Kinetic study on the heterogeneous degradation of coniferyl alcohol by OH radicals
Coniferyl alcohol derived from lignin pyrolysis, is a potential tracer for wood burning emissions, but its atmospheric stability toward OH radicals is not well known. In this work, the degradation kinetics of coniferyl alcohol by OH radicals was studied using a flow reactor at different OH concentra...
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| Published in | Chemosphere (Oxford) Vol. 241; p. 125088 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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Elsevier Ltd
01.02.2020
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| Abstract | Coniferyl alcohol derived from lignin pyrolysis, is a potential tracer for wood burning emissions, but its atmospheric stability toward OH radicals is not well known. In this work, the degradation kinetics of coniferyl alcohol by OH radicals was studied using a flow reactor at different OH concentrations, temperatures, and relative humidity (RH). The results showed that coniferyl alcohol could be degraded effectively by OH radials, and the average second-order rate constant (k2) was (11.6 ± 0.5) × 10−12 cm3 molecule−1 s−1 at the temperature and RH of 25 °C and 40%, respectively. Additionally, increasing temperature facilitated the degradation of coniferyl alcohol and the Arrhenius equation could be expressed as k2 = (1.7 ± 0.3) × 10−9exp [-(1480.2 ± 55.6)/T] at 40% RH. Meanwhile, increasing RH had a negative impact on the degradation of coniferyl alcohol. According to the k2 obtained under different conditions, the atmospheric lifetime of coniferyl alcohol was in the range of 13.5 ± 0.4 h to 22.9 ± 1.4 h. The results suggested that the atmosphere lifetime of coniferyl alcohol was predominantly controlled by OH radicals.
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•Degradation kinetics of coniferyl alcohol by OH radicals was studied.•High temperature and low RH facilitated the degradation of coniferyl alcohol.•OH radicals play a dominant role in the degradation of coniferyl alcohol. |
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| AbstractList | Coniferyl alcohol derived from lignin pyrolysis, is a potential tracer for wood burning emissions, but its atmospheric stability toward OH radicals is not well known. In this work, the degradation kinetics of coniferyl alcohol by OH radicals was studied using a flow reactor at different OH concentrations, temperatures, and relative humidity (RH). The results showed that coniferyl alcohol could be degraded effectively by OH radials, and the average second-order rate constant (k
) was (11.6 ± 0.5) × 10
cm
molecule
s
at the temperature and RH of 25 °C and 40%, respectively. Additionally, increasing temperature facilitated the degradation of coniferyl alcohol and the Arrhenius equation could be expressed as k
= (1.7 ± 0.3) × 10
exp [-(1480.2 ± 55.6)/T] at 40% RH. Meanwhile, increasing RH had a negative impact on the degradation of coniferyl alcohol. According to the k
obtained under different conditions, the atmospheric lifetime of coniferyl alcohol was in the range of 13.5 ± 0.4 h to 22.9 ± 1.4 h. The results suggested that the atmosphere lifetime of coniferyl alcohol was predominantly controlled by OH radicals. Coniferyl alcohol derived from lignin pyrolysis, is a potential tracer for wood burning emissions, but its atmospheric stability toward OH radicals is not well known. In this work, the degradation kinetics of coniferyl alcohol by OH radicals was studied using a flow reactor at different OH concentrations, temperatures, and relative humidity (RH). The results showed that coniferyl alcohol could be degraded effectively by OH radials, and the average second-order rate constant (k2) was (11.6 ± 0.5) × 10−12 cm3 molecule−1 s−1 at the temperature and RH of 25 °C and 40%, respectively. Additionally, increasing temperature facilitated the degradation of coniferyl alcohol and the Arrhenius equation could be expressed as k2 = (1.7 ± 0.3) × 10−9exp [-(1480.2 ± 55.6)/T] at 40% RH. Meanwhile, increasing RH had a negative impact on the degradation of coniferyl alcohol. According to the k2 obtained under different conditions, the atmospheric lifetime of coniferyl alcohol was in the range of 13.5 ± 0.4 h to 22.9 ± 1.4 h. The results suggested that the atmosphere lifetime of coniferyl alcohol was predominantly controlled by OH radicals. [Display omitted] •Degradation kinetics of coniferyl alcohol by OH radicals was studied.