Catalytic activity of powder and monolith perovskites in methane combustion

Honeycomb monolith perovskite catalysts were prepared from ultradispersed powders of mixed oxides of rare-earth metals (La–Ce or Dy–Y) and transition metals (Ni, Fe, Mn) by mechanochemical methods. A plasmochemical method was used to obtain La–Ni containing monoliths. The catalytic activity of powde...

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Published inCatalysis today Vol. 47; no. 1; pp. 199 - 207
Main Authors Ciambelli, P., Palma, V., Tikhov, S.F., Sadykov, V.A., Isupova, L.A., Lisi, L.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1999
Subjects
Catalytic
Combustion
Methane
Monolith
Perovskite
Methane
Catalytic
Perovskite
Combustion
Monolith
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Abstract Honeycomb monolith perovskite catalysts were prepared from ultradispersed powders of mixed oxides of rare-earth metals (La–Ce or Dy–Y) and transition metals (Ni, Fe, Mn) by mechanochemical methods. A plasmochemical method was used to obtain La–Ni containing monoliths. The catalytic activity of powders and monoliths was compared in the catalytic combustion of methane. The intrinsic catalytic properties of the active components (apparent kinetic constant and energy of activation) were not significantly affected by the manufacturing procedure of monoliths in a large range of temperatures. Best performance was exhibited by La–Ni oxides containing monoliths which possess the highest pore volume and fraction of macropores.
AbstractList Honeycomb monolith perovskite catalysts were prepared from ultradispersed powders of mixed oxides of rare-earth metals (La–Ce or Dy–Y) and transition metals (Ni, Fe, Mn) by mechanochemical methods. A plasmochemical method was used to obtain La–Ni containing monoliths. The catalytic activity of powders and monoliths was compared in the catalytic combustion of methane. The intrinsic catalytic properties of the active components (apparent kinetic constant and energy of activation) were not significantly affected by the manufacturing procedure of monoliths in a large range of temperatures. Best performance was exhibited by La–Ni oxides containing monoliths which possess the highest pore volume and fraction of macropores.
Author Ciambelli, P.
Isupova, L.A.
Lisi, L.
Palma, V.
Sadykov, V.A.
Tikhov, S.F.
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  surname: Lisi
  fullname: Lisi, L.
  organization: Research Institute on Combustion IRC-CNR, P.le V. Tecchio80125 NapoliItaly
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Cites_doi 10.1007/BF02075115
10.1039/ft9918702493
10.1016/0166-9834(83)80027-X
10.1016/0926-3373(94)00020-4
10.1016/0920-5861(90)87017-W
10.1016/S0360-0564(08)60019-X
10.1080/01614949308013910
10.1016/0920-5861(95)00195-6
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Keywords Methane
Catalytic
Perovskite
Combustion
Monolith
Language English
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References S.F. Tikhov, V.A. Sadykov, E.A. Pack, O.N. Kimkhai, E.M. Moroz, V.P. Ivanov, G.N. Kustova, G.M. Alikina, Proceedings of the Seventh International Symposium on Heterogeneous Catalysis, Bourgas, 1991, vol. 2, p. 243
Marshneva, Boreskov (BIB12) 1974; 1
Marti, Maciejewski, Baiker (BIB5) 1994; 4
Isupova, Sadykov, Tikhov, Kimkhai, Kovalenko, Kustova, Ovsyannikova, Dovbii, Kriukova, Rozovskii, Tretyakov, Lunin (BIB8) 1996; 27
V.A. Sadykov, L.A. Isupova, S.F. Tikhov, O.N. Kimkhai, Proceedings of the MRS Fall Meeting, Boston, 28 November–2 December 1994, vol. 386, p. 293
Johnson, Gallagher, Schrey, Rhodes (BIB2) 1976; 55
L.A. Isupova, V.A. Sadykov, L.P. Sovoyova, M.P. Andrianova, V.P. Ivanov, G.N. Kriukova, V.N. Kolomiichuk, E.G. Avvakumov, I.A. Pauli, O.V. Andryushkova, V.A. Poluboyarov, A.Ya. Rozovskii, V.F. Tretyakov, Proceedings of the Sixth International Symposium on Scientific Bases Prep. Heterogeneous Catalysts, Louvain-la Neuve, 5–8 September 1994, vol. 2, p. 231
Zwinkels, Jaras, Menon, Griffin (BIB1) 1993; 26
Tejuca, Fierro, Tascon (BIB7) 1989; 36
de Collongue, Garbowski, Primet (BIB4) 1991; 87
Yamazoe, Teraoka (BIB3) 1990; 8
Trimm (BIB6) 1983; 7
Yamazoe (10.1016/S0920-5861(98)00300-9_BIB3) 1990; 8
Zwinkels (10.1016/S0920-5861(98)00300-9_BIB1) 1993; 26
Marti (10.1016/S0920-5861(98)00300-9_BIB5) 1994; 4
Isupova (10.1016/S0920-5861(98)00300-9_BIB8) 1996; 27
10.1016/S0920-5861(98)00300-9_BIB11
Johnson (10.1016/S0920-5861(98)00300-9_BIB2) 1976; 55
10.1016/S0920-5861(98)00300-9_BIB10
Trimm (10.1016/S0920-5861(98)00300-9_BIB6) 1983; 7
10.1016/S0920-5861(98)00300-9_BIB9
Marshneva (10.1016/S0920-5861(98)00300-9_BIB12) 1974; 1
de Collongue (10.1016/S0920-5861(98)00300-9_BIB4) 1991; 87
Tejuca (10.1016/S0920-5861(98)00300-9_BIB7) 1989; 36
References_xml – volume: 26
  start-page: 319
  year: 1993
  ident: BIB1
  publication-title: Catal. Rev.-Sci. Eng.
