A Site‐Selective Doping Strategy of Carbon Anodes with Remarkable K‐Ion Storage Capacity
The limited potassium‐ion intercalation capacity of graphite hampers development of potassium‐ion batteries (PIB). Edge‐nitrogen doping is an effective approach to enhance K‐ion storage in carbonaceous materials. One shortcoming is the lack of precise control over producing the edge‐nitrogen configu...
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| Published in | Angewandte Chemie International Edition Vol. 59; no. 11; pp. 4448 - 4455 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
Wiley Subscription Services, Inc
09.03.2020
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| Edition | International ed. in English |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The limited potassium‐ion intercalation capacity of graphite hampers development of potassium‐ion batteries (PIB). Edge‐nitrogen doping is an effective approach to enhance K‐ion storage in carbonaceous materials. One shortcoming is the lack of precise control over producing the edge‐nitrogen configuration. Here, a molecular‐scale copolymer pyrolysis strategy is used to precisely control edge‐nitrogen doping in carbonaceous materials. This process results in defect‐rich, edge‐nitrogen doped carbons (ENDC) with a high nitrogen‐doping level (up to 10.5 at %) and a high edge‐nitrogen ratio (87.6 %). The optimized ENDC exhibits a high reversible capacity of 423 mAh g−1, a high initial Coulombic efficiency of 65 %, superior rate capability, and long cycle life (93.8 % retention after three months). This strategy can be extended to design other edge‐heteroatom‐rich carbons through pyrolysis of copolymers for efficient storage of various mobile ions.
Edge contributes more: A molecular scale edge‐nitrogen doping method is developed for synthesizing highly edge‐nitrogen‐doped carbons. This doped carbon shows a high nitrogen doping ratio of 10.5 at % (87.6 % edge‐nitrogen ratio), and a high, reversible, stable K‐ion storage capacity of 423 mAh g−1. |
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| AbstractList | The limited potassium‐ion intercalation capacity of graphite hampers development of potassium‐ion batteries (PIB). Edge‐nitrogen doping is an effective approach to enhance K‐ion storage in carbonaceous materials. One shortcoming is the lack of precise control over producing the edge‐nitrogen configuration. Here, a molecular‐scale copolymer pyrolysis strategy is used to precisely control edge‐nitrogen doping in carbonaceous materials. This process results in defect‐rich, edge‐nitrogen doped carbons (ENDC) with a high nitrogen‐doping level (up to 10.5 at %) and a high edge‐nitrogen ratio (87.6 %). The optimized ENDC exhibits a high reversible capacity of 423 mAh g−1, a high initial Coulombic efficiency of 65 %, superior rate capability, and long cycle life (93.8 % retention after three months). This strategy can be extended to design other edge‐heteroatom‐rich carbons through pyrolysis of copolymers for efficient storage of various mobile ions. The limited potassium‐ion intercalation capacity of graphite hampers development of potassium‐ion batteries (PIB). Edge‐nitrogen doping is an effective approach to enhance K‐ion storage in carbonaceous materials. One shortcoming is the lack of precise control over producing the edge‐nitrogen configuration. Here, a molecular‐scale copolymer pyrolysis strategy is used to precisely control edge‐nitrogen doping in carbonaceous materials. This process results in defect‐rich, edge‐nitrogen doped carbons (ENDC) with a high nitrogen‐doping level (up to 10.5 at %) and a high edge‐nitrogen ratio (87.6 %). The optimized ENDC exhibits a high reversible capacity of 423 mAh g−1, a high initial Coulombic efficiency of 65 %, superior rate capability, and long cycle life (93.8 % retention after three months). This strategy can be extended to design other edge‐heteroatom‐rich carbons through pyrolysis of copolymers for efficient storage of various mobile ions. Edge contributes more: A molecular scale edge‐nitrogen doping method is developed for synthesizing highly edge‐nitrogen‐doped carbons. This doped carbon shows a high nitrogen doping ratio of 10.5 at % (87.6 % edge‐nitrogen ratio), and a high, reversible, stable K‐ion storage capacity of 423 mAh g−1. The limited potassium‐ion intercalation capacity of graphite hampers development of potassium‐ion batteries (PIB). Edge‐nitrogen doping is an effective approach to enhance K‐ion storage in carbonaceous materials. One shortcoming is the lack of precise control over producing the edge‐nitrogen configuration. Here, a molecular‐scale copolymer pyrolysis strategy is used to precisely control edge‐nitrogen doping in carbonaceous materials. This process results in defect‐rich, edge‐nitrogen doped carbons (ENDC) with a high nitrogen‐doping level (up to 10.5 at %) and a high edge‐nitrogen ratio (87.6 %). The optimized ENDC exhibits a high reversible capacity of 423 mAh g −1 , a high initial Coulombic efficiency of 65 %, superior rate capability, and long cycle life (93.8 % retention after three months). This strategy can be extended to design other edge‐heteroatom‐rich carbons through pyrolysis of copolymers for efficient storage of various