A Multiple Chirality Switching Device for Spatial Light Modulators

A new and simple strategy towards electric‐field‐driven multiple chirality switching device has been designed and fabricated by combining a newly synthesized base‐responsive chiroptical polymer switch (R‐FLMA) and p‐benzoquinone (p‐BQ) via proton‐coupled electron transfer (PCET) mechanism. Clear and...

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Published inAngewandte Chemie International Edition Vol. 60; no. 4; pp. 2018 - 2023
Main Authors Yang, Guojian, Yu, Yang, Yang, Baige, Lu, Tong, Cai, Yiru, Yin, Hang, Zhang, Huiqi, Zhang, Ning‐Ning, Li, Li, Zhang, Yu‐Mo, Zhang, Sean Xiao‐An
Format Journal Article
LanguageEnglish
Published WEINHEIM Wiley 25.01.2021
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Benzoquinone
Chemistry
Chemistry, Multidisciplinary
Chirality
chirality switching device
electrobase/acid
electrofluorochromism
Electron transfer
Fluorescence
Physical Sciences
Polymers
proton-coupled electron transfer
Science & Technology
Spatial light modulators
Switching
acid
CIRCULARLY-POLARIZED LUMINESCENCE
electrobase
proton-coupled electron transfer
RECOGNITION
chirality switching device
electrofluorochromism
LIQUID-CRYSTALS
SUPRAMOLECULAR GELS
INVERSION
spatial light modulators
electrobase/acid
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Abstract A new and simple strategy towards electric‐field‐driven multiple chirality switching device has been designed and fabricated by combining a newly synthesized base‐responsive chiroptical polymer switch (R‐FLMA) and p‐benzoquinone (p‐BQ) via proton‐coupled electron transfer (PCET) mechanism. Clear and stable triple chirality states (silence, positive, negative) of this device in visible band can be regulated reversibly (>1000 cycles) by adjusting voltage programs. Furthermore, such chiral switching phenomena are also accompanied by apparent changes of color and fluorescence. More importantly, the potential application of this device for a spatial light modulator has also been demonstrated. A simple and new strategy towards electric‐field‐driven multiple chirality switching material and device for spatial light modulators has been developed successfully based on the proton‐coupled electron transfer (PCET) mechanism.
AbstractList A new and simple strategy towards electric‐field‐driven multiple chirality switching device has been designed and fabricated by combining a newly synthesized base‐responsive chiroptical polymer switch (R‐FLMA) and p‐benzoquinone (p‐BQ) via proton‐coupled electron transfer (PCET) mechanism. Clear and stable triple chirality states (silence, positive, negative) of this device in visible band can be regulated reversibly (>1000 cycles) by adjusting voltage programs. Furthermore, such chiral switching phenomena are also accompanied by apparent changes of color and fluorescence. More importantly, the potential application of this device for a spatial light modulator has also been demonstrated. A simple and new strategy towards electric‐field‐driven multiple chirality switching material and device for spatial light modulators has been developed successfully based on the proton‐coupled electron transfer (PCET) mechanism.
A new and simple strategy towards electric-field-driven multiple chirality switching device has been designed and fabricated by combining a newly synthesized base-responsive chiroptical polymer switch (R-FLMA) and p-benzoquinone (p-BQ) via proton-coupled electron transfer (PCET) mechanism. Clear and stable triple chirality states (silence, positive, negative) of this device in visible band can be regulated reversibly (>1000 cycles) by adjusting voltage programs. Furthermore, such chiral switching phenomena are also accompanied by apparent changes of color and fluorescence. More importantly, the potential application of this device for a spatial light modulator has also been demonstrated.
Abstract A new and simple strategy towards electric‐field‐driven multiple chirality switching device has been designed and fabricated by combining a newly synthesized base‐responsive chiroptical polymer switch (R‐FLMA) and p‐benzoquinone (p‐BQ) via proton‐coupled electron transfer (PCET) mechanism. Clear and stable triple chirality states (silence, positive, negative) of this device in visible band can be regulated reversibly (>1000 cycles) by adjusting voltage programs. Furthermore, such chiral switching phenomena are also accompanied by apparent changes of color and fluorescence. More importantly, the potential application of this device for a spatial light modulator has also been demonstrated.
Author Yang, Baige
Yu, Yang
Li, Li
Lu, Tong
Zhang, Ning‐Ning
Zhang, Yu‐Mo
Zhang, Huiqi
Cai, Yiru
Yin, Hang
Yang, Guojian
Zhang, Sean Xiao‐An
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Issue 4
Keywords acid
CIRCULARLY-POLARIZED LUMINESCENCE
electrobase
proton-coupled electron transfer
RECOGNITION
chirality switching device
electrofluorochromism
LIQUID-CRYSTALS
SUPRAMOLECULAR GELS
INVERSION
spatial light modulators
electrobase/acid
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Snippet A new and simple strategy towards electric‐field‐driven multiple chirality switching device has been designed and fabricated by combining a newly synthesized...
A new and simple strategy towards electric-field-driven multiple chirality switching device has been designed and fabricated by combining a newly synthesized...
Abstract A new and simple strategy towards electric‐field‐driven multiple chirality switching device has been designed and fabricated by combining a newly...
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StartPage 2018
SubjectTerms Benzoquinone
Chemistry
Chemistry, Multidisciplinary
Chirality
chirality switching device
electrobase/acid
electrofluorochromism
Electron transfer
Fluorescence
Physical Sciences
Polymers
proton-coupled electron transfer
Science & Technology
Spatial light modulators
Switching
Title A Multiple Chirality Switching Device for Spatial Light Modulators
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.202009916
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=FullRecord&UT=000579090500001
https://www.ncbi.nlm.nih.gov/pubmed/32885573
https://www.proquest.com/docview/2478445039/abstract/
https://search.proquest.com/docview/2440465724
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