Recent advances of Copper- BTC metal-organic frameworks for efficient degradation of organic dye-polluted wastewater: Synthesis, mechanistic insights and future outlook

Water borne emerging pollutants represents a significant challenge confronting the modern society. As a result of excessive use of dyes and pigments by the textile and other industries, substantial amount of these toxic and recalcitrant substances are widely dispersed into the aquatic sources that m...

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Published inJournal of hazardous materials letters Vol. 5; p. 100094
Main Authors Roy, Saptarshi, Darabdhara, Jnyanashree, Ahmaruzzaman, Md
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.11.2024
Elsevier
Subjects
HKUST-1
Mechanistic Insights
Metal Organic Framework
Organic dyes
Photodegradation
Wastewater
Photodegradation
Wastewater
Organic dyes
Mechanistic Insights
Metal Organic Framework
HKUST-1
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Abstract Water borne emerging pollutants represents a significant challenge confronting the modern society. As a result of excessive use of dyes and pigments by the textile and other industries, substantial amount of these toxic and recalcitrant substances are widely dispersed into the aquatic sources that may raise serious health issues to all life forms besides causing potential disruption to the ecosystem. Treatments of these hazardous and non-biodegradable organic contaminants in wastewater effluents have become a focal point for researchers dedicated to environmental remediation. Notably, Metal organic frameworks (MOFs) and their composites have been reported to be promising materials for tackling such challenges. This review is dedicated to provide a concise overview by consolidating the diverse beneficial attributes of Cu-BTC MOF rendering it as a versatile material with applications spanning diverse domains, focusing on the reactivity, the role of the metal ion and its recent potential for addressing the elimination of toxic textile dye wastes from the wastewater effluent. Furthermore, it also documents the underlying mechanistic pathway governing the degradation mechanism and the superior electron transport property of Cu ̶ BTC, besides painting in detail the existing limitations that hinder their applicability at an industrial platform. Moreover, a set of future research outlooks serving as a roadmap for exploring the potentiality of Cu ̶ BTC MOFs have also been presented. [Display omitted] •Structure and properties of Cu−BTC MOF.•Recent advancements of HKUST-1 MOF composites in remediation of dye contaminated wastewater.•Detailed explanation of the mechanism involved in photocatalysis.•Underlying present challenges and the prospect of future outlook in developing Cu−BTC photocatalysts.•Next generation smart technology for treatment of wastewater.
AbstractList Water borne emerging pollutants represents a significant challenge confronting the modern society. As a result of excessive use of dyes and pigments by the textile and other industries, substantial amount of these toxic and recalcitrant substances are widely dispersed into the aquatic sources that may raise serious health issues to all life forms besides causing potential disruption to the ecosystem. Treatments of these hazardous and non-biodegradable organic contaminants in wastewater effluents have become a focal point for researchers dedicated to environmental remediation. Notably, Metal organic frameworks (MOFs) and their composites have been reported to be promising materials for tackling such challenges. This review is dedicated to provide a concise overview by consolidating the diverse beneficial attributes of Cu-BTC MOF rendering it as a versatile material with applications spanning diverse domains, focusing on the reactivity, the role of the metal ion and its recent potential for addressing the elimination of toxic textile dye wastes from the wastewater effluent. Furthermore, it also documents the underlying mechanistic pathway governing the degradation mechanism and the superior electron transport property of Cu ̶ BTC, besides painting in detail the existing limitations that hinder their applicability at an industrial platform. Moreover, a set of future research outlooks serving as a roadmap for exploring the potentiality of Cu ̶ BTC MOFs have also been presented. [Display omitted] •Structure and properties of Cu−BTC MOF.•Recent advancements of HKUST-1 MOF composites in remediation of dye contaminated wastewater.•Detailed explanation of the mechanism involved in photocatalysis.•Underlying present challenges and the prospect of future outlook in developing Cu−BTC photocatalysts.•Next generation smart technology for treatment of wastewater.
Water borne emerging pollutants represents a significant challenge confronting the modern society. As a result of excessive use of dyes and pigments by the textile and other industries, substantial amount of these toxic and recalcitrant substances are widely dispersed into the aquatic sources that may raise serious health issues to all life forms besides causing potential disruption to the ecosystem. Treatments of these hazardous and non-biodegradable organic contaminants in wastewater effluents have become a focal point for researchers dedicated to environmental remediation. Notably, Metal organic frameworks (MOFs) and their composites have been reported to be promising materials for tackling such challenges. This review is dedicated to provide a concise overview by consolidating the diverse beneficial attributes of Cu-BTC MOF rendering it as a versatile material with applications spanning diverse domains, focusing on the reactivity, the role of the metal ion and its recent potential for addressing the elimination of toxic textile dye wastes from the wastewater effluent. Furthermore, it also documents the underlying mechanistic pathway governing the degradation mechanism and the superior electron transport property of Cu ̶ BTC, besides painting in detail the existing limitations that hinder their applicability at an industrial platform. Moreover, a set of future research outlooks serving as a roadmap for exploring the potentiality of Cu ̶ BTC MOFs have also been presented.
ArticleNumber 100094
Author Roy, Saptarshi
Ahmaruzzaman, Md
Darabdhara, Jnyanashree
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Keywords Photodegradation
Wastewater
Organic dyes
Mechanistic Insights
Metal Organic Framework
HKUST-1
Language English
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Snippet Water borne emerging pollutants represents a significant challenge confronting the modern society. As a result of excessive use of dyes and pigments by the...
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SubjectTerms HKUST-1
Mechanistic Insights
Metal Organic Framework
Organic dyes
Photodegradation
Wastewater
Title Recent advances of Copper- BTC metal-organic frameworks for efficient degradation of organic dye-polluted wastewater: Synthesis, mechanistic insights and future outlook
URI https://dx.doi.org/10.1016/j.hazl.2023.100094
https://doaj.org/article/b18fbe7493434221ae514a344c37abf9
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