mobile ions. The limited potassium-ion intercalation capacity of graphite hampers development of potassium-ion batteries (PIB). Edge-nitrogen doping is an effective approach to enhance K-ion storage in carbonaceous materials. One shortcoming is the lack of precise control over producing the edge-nitrogen configuration. Here, a molecular-scale copolymer pyrolysis strategy is used to precisely control edge-nitrogen doping in carbonaceous materials. This process results in defect-rich, edge-nitrogen doped carbons (ENDC) with a high nitrogen-doping level (up to 10.5 at %) and a high edge-nitrogen ratio (87.6 %). The optimized ENDC exhibits a high reversible capacity of 423 mAh g-1 , a high initial Coulombic efficiency of 65 %, superior rate capability, and long cycle life (93.8 % retention after three months). This strategy can be extended to design other edge-heteroatom-rich carbons through pyrolysis of copolymers for efficient storage of various mobile ions.The limited potassium-ion intercalation capacity of graphite hampers development of potassium-ion batteries (PIB). Edge-nitrogen doping is an effective approach to enhance K-ion storage in carbonaceous materials. One shortcoming is the lack of precise control over producing the edge-nitrogen configuration. Here, a molecular-scale copolymer pyrolysis strategy is used to precisely control edge-nitrogen doping in carbonaceous materials. This process results in defect-rich, edge-nitrogen doped carbons (ENDC) with a high nitrogen-doping level (up to 10.5 at %) and a high edge-nitrogen ratio (87.6 %). The optimized ENDC exhibits a high reversible capacity of 423 mAh g-1 , a high initial Coulombic efficiency of 65 %, superior rate capability, and long cycle life (93.8 % retention after three months). This strategy can be extended to design other edge-heteroatom-rich carbons through pyrolysis of copolymers for efficient storage of various mobile ions. The limited potassium-ion intercalation capacity of graphite hampers development of potassium-ion batteries (PIB). Edge-nitrogen doping is an effective approach to enhance K-ion storage in carbonaceous materials. One shortcoming is the lack of precise control over producing the edge-nitrogen configuration. Here, a molecular-scale copolymer pyrolysis strategy is used to precisely control edge-nitrogen doping in carbonaceous materials. This process results in defect-rich, edge-nitrogen doped carbons (ENDC) with a high nitrogen-doping level (up to 10.5 at %) and a high edge-nitrogen ratio (87.6 %). The optimized ENDC exhibits a high reversible capacity of 423 mAh g , a high initial Coulombic efficiency of 65 %, superior rate capability, and long cycle life (93.8 % retention after three months). This strategy can be extended to design other edge-heteroatom-rich carbons through pyrolysis of copolymers for efficient storage of various mobile ions. |
| Author | Alhajji, Eman Costa, Pedro M. F. J. Cavallo, Luigi Zhang, Wenli Emwas, Abdul‐Hamid Alshareef, Husam N. Cao, Zhen Wang, Wenxi |
| Author_xml | – sequence: 1 givenname: Wenli orcidid: 0000-0002-6781-2826 surname: Zhang fullname: Zhang, Wenli organization: King Abdullah University of Science and Technology (KAUST) – sequence: 2 givenname: Zhen surname: Cao fullname: Cao, Zhen organization: King Abdullah University of Science and Technology (KAUST) – sequence: 3 givenname: Wenxi surname: Wang fullname: Wang, Wenxi organization: King Abdullah University of Science and Technology (KAUST) – sequence: 4 givenname: Eman surname: Alhajji fullname: Alhajji, Eman organization: King Abdullah University of Science and Technology (KAUST) – sequence: 5 givenname: Abdul‐Hamid orcidid: 0000-0002-9231-3850 surname: Emwas fullname: Emwas, Abdul‐Hamid organization: King Abdullah University of Science and Technology (KAUST) – sequence: 6 givenname: Pedro M. F. J. surname: Costa fullname: Costa, Pedro M. F. J. organization: King Abdullah University of Science and Technology (KAUST) – sequence: 7 givenname: Luigi orcidid: 0000-0002-1398-338X surname: Cavallo fullname: Cavallo, Luigi organization: King Abdullah University of Science and Technology (KAUST) – sequence: 8 givenname: Husam N. orcidid: 0000-0001-5029-2142 surname: Alshareef fullname: Alshareef, Husam N. email: husam.alshareef@kaust.edu.sa organization: King Abdullah University of Science and Technology (KAUST) |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31943603$$D View this record in MEDLINE/PubMed |
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| Snippet | The limited potassium‐ion intercalation capacity of graphite hampers development of potassium‐ion batteries (PIB). Edge‐nitrogen doping is an effective... The limited potassium-ion intercalation capacity of graphite hampers development of potassium-ion batteries (PIB). Edge-nitrogen doping is an effective... |
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| SubjectTerms | adsorption energy anodes carbon Carbonaceous materials Copolymers Doping Ion storage Nitrogen nitrogen doping Potassium potassium-ion batteries Pyrolysis Rechargeable batteries Storage capacity Strategy |
| Title | A Site‐Selective Doping Strategy of Carbon Anodes with Remarkable K‐Ion Storage Capacity |
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