Formation of a supramolecular charge-transfer complex. Ultrafast excited state dynamics and quantum-chemical calculations

The formation of a supramolecular complex of bis(18-crown-6)stilbene ( 1 ) and 4,4′-bipyridine with two ammoniopropyl N -substituents ( 3 ) and the substitution reaction between 1·3 and alkali and alkaline-earth metal perchlorates have been studied using absorption, steady-state fluorescence, and fe...

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Published inPhotochemical & photobiological sciences Vol. 18; no. 1; pp. 232 - 241
Main Authors Volchkov, Valery V, Khimich, Mikhail N, Rusalov, Mikhail V, Gostev, Fedor E, Shelaev, Ivan V, Nadtochenko, Viktor A, Vedernikov, Artem I, Gromov, Sergey P, Freidzon, Alexandra Ya, Alfimov, Michael V, Melnikov, Mikhail Ya
Format Journal Article
LanguageEnglish
Published Cham Springer International Publishing 01.01.2019
Royal Society of Chemistry
Subjects
Absorption spectra
Absorption spectroscopy
Acetonitrile
Alkali metals
Alkaline earth metals
Biochemistry
Biomaterials
Cations
Charge transfer
Chemistry
Disruption
Electron transfer
Femtosecond pulses
Fluorescence
Mathematical analysis
Metal ions
Organic chemistry
Perchlorates
Physical Chemistry
Plant Sciences
Quantum chemistry
Stilbene
Substitution reactions
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Abstract The formation of a supramolecular complex of bis(18-crown-6)stilbene ( 1 ) and 4,4′-bipyridine with two ammoniopropyl N -substituents ( 3 ) and the substitution reaction between 1·3 and alkali and alkaline-earth metal perchlorates have been studied using absorption, steady-state fluorescence, and femtosecond transient absorption spectroscopy. The formation of 1 ·(M n + ) 2 complexes in acetonitrile was demonstrated. The weak long-wavelength charge-transfer absorption band of 1·3 completely vanishes upon complexation with metal cations because of disruption of the pseudocyclic structure. The spectroscopic and luminescence parameters, stability and substitution constants were calculated. The relaxation scheme of the 1·3 singlet state excited by a 25 fs laser pulse was proposed. It includes very fast vibrational relaxation and direct ( τ CT-d = 0.32 ps) and back ( τ CT-b = 0.51 ps) electron transfer resulting in complete fluorescence quenching. The quantum-chemistry calculations revealed the species taking part in the ET process and elucidated the mechanism of relaxation of the excited complex. The relaxation scheme of the 1·3 singlet state excited by a 25 fs laser pulse was proposed. It includes very fast vibrational relaxation, and direct and back electron transfer resulting in complete fluorescence quenching.
AbstractList The formation of a supramolecular complex of bis(18-crown-6)stilbene (1) and 4,4′-bipyridine with two ammoniopropyl N-substituents (3) and the substitution reaction between 1·3 and alkali and alkaline-earth metal perchlorates have been studied using absorption, steady-state fluorescence, and femtosecond transient absorption spectroscopy. The formation of 1·(Mn+)2 complexes in acetonitrile was demonstrated. The weak long-wavelength charge-transfer absorption band of 1·3 completely vanishes upon complexation with metal cations because of disruption of the pseudocyclic structure. The spectroscopic and luminescence parameters, stability and substitution constants were calculated. The relaxation scheme of the 1·3 singlet state excited by a 25 fs laser pulse was proposed. It includes very fast vibrational relaxation and direct (τCT-d = 0.32 ps) and back (τCT-b = 0.51 ps) electron transfer resulting in complete fluorescence quenching. The quantum-chemistry calculations revealed the species taking part in the ET process and elucidated the mechanism of relaxation of the excited complex.
