The effect of fluoride on the formation of an electroless Ni–P plating film on MAO-coated AZ31B magnesium alloy

This study adds fluoride to the electroless nickel-phosphorus (Ni–P) plating solution to prevent the deterioration of MAO-coated AZ31B Magnesium alloy after contact with an electroless plating bath. During the electroless Ni–P plating process, fluoride reacts with Ni2+ ions and the MAO coating to fo...

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Published inJournal of materials research and technology Vol. 19; pp. 542 - 556
Main Authors Lee, Chia-Yu, Lee, Jeou-Long, Jian, Shun-Yi, Chen, Chi-An, Aktug, Salim Levent, Ger, Ming-Der
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.07.2022
Elsevier
Subjects
AZ31B magnesium Alloy
Corrosion resistance
Electroless Ni–P plating
Fluoride
NaMgF3
Corrosion resistance
AZ31B magnesium Alloy
Fluoride
Electroless Ni–P plating
NaMgF3
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Abstract This study adds fluoride to the electroless nickel-phosphorus (Ni–P) plating solution to prevent the deterioration of MAO-coated AZ31B Magnesium alloy after contact with an electroless plating bath. During the electroless Ni–P plating process, fluoride reacts with Ni2+ ions and the MAO coating to form interphases (NaMgF3), which exhibit good bonding and corrosion resistance. NaMgF3 buffers H+ ions formed from the initiation of Ni–P deposition, preventing the interface of materials from damaging the MAO coating with H+ ions. As immersion time increases, nickel is scattered over the coating. The fundamental data for MAO/Ni–P coated AZ31B Mg alloy determines whether there is fluoride in the electroless Ni–P plating solution. The results show that the coating for a fluoride-containing solution is more resistant to corrosion than those in fluoride-free solution. The compositions, structure and morphology of the MAO/Ni–P coatings that formed for different working parameters are determined using energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The corrosion resistance of the MAO/Ni–P coatings is calculated in a 3.5 wt.% NaCl solution using a potentiodynamic polarization test, electrochemical impedance spectroscopy (EIS) and a salt spray test (SST).
AbstractList This study adds fluoride to the electroless nickel-phosphorus (Ni–P) plating solution to prevent the deterioration of MAO-coated AZ31B Magnesium alloy after contact with an electroless plating bath. During the electroless Ni–P plating process, fluoride reacts with Ni2+ ions and the MAO coating to form interphases (NaMgF3), which exhibit good bonding and corrosion resistance. NaMgF3 buffers H+ ions formed from the initiation of Ni–P deposition, preventing the interface of materials from damaging the MAO coating with H+ ions. As immersion time increases, nickel is scattered over the coating.The fundamental data for MAO/Ni–P coated AZ31B Mg alloy determines whether there is fluoride in the electroless Ni–P plating solution. The results show that the coating for a fluoride-containing solution is more resistant to corrosion than those in fluoride-free solution. The compositions, structure and morphology of the MAO/Ni–P coatings that formed for different working parameters are determined using energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The corrosion resistance of the MAO/Ni–P coatings is calculated in a 3.5 wt.% NaCl solution using a potentiodynamic polarization test, electrochemical impedance spectroscopy (EIS) and a salt spray test (SST).
This study adds fluoride to the electroless nickel-phosphorus (Ni–P) plating solution to prevent the deterioration of MAO-coated AZ31B Magnesium alloy after contact with an electroless plating bath. During the electroless Ni–P plating process, fluoride reacts with Ni2+ ions and the MAO coating to form interphases (NaMgF3), which exhibit good bonding and corrosion resistance. NaMgF3 buffers H+ ions formed from the initiation of Ni–P deposition, preventing the interface of materials from damaging the MAO coating with H+ ions. As immersion time increases, nickel is scattered over the coating. The fundamental data for MAO/Ni–P coated AZ31B Mg alloy determines whether there is fluoride in the electroless Ni–P plating solution. The results show that the coating for a fluoride-containing solution is more resistant to corrosion than those in fluoride-free solution. The compositions, structure and morphology of the MAO/Ni–P coatings that formed for different working parameters are determined using energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The corrosion resistance of the MAO/Ni–P coatings is calculated in a 3.5 wt.% NaCl solution using a potentiodynamic polarization test, electrochemical impedance spectroscopy (EIS) and a salt spray test (SST).
Author Ger, Ming-Der
Chen, Chi-An
Jian, Shun-Yi
Lee, Chia-Yu
Lee, Jeou-Long
Aktug, Salim Levent
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Keywords Corrosion resistance
AZ31B magnesium Alloy
Fluoride
Electroless Ni–P plating
NaMgF3
Language English
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Snippet This study adds fluoride to the electroless nickel-phosphorus (Ni–P) plating solution to prevent the deterioration of MAO-coated AZ31B Magnesium alloy after...
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SubjectTerms AZ31B magnesium Alloy
Corrosion resistance
Electroless Ni–P plating
Fluoride
NaMgF3
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  providerName: Elsevier
Title The effect of fluoride on the formation of an electroless Ni–P plating film on MAO-coated AZ31B magnesium alloy
URI https://dx.doi.org/10.1016/j.jmrt.2022.05.081
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