Stereoselective Transfer Semi‐Hydrogenation of Alkynes to E‐Olefins with N‐Heterocyclic Silylene–Manganese Catalysts
The synthesis and structures of the first SiII‐donor supported manganese(II) complexes [L1]MnCl2, [L2]MnCl2, and [L3]2MnCl2 are reported, bearing a pincer‐type bis(NHSi)‐pyridine ligand L1, bidentate bis(NHSi)‐ferrocene ligand L2, and two monodentate NHSi ligands L3 (NHSi = N‐heterocyclic silylene),...
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| Published in | Chemistry : a European journal Vol. 24; no. 19; pp. 4780 - 4784 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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Wiley Subscription Services, Inc
03.04.2018
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| Abstract | The synthesis and structures of the first SiII‐donor supported manganese(II) complexes [L1]MnCl2, [L2]MnCl2, and [L3]2MnCl2 are reported, bearing a pincer‐type bis(NHSi)‐pyridine ligand L1, bidentate bis(NHSi)‐ferrocene ligand L2, and two monodentate NHSi ligands L3 (NHSi = N‐heterocyclic silylene), respectively. They act as unprecedented very active and stereoselective Mn‐based precatalysts (1 mol % loading) in transfer semi‐hydrogenations of alkynes to give the corresponding E‐olefins using ammonia–borane as a convenient hydrogen source under mild reaction conditions. Complex [L1]MnCl2 shows the best catalytic performance with quantitative conversion rates and excellent E‐stereoselectivities (up to 98 %) for different alkyne substrates. Different types of functional groups can be tolerated, except CN, NH2, NO2, and OH groups at the phenyl group of 1‐phenyl substituted alkynes.
Give me the E: The first N‐heterocyclic silylene (NHSi)–manganese(II) complexes have been synthesized and fully characterized. Among them, the [L1]MnCl2 complex, which bear bis‐NHSi pyridine pincer ligand L1, acts as a superior precatalysts in homogeneous transfer semi‐hydrogenation of alkynes, using ammonia‐borane as a convenient hydrogen source at mild reaction conditions ([Mn]=[L1]MnCl2). |
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| AbstractList | The synthesis and structures of the first Si
II
‐donor supported manganese(II) complexes
[L1]MnCl
2
,
[L2]MnCl
2
, and
[L3]
2
MnCl
2
are reported, bearing a pincer‐type bis(NHSi)‐pyridine ligand
L1
, bidentate bis(NHSi)‐ferrocene ligand
L2
, and two monodentate NHSi ligands
L3
(NHSi =
N
‐heterocyclic silylene), respectively. They act as unprecedented very active and stereoselective Mn‐based precatalysts (1 mol % loading) in transfer semi‐hydrogenations of alkynes to give the corresponding
E
‐olefins using ammonia–borane as a convenient hydrogen source under mild reaction conditions. Complex
[L1]MnCl
2
shows the best catalytic performance with quantitative conversion rates and excellent
E
‐stereoselectivities (up to 98 %) for different alkyne substrates. Different types of functional groups can be tolerated, except CN, NH
2
, NO
2
, and OH groups at the phenyl group of 1‐phenyl substituted alkynes. The synthesis and structures of the first SiII‐donor supported manganese(II) complexes [L1]MnCl2, [L2]MnCl2, and [L3]2MnCl2 are reported, bearing a pincer‐type bis(NHSi)‐pyridine ligand L1, bidentate bis(NHSi)‐ferrocene ligand L2, and two monodentate NHSi ligands L3 (NHSi = N‐heterocyclic silylene), respectively. They act as unprecedented very active and stereoselective Mn‐based precatalysts (1 mol % loading) in transfer semi‐hydrogenations of alkynes to give the corresponding E‐olefins using ammonia–borane as a convenient hydrogen source under mild reaction conditions. Complex [L1]MnCl2 shows the best catalytic performance with quantitative conversion rates and excellent E‐stereoselectivities (up to 98 %) for different alkyne substrates. Different types of functional groups can be tolerated, except CN, NH2, NO2, and OH groups at the phenyl group of 1‐phenyl substituted alkynes. The synthesis and structures of the first SiII -donor supported manganese(II) complexes [L1]MnCl2 , [L2]MnCl2 , and [L3]2 MnCl2 are reported, bearing a pincer-type bis(NHSi)-pyridine ligand L1, bidentate bis(NHSi)-ferrocene ligand L2, and two monodentate NHSi ligands L3 (NHSi = N-heterocyclic silylene), respectively. They act as unprecedented very active and stereoselective Mn-based precatalysts (1 mol % loading) in transfer semi-hydrogenations of alkynes to give the corresponding E-olefins using ammonia-borane as a convenient hydrogen source under mild reaction conditions. Complex [L1]MnCl2 shows the best catalytic performance with quantitative conversion rates and excellent E-stereoselectivities (up to 98 %) for different alkyne substrates. Different types of functional