The formation of a supramolecular complex of bis(18-crown-6)stilbene (1) and 4,4'-bipyridine with two ammoniopropyl N-substituents (3) and the substitution reaction between 1·3 and alkali and alkaline-earth metal perchlorates have been studied using absorption, steady-state fluorescence, and femtosecond transient absorption spectroscopy. The formation of 1·(Mn+)2 complexes in acetonitrile was demonstrated. The weak long-wavelength charge-transfer absorption band of 1·3 completely vanishes upon complexation with metal cations because of disruption of the pseudocyclic structure. The spectroscopic and luminescence parameters, stability and substitution constants were calculated. The relaxation scheme of the 1·3 singlet state excited by a 25 fs laser pulse was proposed. It includes very fast vibrational relaxation and direct (τCT-d = 0.32 ps) and back (τCT-b = 0.51 ps) electron transfer resulting in complete fluorescence quenching. The quantum-chemistry calculations revealed the species taking part in the ET process and elucidated the mechanism of relaxation of the excited complex.The formation of a supramolecular complex of bis(18-crown-6)stilbene (1) and 4,4'-bipyridine with two ammoniopropyl N-substituents (3) and the substitution reaction between 1·3 and alkali and alkaline-earth metal perchlorates have been studied using absorption, steady-state fluorescence, and femtosecond transient absorption spectroscopy. The formation of 1·(Mn+)2 complexes in acetonitrile was demonstrated. The weak long-wavelength charge-transfer absorption band of 1·3 completely vanishes upon complexation with metal cations because of disruption of the pseudocyclic structure. The spectroscopic and luminescence parameters, stability and substitution constants were calculated. The relaxation scheme of the 1·3 singlet state excited by a 25 fs laser pulse was proposed. It includes very fast vibrational relaxation and direct (τCT-d = 0.32 ps) and back (τCT-b = 0.51 ps) electron transfer resulting in complete fluorescence quenching. The quantum-chemistry calculations revealed the species taking part in the ET process and elucidated the mechanism of relaxation of the excited complex.
The formation of a supramolecular complex of bis(18-crown-6)stilbene (1) and 4,4'-bipyridine with two ammoniopropyl N-substituents (3) and the substitution reaction between 1·3 and alkali and alkaline-earth metal perchlorates have been studied using absorption, steady-state fluorescence, and femtosecond transient absorption spectroscopy. The formation of 1·(M ) complexes in acetonitrile was demonstrated. The weak long-wavelength charge-transfer absorption band of 1·3 completely vanishes upon complexation with metal cations because of disruption of the pseudocyclic structure. The spectroscopic and luminescence parameters, stability and substitution constants were calculated. The relaxation scheme of the 1·3 singlet state excited by a 25 fs laser pulse was proposed. It includes very fast vibrational relaxation and direct (τ = 0.32 ps) and back (τ = 0.51 ps) electron transfer resulting in complete fluorescence quenching. The quantum-chemistry calculations revealed the species taking part in the ET process and elucidated the mechanism of relaxation of the excited complex.
The formation of a supramolecular complex of bis(18-crown-6)stilbene ( 1 ) and 4,4′-bipyridine with two ammoniopropyl N -substituents ( 3 ) and the substitution reaction between 1·3 and alkali and alkaline-earth metal perchlorates have been studied using absorption, steady-state fluorescence, and femtosecond transient absorption spectroscopy. The formation of 1 ·(M n + ) 2 complexes in acetonitrile was demonstrated. The weak long-wavelength charge-transfer absorption band of 1·3 completely vanishes upon complexation with metal cations because of disruption of the pseudocyclic structure. The spectroscopic and luminescence parameters, stability and substitution constants were calculated. The relaxation scheme of the 1·3 singlet state excited by a 25 fs laser pulse was proposed. It includes very fast vibrational relaxation and direct ( τ CT-d = 0.32 ps) and back ( τ CT-b = 0.51 ps) electron transfer resulting in complete fluorescence quenching. The quantum-chemistry calculations revealed the species taking part in the ET process and elucidated the mechanism of relaxation of the excited complex. The relaxation scheme of the 1·3 singlet state excited by a 25 fs laser pulse was proposed. It includes very fast vibrational relaxation, and direct and back electron transfer resulting in complete fluorescence quenching.
The formation of a supramolecular complex of bis(18-crown-6)stilbene ( 1 ) and 4,4'-bipyridine with two ammoniopropyl N -substituents ( 3 ) and the substitution reaction between 1•3 and alkali and alkaline-earth metal perchlorates have been studied using absorption, steady-state fluorescence, and femtosecond transient absorption spectroscopy. The formation of 1 •(M n + ) 2 complexes in acetonitrile was demonstrated. The weak long-wavelength charge-transfer absorption band of 1•3 completely vanishes upon complexation with metal cations because of disruption of the pseudocyclic structure. The spectroscopic and luminescence parameters, stability and substitution constants were calculated. The relaxation scheme of the 1-3 singlet state excited by a 25 fs laser pulse was proposed. It includes very fast vibrational relaxation and direct (τ CT-d = 0.32 ps) and back (τ CT-b = 0.51 ps) electron transfer resulting in complete fluorescence quenching. The quantum-chemistry calculations revealed the species taking part in the ET process and elucidated the mechanism of relaxation of the excited complex.
