Aggregation of Giant Cerium–Bismuth Tungstate Clusters into a 3D Porous Framework with High Proton Conductivity

• Published in: Angewandte Chemie International Edition Vol. 57; no. 28; pp. 8416 - 8420
• Main Authors: Liu, Jian‐Cai, Han, Qing, Chen, Li‐Juan, Zhao, Jun‐Wei, Streb, Carsten, Song, Yu‐Fei
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 09.07.2018
• Edition: International ed. in English
• Subjects: Anions; Bismuth; Bismuth compounds; Cerium; Clusters; Conductivity; Crystal growth; Crystal lattices; Electrochemical impedance spectroscopy; Electrochemistry; Low temperature; Materials science; Metal oxides; Metals; Molecular chains; Organic chemistry; polyoxometalates; polyoxotungstate; porous materials; proton conduction; self-assembly; Spectroscopy; Tungstates; X-ray diffraction; polyoxotungstate; self-assembly; proton conduction; porous materials; polyoxometalates

The exploration of high nuclearity molecular metal oxide clusters and their reactivity is a challenge for chemistry and materials science. Herein, we report an unprecedented giant molecular cerium–bismuth tungstate superstructure formed by self‐assembly from simple metal oxide precursors in aqueous...