Desulfurization on Boron Nitride and Boron Nitride‐based Materials

• Published in: Chemistry, an Asian journal Vol. 15; no. 14; pp. 2038 - 2059
• Main Authors: Rajendran, Antony, Fan, Hong‐Xia, Feng, Jie, Li, Wen‐Ying
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 16.07.2020
• Subjects: 2D materials; Adsorptivity; Boron; Boron compounds; Boron nitride; Chemistry; clean liquid fuels; composites; Desulfurizing; hexagonal boron-nitride; Liquid fuels; Morphology; nanosheets; Physical properties; Porosity; Sulfur; Sulfur compounds; composites; clean liquid fuels; hexagonal boron-nitride; 2D materials; nanosheets
• ISSN: 1861-4728; 1861-471X
• DOI: 10.1002/asia.202000479

Combustion of liquid fuels containing sulfur compounds is highly unfavorable due to the adverse effects caused by the resultant SOx emission. Consequently, catalytic and adsorptive materials having the capacity to eliminate the sulfur compounds from liquid fuels are very attractive. Hexagonal boron nitride (BN), with its interesting chemical and physical properties, finds applications in diverse fields, especially in energy and environmental applications. Recently, BN and BN‐based materials have gained significant interest in emerging desulfurization processes such as oxidative desulfurization and adsorptive desulfurization. In this review, BN and BN‐based materials are elaborately discussed in the context of their use in various desulfurization techniques. A brief description about the different desulfurization processes is provided at the outset. The relationship between the characteristics (the defects, morphology, porosity and surface area) of BN and desulfurization efficiency is also summarized. Furthermore, the mechanistic insights regarding the action of BN materials in the desulfurization processes are discussed. With this review, the synthetic strategies for designing the novel BN‐based catalysts/adsorbents for the effective desulfurization of liquid fuels can be grasped. Designing materials for accomplishing sulfur‐free fuels is vibrant now. This review covers boron nitride (BN) and BN‐based materials that find applications in oxidative and adsorptive desulfurization. The impact of electronic and textural properties, doping, defect engineering and active‐sites incorporation on the desulfurization activity of BN‐materials are profoundly discussed along with the mechanistic pathways.