Author Melnikov, Mikhail Ya
Freidzon, Alexandra Ya
Volchkov, Valery V
Vedernikov, Artem I
Alfimov, Michael V
Gromov, Sergey P
Rusalov, Mikhail V
Shelaev, Ivan V
Khimich, Mikhail N
Gostev, Fedor E
Nadtochenko, Viktor A
AuthorAffiliation Chemistry Department
M. V. Lomonosov Moscow State University
N. N. Semenov Institute of Chemical Physics
FSRC "Crystallography and Photonics"
Russian Academy of Sciences
National Research Nuclear University MEPhI (Moscow Engineering Physics Institute)
Photochemistry Center
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  givenname: Valery V
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Cites_doi 10.1063/1.3596699
10.1021/jp013274x
10.1016/B978-044451719-7/50084-6
10.1146/annurev.physchem.49.1.233
10.1021/jp071560o
10.1021/ol990710d
10.1002/jcc.21759
10.1021/jp304518f
10.1016/0301-0104(81)85090-2
10.1016/j.chemphys.2003.12.002
10.1021/ja00236a005
10.1021/jo201172w
10.1002/poc.3759
10.1007/978-3-642-58150-2_4
10.1016/0009-2614(90)85369-N
10.1021/acs.chemrev.6b00491
10.1021/jp012082z
10.1002/jcc.540141112
10.1039/b500667h
10.1351/pac199567050783
10.1021/j100355a001
10.1103/RevModPhys.68.985
10.1063/1.459170
10.1021/j100820a009
10.1021/j100286a016
10.1007/s10895-015-1744-5
10.1021/jp810292n
10.1021/j100794a511
10.1021/ja00406a009
10.1039/C7PP00170C
10.1070/PU1964v006n04ABEH003587
10.1038/467412a
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References Rusalov, Volchkov, Ivanov, Ya. Melnikov, Gostev, Nadtochenko, Vedernikov, Gromov, Alfimov (CR33) 2018
Himmelblau (CR19) 1972
Grimme, Ehrlich, Goerigk (CR22) 2011; 32
Mataga, Shioyama, Kanda (CR1) 1987; 91
Perlin (CR34) 1964; 6
Volchkov, Rusalov, Gostev, Shelaev, Nadtochenko, Vedernikov, Efremova, Kuz'mina, Gromov, Alfimov, Ya. Melnikov (CR11) 2018; 31
Xia, Schmehl, Li, Mague, Luo, Guldi (CR13) 2002; 106
Roos (CR29) 1987; 69
Kao, Guo, Yang, Liu, Hassanali, Song, Wang, Zhong (CR6) 2012; 116
Ushakov, Nadtochenko, Gromov, Vedernikov, Lobova, Alfimov, Gostev, Petrukhin, Sarkisov (CR9) 2004; 298
Gordon, Schmidt (CR21) 2005
Tully (CR35) 1990; 93
Rusalov, Volchkov, Ivanov, Ya. Melnikov, Shelaev, Gostev, Nadtochenko, Vedernikov, Gromov, Alfimov (CR10) 2017; 16
Kumpulainen, Lang, Rosspeintner, Vauthey (CR8) 2017; 117
Ushakov, Gromov, Vedernikov, Malysheva, Botsmanova, Alfimov, Eliasson, Edlung, Whitesell, Fox (CR12) 2002; 106
Swinnen, Van der Auweraer, de Schryver, Makatani, Okada, Mataga (CR5) 1987; 109
Wallace, Katz (CR32) 1964; 68
Gromov, Ushakov, Vedernikov, Lobova, Alfimov, Strelenko, Alfimov, Whitesell, Fox (CR16) 1999; 1
Granovsky (CR24) 2017
Miertus, Scrocco, Tomasi (CR31) 1981; 55
Martinez (CR36) 2010; 467
Schmidt, Gordon (CR25) 1998; 49
Robb, Bernardi, Olivucci (CR38) 1995; 67
Shepard (CR28) 1987; 69
Gromov, Vedernikov, Ushakov, Lobova, Botsmanova, Kuz'mina, Churakov, Strelenko, Alfimov, Howard, Johnels, Edlung (CR14) 2005; 29
CR26
Marenich, Cramer, Truhlar (CR23) 2009; 113
Yarkony (CR37) 1996; 68
Asahi, Mataga, Takahashi, Miyashi (CR3) 1990; 171
Vedernikov, Ushakov, Efremova, Kuz'mina, Moiseeva, Lobova, Churakov, Strelenko, Alfimov, Howard, Gromov (CR15) 2011; 76
Melhuish (CR17) 1961; 65
Granovsky (CR30) 2011; 134
Roos, in (CR27) 1994; 58
Asahi, Mataga (CR2) 1989; 93
Volchkov, Gostev, Shelaev, Nadtochenko, Dmitrieva, Gromov, Alfimov, Ya. Melnikov (CR18) 2016; 26
