.7-(PbO)0.3]1-x with x = 0.15, 0.17, 0.20, 0.22 and 0.25 mol% were prepared using the melt quenching technique.•FTIR and UV spectra were recorded at 280–4000 cm−1 and 200–800 nm, respectively.•XRD of the prepared samples have been measured for all samples.•The Optical energy band gap (Eopt), index of refraction (n) were calculated using absorption spectrum.•Molar polarizability, metallization criterion, polaron radius have been calculated for every glass composition. Tellurite glass systems in the form of [ZnO]x [(TeO2)0.7-(PbO)0.3]1-x with x = 0.15, 0.17, 0.20, 0.22 and 0.25 mol% were prepared using the melt quenching technique. XRD of the prepared samples have been measured for all samples. Both FTIR (280–4000 cm−1) and UV-Vis (200–800 nm) spectra have been measured. Optical band gap and refractive index were calculated for every glass sample. Density of glass, molar volume and oxygen packing density (OPD) were obtained. Values of the direct, indirect band gap ranged were found in the range 3.41–3.94 eV and 2.40–2.63 eV with increasing of ZnO concentration. Refractive index 2.58 and dielectric constant 6.66 were heigh at 17 ZnO mol% concentration. Molar polarizability, metallization criterion, polaron radius have been calculated for every glass composition.
AbstractList •Tellurite glass systems in the form of [ZnO]x [(TeO2)0.7-(PbO)0.3]1-x with x = 0.15, 0.17, 0.20, 0.22 and 0.25 mol% were prepared using the melt quenching technique.•FTIR and UV spectra were recorded at 280–4000 cm−1 and 200–800 nm, respectively.•XRD of the prepared samples have been measured for all samples.•The Optical energy band gap (Eopt), index of refraction (n) were calculated using absorption spectrum.•Molar polarizability, metallization criterion, polaron radius have been calculated for every glass composition. Tellurite glass systems in the form of [ZnO]x [(TeO2)0.7-(PbO)0.3]1-x with x = 0.15, 0.17, 0.20, 0.22 and 0.25 mol% were prepared using the melt quenching technique. XRD of the prepared samples have been measured for all samples. Both FTIR (280–4000 cm−1) and UV-Vis (200–800 nm) spectra have been measured. Optical band gap and refractive index were calculated for every glass sample. Density of glass, molar volume and oxygen packing density (OPD) were obtained. Values of the direct, indirect band gap ranged were found in the range 3.41–3.94 eV and 2.40–2.63 eV with increasing of ZnO concentration. Refractive index 2.58 and dielectric constant 6.66 were heigh at 17 ZnO mol% concentration. Molar polarizability, metallization criterion, polaron radius have been calculated for every glass composition.
Tellurite glass systems in the form of [ZnO]x [(TeO2)0.7-(PbO)0.3]1-x with x = 0.15, 0.17, 0.20, 0.22 and 0.25 mol% were prepared using the melt quenching technique. XRD of the prepared samples have been measured for all samples. Both FTIR (280–4000 cm−1) and UV-Vis (200–800 nm) spectra have been measured. Optical band gap and refractive index were calculated for every glass sample. Density of glass, molar volume and oxygen packing density (OPD) were obtained. Values of the direct, indirect band gap ranged were found in the range 3.41–3.94 eV and 2.40–2.63 eV with increasing of ZnO concentration. Refractive index 2.58 and dielectric constant 6.66 were heigh at 17 ZnO mol% concentration. Molar polarizability, metallization criterion, polaron radius have been calculated for every glass composition. Keywords: Tellurite, Glass, Optical band gap, Refractive index
Author Zaid, Mohd Hafiz Mohd Mohd
Matori, Khamirul Amin
Aliyu, Umar Sa'ad
Ushah, Abdulbaset
Alazoumi, Salah Hassan
El-Mallawany, R.
Aziz, Sidek Abdul
Kamari, Halimah Mohamed
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  givenname: Sidek Abdul
  surname: Aziz
  fullname: Aziz, Sidek Abdul
  email: sidek@upm.edu.my
  organization: Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia
– sequence: 3
  givenname: R.
  surname: El-Mallawany
  fullname: El-Mallawany, R.
  organization: Physics Department, Faculty of Science, Menoufia University, Egypt
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  givenname: Umar Sa'ad
  surname: Aliyu
  fullname: Aliyu, Umar Sa'ad
  organization: Department of Physics, Faculty of Science, Federal University Lafia, Nigeria
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  givenname: Halimah Mohamed
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  fullname: Kamari, Halimah Mohamed
  organization: Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia
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  givenname: Mohd Hafiz Mohd Mohd
  surname: Zaid
  fullname: Zaid, Mohd Hafiz Mohd Mohd
  organization: Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia
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  givenname: Khamirul Amin
  surname: Matori
  fullname: Matori, Khamirul Amin
  organization: Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia
– sequence: 8
  givenname: Abdulbaset
  surname: Ushah
  fullname: Ushah, Abdulbaset
  organization: Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia
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Keywords Tellurite
Optical band gap
Refractive index
Glass
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SSID ssj0001645511
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Snippet •Tellurite glass systems in the form of [ZnO]x [(TeO2)0.7-(PbO)0.3]1-x with x = 0.15, 0.17, 0.20, 0.22 and 0.25 mol% were prepared using the melt quenching...
Tellurite glass systems in the form of [ZnO]x [(TeO2)0.7-(PbO)0.3]1-x with x = 0.15, 0.17, 0.20, 0.22 and 0.25 mol% were prepared using the melt quenching...
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crossref
elsevier
SourceType Open Website
Enrichment Source
Index Database
Publisher
StartPage 1371
SubjectTerms Glass
Optical band gap
Refractive index
Tellurite
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Title Optical properties of zinc lead tellurite glasses
URI https://dx.doi.org/10.1016/j.rinp.2018.04.041
https://doaj.org/article/cf5d8da096c448498bd3419c9c28b680
Volume 9
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