  contributor:
    fullname: Griffin
– volume: 4
  start-page: 225
  year: 1994
  ident: BIB5
  publication-title: Appl. Catal. B
  contributor:
    fullname: Baiker
– volume: 1
  start-page: 15
  year: 1974
  ident: BIB12
  publication-title: React. Kinet. Catal. Lett.
  contributor:
    fullname: Boreskov
– volume: 87
  start-page: 2493
  year: 1991
  ident: BIB4
  publication-title: J. Chem. Soc., Faraday Trans.
  contributor:
    fullname: Primet
– volume: 8
  start-page: 175
  year: 1990
  ident: BIB3
  publication-title: Catal. Today
  contributor:
    fullname: Teraoka
– volume: 7
  start-page: 249
  year: 1983
  ident: BIB6
  publication-title: Appl. Catal.
  contributor:
    fullname: Trimm
– volume: 36
  start-page: 237
  year: 1989
  ident: BIB7
  publication-title: Adv. Catal.
  contributor:
    fullname: Tascon
– volume: 55
  start-page: 589
  year: 1976
  ident: BIB2
  publication-title: Am. Ceram. Soc. Bull.
  contributor:
    fullname: Rhodes
– volume: 27
  start-page: 249
  year: 1996
  ident: BIB8
  publication-title: Catal. Today
  contributor:
    fullname: Lunin
– volume: 55
  start-page: 589
  year: 1976
  ident: 10.1016/S0920-5861(98)00300-9_BIB2
  publication-title: Am. Ceram. Soc. Bull.
  contributor:
    fullname: Johnson
– volume: 1
  start-page: 15
  year: 1974
  ident: 10.1016/S0920-5861(98)00300-9_BIB12
  publication-title: React. Kinet. Catal. Lett.
  doi: 10.1007/BF02075115
  contributor:
    fullname: Marshneva
– volume: 87
  start-page: 2493
  year: 1991
  ident: 10.1016/S0920-5861(98)00300-9_BIB4
  publication-title: J. Chem. Soc., Faraday Trans.
  doi: 10.1039/ft9918702493
  contributor:
    fullname: de Collongue
– volume: 7
  start-page: 249
  year: 1983
  ident: 10.1016/S0920-5861(98)00300-9_BIB6
  publication-title: Appl. Catal.
  doi: 10.1016/0166-9834(83)80027-X
  contributor:
    fullname: Trimm
– ident: 10.1016/S0920-5861(98)00300-9_BIB10
– volume: 4
  start-page: 225
  year: 1994
  ident: 10.1016/S0920-5861(98)00300-9_BIB5
  publication-title: Appl. Catal. B
  doi: 10.1016/0926-3373(94)00020-4
  contributor:
    fullname: Marti
– ident: 10.1016/S0920-5861(98)00300-9_BIB11
– volume: 8
  start-page: 175
  year: 1990
  ident: 10.1016/S0920-5861(98)00300-9_BIB3
  publication-title: Catal. Today
  doi: 10.1016/0920-5861(90)87017-W
  contributor:
    fullname: Yamazoe
– volume: 36
  start-page: 237
  year: 1989
  ident: 10.1016/S0920-5861(98)00300-9_BIB7
  publication-title: Adv. Catal.
  doi: 10.1016/S0360-0564(08)60019-X
  contributor:
    fullname: Tejuca
– volume: 26
  start-page: 319
  year: 1993
  ident: 10.1016/S0920-5861(98)00300-9_BIB1
  publication-title: Catal. Rev.-Sci. Eng.
  doi: 10.1080/01614949308013910
  contributor:
    fullname: Zwinkels
– ident: 10.1016/S0920-5861(98)00300-9_BIB9
– volume: 27
  start-page: 249
  year: 1996
  ident: 10.1016/S0920-5861(98)00300-9_BIB8
  publication-title: Catal. Today
  doi: 10.1016/0920-5861(95)00195-6
  contributor:
    fullname: Isupova
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SubjectTerms Catalytic
Combustion
Methane
Monolith
Perovskite
Title Catalytic activity of powder and monolith perovskites in methane combustion
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