Schmidt, Baldridge, Boatz, Elbert, Gordon, Jensen, Koseki, Matsunaga, Nguyen, Su, Windus, Dupuis, Montgomery (CR20) 1993; 14
Duvanel, Banerji, Vauthey (CR7) 2007; 111
Okada, Migita, Mataga, Sakata, Misumi (CR4) 1981; 103
S Grimme (1801024_CR22) 2011; 32
R Shepard (1801024_CR28) 1987; 69
T Kumpulainen (1801024_CR8) 2017; 117
M W Schmidt (1801024_CR25) 1998; 49
Yu E Perlin (1801024_CR34) 1964; 6
B O Roos (1801024_CR29) 1987; 69
M A Robb (1801024_CR38) 1995; 67
D M Himmelblau (1801024_CR19) 1972
Y-T Kao (1801024_CR6) 2012; 116
A M Swinnen (1801024_CR5) 1987; 109
R M Wallace (1801024_CR32) 1964; 68
T J Martinez (1801024_CR36) 2010; 467
D R Yarkony (1801024_CR37) 1996; 68
S P Gromov (1801024_CR14) 2005; 29
T Okada (1801024_CR4) 1981; 103
N Mataga (1801024_CR1) 1987; 91
A V Marenich (1801024_CR23) 2009; 113
V V Volchkov (1801024_CR18) 2016; 26
M S Gordon (1801024_CR21) 2005
T Asahi (1801024_CR3) 1990; 171
M V Rusalov (1801024_CR10) 2017; 16
1801024_CR26
V V Volchkov (1801024_CR11) 2018; 31
M V Rusalov (1801024_CR33) 2018
E N Ushakov (1801024_CR12) 2002; 106
A A Granovsky (1801024_CR30) 2011; 134
G Duvanel (1801024_CR7) 2007; 111
S P Gromov (1801024_CR16) 1999; 1
S Miertus (1801024_CR31) 1981; 55
M W Schmidt (1801024_CR20) 1993; 14
T Asahi (1801024_CR2) 1989; 93
J C Tully (1801024_CR35) 1990; 93
W H Melhuish (1801024_CR17) 1961; 65
B O Roos, in (1801024_CR27) 1994; 58
E N Ushakov (1801024_CR9) 2004; 298
A A Granovsky (1801024_CR24) 2017
W-S Xia (1801024_CR13) 2002; 106
A I Vedernikov (1801024_CR15) 2011; 76
References_xml – issn: 2005
  volume-title: Advances in electronic structure theory: GAMESS a decade later
  end-page: 1167-1189
  publication-title: Theory and applications of computational chemistry: the first forty years
  doi: Gordon Schmidt
– issn: 1983
  end-page: 161-187
  publication-title: Methods in computational molecular physics
  doi: Roos
– issn: 1994
  issue: 58
  end-page: 177-254
  publication-title: Lecture notes in quantum chemistry
  doi: Roos
– issn: 1987
  issue: 69
  volume-title: The multiconfiguration self-consistent field method. Ab initio methods in quantum chemistry - II
  end-page: 63-200
  publication-title: Adv. Chem. Phys
  doi: Shepard
– issn: 2017
  publication-title: Firefly 8.2, build 10203
  doi: Granovsky
– issn: 1972
  publication-title: Applied nonlinear programming
  doi: Himmelblau
– volume: 134
  start-page: 214113
  year: 2011
  end-page: 214126
  ident: CR30
  article-title: Extended multi-configuration quasi-degenerate perturbation theory: the new approach to multi-state multi-reference perturbation theory
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.3596699
– volume: 106
  start-page: 833
  year: 2002
  end-page: 843
  ident: CR13
  article-title: Chemosensors for lead(II) and alkali metal ions based on self-assembling fluorescence enhancement (SAFE)
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp013274x
– start-page: 1167
  year: 2005
  end-page: 1189
  ident: CR21
  article-title: Advances in electronic structure theory: GAMESS a decade later
  publication-title: Theory and applications of computational chemistry: the first forty years
  doi: 10.1016/B978-044451719-7/50084-6
– volume: 49
  start-page: 233
  year: 1998
  end-page: 266
  ident: CR25
  article-title: The construction and interpretation of MCSCF wavefunctions
  publication-title: Annu. Rev. Phys. Chem.