•High temperature and low RH facilitated the degradation of coniferyl alcohol.•OH radicals play a dominant role in the degradation of coniferyl alcohol. Coniferyl alcohol derived from lignin pyrolysis, is a potential tracer for wood burning emissions, but its atmospheric stability toward OH radicals is not well known. In this work, the degradation kinetics of coniferyl alcohol by OH radicals was studied using a flow reactor at different OH concentrations, temperatures, and relative humidity (RH). The results showed that coniferyl alcohol could be degraded effectively by OH radials, and the average second-order rate constant (k2) was (11.6 ± 0.5) × 10-12 cm3 molecule-1 s-1 at the temperature and RH of 25 °C and 40%, respectively. Additionally, increasing temperature facilitated the degradation of coniferyl alcohol and the Arrhenius equation could be expressed as k2 = (1.7 ± 0.3) × 10-9exp [-(1480.2 ± 55.6)/T] at 40% RH. Meanwhile, increasing RH had a negative impact on the degradation of coniferyl alcohol. According to the k2 obtained under different conditions, the atmospheric lifetime of coniferyl alcohol was in the range of 13.5 ± 0.4 h to 22.9 ± 1.4 h. The results suggested that the atmosphere lifetime of coniferyl alcohol was predominantly controlled by OH radicals.Coniferyl alcohol derived from lignin pyrolysis, is a potential tracer for wood burning emissions, but its atmospheric stability toward OH radicals is not well known. In this work, the degradation kinetics of coniferyl alcohol by OH radicals was studied using a flow reactor at different OH concentrations, temperatures, and relative humidity (RH). The results showed that coniferyl alcohol could be degraded effectively by OH radials, and the average second-order rate constant (k2) was (11.6 ± 0.5) × 10-12 cm3 molecule-1 s-1 at the temperature and RH of 25 °C and 40%, respectively. Additionally, increasing temperature facilitated the degradation of coniferyl alcohol and the Arrhenius equation could be expressed as k2 = (1.7 ± 0.3) × 10-9exp [-(1480.2 ± 55.6)/T] at 40% RH. Meanwhile, increasing RH had a negative impact on the degradation of coniferyl alcohol. According to the k2 obtained under different conditions, the atmospheric lifetime of coniferyl alcohol was in the range of 13.5 ± 0.4 h to 22.9 ± 1.4 h. The results suggested that the atmosphere lifetime of coniferyl alcohol was predominantly controlled by OH radicals. Coniferyl alcohol derived from lignin pyrolysis, is a potential tracer for wood burning emissions, but its atmospheric stability toward OH radicals is not well known. In this work, the degradation kinetics of coniferyl alcohol by OH radicals was studied using a flow reactor at different OH concentrations, temperatures, and relative humidity (RH). The results showed that coniferyl alcohol could be degraded effectively by OH radials, and the average second-order rate constant (k₂) was (11.6 ± 0.5) × 10⁻¹² cm³ molecule⁻¹ s⁻¹ at the temperature and RH of 25 °C and 40%, respectively. Additionally, increasing temperature facilitated the degradation of coniferyl alcohol and the Arrhenius equation could be expressed as k₂ = (1.7 ± 0.3) × 10⁻⁹exp [-(1480.2 ± 55.6)/T] at 40% RH. Meanwhile, increasing RH had a negative impact on the degradation of coniferyl alcohol. According to the k₂ obtained under different conditions, the atmospheric lifetime of coniferyl alcohol was in the range of 13.5 ± 0.4 h to 22.9 ± 1.4 h. The results suggested that the atmosphere lifetime of coniferyl alcohol was predominantly controlled by OH radicals. |
| ArticleNumber | 125088 |
| Author | Chen, Xiao’e Liu, Changgeng He, Yucan |
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| Keywords | Relative humidity Coniferyl alcohol Temperature OH radicals Heterogeneous reaction |
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| SubjectTerms | Air Pollutants - chemistry Atmosphere burning Coniferyl alcohol emissions equations free radicals Heterogeneous reaction Humidity Hydroxyl Radical - chemistry hydroxyl radicals Kinetics lignin OH radicals Phenols - chemistry pyrolysis Relative humidity Temperature wood |
| Title | Kinetic study on the heterogeneous degradation of coniferyl alcohol by OH radicals |
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