  doi: 10.1146/annurev.physchem.49.1.233
– volume: 111
  start-page: 5361
  year: 2007
  end-page: 5369
  ident: CR7
  article-title: Excited-state dynamics of donor-acceptor bridged systems containing a boron-dipyrromethene chromophore: interplay between charge separation and reorientational motion
  publication-title: J. Phys. Chem. A
  doi: 10.1021/jp071560o
– volume: 1
  start-page: 1697
  year: 1999
  end-page: 1699
  ident: CR16
  article-title: A novel optical sensors for metal ions based on ground-state intermolecular chargetransfer complexation
  publication-title: Org. Lett.
  doi: 10.1021/ol990710d
– volume: 32
  start-page: 1456
  year: 2011
  end-page: 1465
  ident: CR22
  article-title: Effect of the damping function in dispersion corrected density functional theory
  publication-title: J. Comput. Chem.
  doi: 10.1002/jcc.21759
– volume: 116
  start-page: 9130
  year: 2012
  end-page: 9140
  ident: CR6
  article-title: Ultrafast dynamics of nonequilibrium electron transfer in photoinduced redox cycle: solvent mediation and conformation flexibility
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp304518f
– volume: 55
  start-page: 117
  year: 1981
  end-page: 129
  ident: CR31
  article-title: Electrostatic interaction of a solute with a continuum. A direct utilizaion of AB initio molecular potentials for the prevision of solvent effects
  publication-title: Chem. Phys.
  doi: 10.1016/0301-0104(81)85090-2
– volume: 298
  start-page: 251
  year: 2004
  end-page: 261
  ident: CR9
  article-title: Ultrafast excited state dynamics of the bi- and termolecular stilbene-viologen charge-transfer complexes assembled via host-guest interactions
  publication-title: Chem. Phys.
  doi: 10.1016/j.chemphys.2003.12.002
– volume: 109
  start-page: 321
  year: 1987
  end-page: 330
  ident: CR5
  article-title: Photophysics of the intramolecular exciplex formation in ω,-(1-pyrenyl)-alpha-N,N-dimethylaminoalkanes
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00236a005
– volume: 76
  start-page: 6768
  year: 2011
  end-page: 6779
  ident: CR15
  article-title: Synthesis, structure, and properties of supra-molecular charge-transfer complex between bis-(18-crown-6) stilbene and ammonioalkyl derivatives of 4,4'-bipyridine and 2,7-diazapyrene
  publication-title: J. Org. Chem.
  doi: 10.1021/jo201172w
– volume: 31
  start-page: e3759
  issue: 2
  year: 2018
  ident: CR11
  article-title: Complexation of bis-crown stilbene with alkali and alkaline-earth metal cations. Ultrafast excited state dynamics of the stilbene-viologen analogue charge transfer complex
  publication-title: J. Phys. Org. Chem.
  doi: 10.1002/poc.3759
– year: 1972
  ident: CR19
  publication-title: Applied nonlinear programming
– volume: 58
  start-page: 177
  year: 1994
  end-page: 254
  ident: CR27
  publication-title: Lecture notes in quantum chemistry
  doi: 10.1007/978-3-642-58150-2_4
– volume: 171
  start-page: 309
  year: 1990
  end-page: 313
  ident: CR3
  article-title: Energy gap dependence of the charge recombination process of ion pairs produced by excitation of 2,6,9,10-tetracyano-anthracene-methyl substituted benzene charge transfer complexes in acetonitrile
  publication-title: Chem. Phys. Lett.
  doi: 10.1016/0009-2614(90)85369-N
– volume: 117
  start-page: 10826
  year: 2017
  end-page: 10939
  ident: CR8
  article-title: Ultrafast elementary photochemical processes of organic molecules in liquid solution
  publication-title: Chem. Rev.
  doi: 10.1021/acs.chemrev.6b00491
– volume: 106
  start-page: 2020
  year: 2002
  end-page: 2023
  ident: CR12
  article-title: Self-organization of highly stable electron donor-acceptor complexes via host-guest interactions
  publication-title: J. Phys. Chem. A
  doi: 10.1021/jp012082z
– volume: 14
  start-page: 1347
  year: 1993
  end-page: 1363
  ident: CR20
  article-title: General atomic and molecular electronic structure system
  publication-title: J. Comput. Chem.
  doi: 10.1002/jcc.540141112
– volume: 29
  start-page: 881
  year: 2005
  end-page: 894
  ident: CR14
  article-title: Novel supramolecular charge-transfer systems based on bis-(18-crown-6)stilbene and viologen analogues bearing two ammonioalkyl groups
  publication-title: New J. Chem.
  doi: 10.1039/b500667h
– volume: 67
  start-page: 783
  year: 1995
  end-page: 789
  ident: CR38
  article-title: Conical intersections as a mechanistic feature of organic photochemistry
  publication-title: PureAppl. Chem.
  doi: 10.1351/pac199567050783
– volume: 93
  start-page: 6575
  year: 1989
  end-page: 6578
  ident: CR2
  article-title: Charge recombination process of ion pair state produced excitation of charge-transfer complex in acetonitrile solution. Essentially different character of its energy gap dependence from that of geminate ion pair formed by encounter between fluorescer and quencher
  publication-title: J. Phys. Chem.
  doi: 10.1021/j100355a001
– volume: 69
  start-page: 63
  year: 1987
  end-page: 200
  ident: CR28
  article-title: The multiconfiguration self-consistent field method. Ab initio methods in quantum chemistry - II
  publication-title: Adv. Chem. Phys
– volume: 68
  start-page: 985
  year: 1996
  end-page: 1013
  ident: CR37
  article-title: Diabolical conical intersections
  publication-title: Rev. Mod. Phys.
  doi: 10.1103/RevModPhys.68.985
– volume: 93
  start-page: 1061
  year: 1990
  end-page: 1071
  ident: CR35
  article-title: Molecular dynamics with electronic transitions
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.459170
– volume: 65
  start-page: 229
  year: 1961
  end-page: 235
  ident: CR17
  article-title: Quantum efficiencies of fluorescence of organic substances: Effect of solvent and concentration of the fluorescent solute
  publication-title: J. Phys. Chem.
  doi: 10.1021/j100820a009
– volume: 91
  start-page: 314
  year: 1987
  end-page: 317
  ident: CR1
  article-title: Dynamics of charge recombination processes in the singlet electron-transfer state of pyrene-pyromellitic dianhydride systems in various solvents. Picosecond laser photolysis studies
  publication-title: J. Phys. Chem.
  doi: 10.1021/j100286a016
– year: 2017
  ident: CR24
  publication-title: Firefly 8.2, build 10203
– volume: 26
  start-page: 585
  year: 2016
  end-page: 592
  ident: CR18
  article-title: Complexation of donor-acceptor substituted aza-crowns with alkali and alkaline earth metal cations. Charge transfer and recoordination in excited state
  publication-title: J. Fluoresc.
  doi: 10.1007/s10895-015-1744-5
– volume: 113
  start-page: 6378
  year: 2009
  end-page: 6396
  ident: CR23
  article-title: Universal solvation model based on solute electron density and on a continuum model of the solvent defined by the bulk dielectric constant and atomic surface tensions
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp810292n
– ident: CR26
– volume: 68
  start-page: 3890
  year: 1964
  end-page: 3892
  ident: CR32
  article-title: A method for the determination of rank in the analysis of absorption spectra of multi-component system
  publication-title: J. Phys. Chem.
  doi: 10.1021/j100794a511
– year: 2018
  ident: CR33
  article-title: Ultrafast excited state dynamics of a stilbene-viologen charge transfer complex and its interaction with alkanediammonium salts
  publication-title: J. Photochem. Photobiol.
– volume: 103
  start-page: 4715
  year: 1981
  end-page: 4720
  ident: CR4
  article-title: Picosecond laser spectroscopy of intramolecular heteroexcimer systems. Time-resolved absorption studies of p-(CH NC H (CH ), (1-pyrenyl) and -(9-anthryl) systems
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00406a009
– volume: 16
  start-page: 1800
  year: 2017
  end-page: 1811
  ident: CR10
  article-title: Femtosecond excited state dynamics of a stilbene-viologene charge transfer complex assembled via host-guest interactions
  publication-title: Photochem. Photobiol. Sci.
  doi: 10.1039/C7PP00170C
– volume: 6
  start-page: 542
  year: 1964
  end-page: 565
  ident: CR34
  article-title: Modern methods in the theory of manyphonon processes
  publication-title: Sov. Phys. Usp.
  doi: 10.1070/PU1964v006n04ABEH003587
– volume: 69
  start-page: 339
  year: 1987
  end-page: 445
  ident: CR29
  publication-title: Adv. Chem. Phys.
– volume: 467
  start-page: 412
  year: 2010
  end-page: 413
  ident: CR36
  article-title: Physical chemistry: Seaming is believing
  publication-title: Nature
  doi: 10.1038/467412a
– volume-title: Firefly 8.2, build 10203
  year: 2017
  ident: 1801024_CR24
– volume: 111
  start-page: 5361
  year: 2007
  ident: 1801024_CR7
  publication-title: J. Phys. Chem. A
  doi: 10.1021/jp071560o
– start-page: 1167
  volume-title: Theory and applications of computational chemistry: the first forty years
  year: 2005
  ident: 1801024_CR21
  doi: 10.1016/B978-044451719-7/50084-6
– volume-title: Applied nonlinear programming
  year: 1972
  ident: 1801024_CR19
– volume: 58
  start-page: 177
  year: 1994
  ident: 1801024_CR27
  publication-title: Lecture notes in quantum chemistry
  doi: 10.1007/978-3-642-58150-2_4
– volume: 467
  start-page: 412
  year: 2010
  ident: 1801024_CR36
  publication-title: Nature
  doi: 10.1038/467412a
– volume: 69
  start-page: 339
  year: 1987
  ident: 1801024_CR29
  publication-title: Adv. Chem. Phys.
– volume: 76
  start-page: 6768
  year: 2011
  ident: 1801024_CR15
  publication-title: J. Org. Chem.
  doi: 10.1021/jo201172w
– volume: 55
  start-page: 117
  year: 1981
  ident: 1801024_CR31
  publication-title: Chem. Phys.
  doi: 10.1016/0301-0104(81)85090-2
– volume: 14
  start-page: 1347
  year: 1993
  ident: 1801024_CR20
  publication-title: J. Comput. Chem.
  doi: 10.1002/jcc.540141112
– volume: 117
  start-page: 10826
  year: 2017
  ident: 1801024_CR8
  publication-title: Chem. Rev.
  doi: 10.1021/acs.chemrev.6b00491
– volume: 26
  start-page: 585
  year: 2016
  ident: 1801024_CR18
  publication-title: J. Fluoresc.
  doi: 10.1007/s10895-015-1744-5
– volume: 103
  start-page: 4715
  year: 1981
  ident: 1801024_CR4
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00406a009
– volume: 109
  start-page: 321
  year: 1987
  ident: 1801024_CR5
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00236a005
– volume: 6
  start-page: 542
  year: 1964
  ident: 1801024_CR34
  publication-title: Sov. Phys. Usp.
  doi: 10.1070/PU1964v006n04ABEH003587
– volume: 67
  start-page: 783
  year: 1995
  ident: 1801024_CR38
  publication-title: PureAppl. Chem.
  doi: 10.1351/pac199567050783
– volume: 171
  start-page: 309
  year: 1990
  ident: 1801024_CR3
  publication-title: Chem. Phys. Lett.
  doi: 10.1016/0009-2614(90)85369-N
– volume: 65
  start-page: 229
  year: 1961
  ident: 1801024_CR17
  publication-title: J. Phys. Chem.
  doi: 10.1021/j100820a009
– volume: 298
  start-page: 251
  year: 2004
  ident: 1801024_CR9
  publication-title: Chem. Phys.
  doi: 10.1016/j.chemphys.2003.12.002
– volume: 32
  start-page: 1456
  year: 2011
  ident: 1801024_CR22
  publication-title: J. Comput. Chem.
  doi: 10.1002/jcc.21759
– volume: 68
  start-page: 3890
  year: 1964
  ident: 1801024_CR32
  publication-title: J. Phys. Chem.
  doi: 10.1021/j100794a511
– volume: 134
  start-page: 214113
  year: 2011
  ident: 1801024_CR30
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.3596699
– volume: 116
  start-page: 9130
  year: 2012
  ident: 1801024_CR6
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp304518f
– volume: 93
  start-page: 6575
  year: 1989
  ident: 1801024_CR2
  publication-title: J. Phys. Chem.
  doi: 10.1021/j100355a001
– volume: 106
  start-page: 2020
  year: 2002
  ident: 1801024_CR12
  publication-title: J. Phys. Chem. A
  doi: 10.1021/jp012082z
– volume: 29
  start-page: 881
  year: 2005
  ident: 1801024_CR14
  publication-title: New J. Chem.
  doi: 10.1039/b500667h
– volume: 113
  start-page: 6378
  year: 2009
  ident: 1801024_CR23
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp810292n
– volume: 68
  start-page: 985
  year: 1996
  ident: 1801024_CR37
  publication-title: Rev. Mod. Phys.
  doi: 10.1103/RevModPhys.68.985
– volume: 31
  start-page: e3759
  issue: 2
  year: 2018
  ident: 1801024_CR11
  publication-title: J. Phys. Org. Chem.
  doi: 10.1002/poc.3759
– volume: 1
  start-page: 1697
  year: 1999
  ident: 1801024_CR16
  publication-title: Org. Lett.
  doi: 10.1021/ol990710d
– volume: 16
  start-page: 1800
  year: 2017
  ident: 1801024_CR10
  publication-title: Photochem. Photobiol. Sci.
  doi: 10.1039/C7PP00170C
– volume: 49
  start-page: 233
  year: 1998
  ident: 1801024_CR25
  publication-title: Annu. Rev. Phys. Chem.
  doi: 10.1146/annurev.physchem.49.1.233
– volume: 91
  start-page: 314
  year: 1987
  ident: 1801024_CR1
  publication-title: J. Phys. Chem.
  doi: 10.1021/j100286a016
– ident: 1801024_CR26
– volume-title: J. Photochem. Photobiol.
  year: 2018
  ident: 1801024_CR33
– volume: 69
  start-page: 63
  year: 1987
  ident: 1801024_CR28
  publication-title: Adv. Chem. Phys
– volume: 93
  start-page: 1061
  year: 1990
  ident: 1801024_CR35
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.459170
– volume: 106
  start-page: 833
  year: 2002
  ident: 1801024_CR13
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp013274x
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Snippet The formation of a supramolecular complex of bis(18-crown-6)stilbene ( 1 ) and 4,4′-bipyridine with two ammoniopropyl N -substituents ( 3 ) and the...
The formation of a supramolecular complex of bis(18-crown-6)stilbene ( 1 ) and 4,4'-bipyridine with two ammoniopropyl N -substituents ( 3 ) and the...
The formation of a supramolecular complex of bis(18-crown-6)stilbene (1) and 4,4'-bipyridine with two ammoniopropyl N-substituents (3) and the substitution...
The formation of a supramolecular complex of bis(18-crown-6)stilbene (1) and 4,4′-bipyridine with two ammoniopropyl N-substituents (3) and the substitution...
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SubjectTerms Absorption spectra
Absorption spectroscopy
Acetonitrile
Alkali metals
Alkaline earth metals
Biochemistry
Biomaterials
Cations
Charge transfer
Chemistry
Disruption
Electron transfer
Femtosecond pulses
Fluorescence
Mathematical analysis
Metal ions
Organic chemistry
Perchlorates
Physical Chemistry
Plant Sciences
Quantum chemistry
Stilbene
Substitution reactions
Title Formation of a supramolecular charge-transfer complex. Ultrafast excited state dynamics and quantum-chemical calculations
URI https://link.springer.com/article/10.1039/c8pp00328a
https://www.ncbi.nlm.nih.gov/pubmed/30462131
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https://www.proquest.com/docview/2136555016
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