groups can be tolerated, except CN, NH2 , NO2 , and OH groups at the phenyl group of 1-phenyl substituted alkynes.The synthesis and structures of the first SiII -donor supported manganese(II) complexes [L1]MnCl2 , [L2]MnCl2 , and [L3]2 MnCl2 are reported, bearing a pincer-type bis(NHSi)-pyridine ligand L1, bidentate bis(NHSi)-ferrocene ligand L2, and two monodentate NHSi ligands L3 (NHSi = N-heterocyclic silylene), respectively. They act as unprecedented very active and stereoselective Mn-based precatalysts (1 mol % loading) in transfer semi-hydrogenations of alkynes to give the corresponding E-olefins using ammonia-borane as a convenient hydrogen source under mild reaction conditions. Complex [L1]MnCl2 shows the best catalytic performance with quantitative conversion rates and excellent E-stereoselectivities (up to 98 %) for different alkyne substrates. Different types of functional groups can be tolerated, except CN, NH2 , NO2 , and OH groups at the phenyl group of 1-phenyl substituted alkynes. The synthesis and structures of the first SiII‐donor supported manganese(II) complexes [L1]MnCl2, [L2]MnCl2, and [L3]2MnCl2 are reported, bearing a pincer‐type bis(NHSi)‐pyridine ligand L1, bidentate bis(NHSi)‐ferrocene ligand L2, and two monodentate NHSi ligands L3 (NHSi = N‐heterocyclic silylene), respectively. They act as unprecedented very active and stereoselective Mn‐based precatalysts (1 mol % loading) in transfer semi‐hydrogenations of alkynes to give the corresponding E‐olefins using ammonia–borane as a convenient hydrogen source under mild reaction conditions. Complex [L1]MnCl2 shows the best catalytic performance with quantitative conversion rates and excellent E‐stereoselectivities (up to 98 %) for different alkyne substrates. Different types of functional groups can be tolerated, except CN, NH2, NO2, and OH groups at the phenyl group of 1‐phenyl substituted alkynes. Give me the E: The first N‐heterocyclic silylene (NHSi)–manganese(II) complexes have been synthesized and fully characterized. Among them, the [L1]MnCl2 complex, which bear bis‐NHSi pyridine pincer ligand L1, acts as a superior precatalysts in homogeneous transfer semi‐hydrogenation of alkynes, using ammonia‐borane as a convenient hydrogen source at mild reaction conditions ([Mn]=[L1]MnCl2). The synthesis and structures of the first Si -donor supported manganese(II) complexes [L1]MnCl , [L2]MnCl , and [L3] MnCl are reported, bearing a pincer-type bis(NHSi)-pyridine ligand L1, bidentate bis(NHSi)-ferrocene ligand L2, and two monodentate NHSi ligands L3 (NHSi = N-heterocyclic silylene), respectively. They act as unprecedented very active and stereoselective Mn-based precatalysts (1 mol % loading) in transfer semi-hydrogenations of alkynes to give the corresponding E-olefins using ammonia-borane as a convenient hydrogen source under mild reaction conditions. Complex [L1]MnCl shows the best catalytic performance with quantitative conversion rates and excellent E-stereoselectivities (up to 98 %) for different alkyne substrates. Different types of functional groups can be tolerated, except CN, NH , NO , and OH groups at the phenyl group of 1-phenyl substituted alkynes. |
| Author | Mo, Zhenbo Driess, Matthias Zhou, Yu‐Peng Luecke, Marcel‐Philip |
| Author_xml | – sequence: 1 givenname: Yu‐Peng surname: Zhou fullname: Zhou, Yu‐Peng organization: Technische Universität Berlin – sequence: 2 givenname: Zhenbo surname: Mo fullname: Mo, Zhenbo organization: Technische Universität Berlin – sequence: 3 givenname: Marcel‐Philip surname: Luecke fullname: Luecke, Marcel‐Philip organization: Technische Universität Berlin – sequence: 4 givenname: Matthias orcidid: 0000-0002-9873-4103 surname: Driess fullname: Driess, Matthias email: matthias.driess@tu-berlin.de organization: Technische Universität Berlin |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29228457$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1021/jacs.6b04271 10.1021/om400805v 10.1021/acs.chemrev.5b00340 10.1002/ejoc.201700376 10.1002/cssc.201601057 10.1002/ange.201306629 10.1016/j.ccr.2015.06.015 10.1021/ja402480v 10.1016/j.jorganchem.2016.07.014 10.1039/b108132b 10.1002/anie.201205946 10.1039/dt9760000714 10.1002/anie.201608345 10.1002/anie.201409739 10.1016/j.ces.2017.05.021 10.1039/C6CC09067B 10.1002/cssc.201402812 10.1002/ange.200301628 10.1021/ol501137x 10.15227/orgsyn.046.0089 10.1002/anie.201607579 10.1002/ange.201606979 10.1002/anie.201606218 10.1021/ja4116346 10.1021/acs.organomet.5b00684 10.1002/ange.201609520 10.1021/jacs.6b03709 10.1016/j.catcom.2016.12.017 10.1002/cctc.201000126 10.1002/ange.201409739 10.1002/anie.201506075 10.1002/anie.201702406 10.1039/C7DT03301J 10.1021/acs.orglett.7b00935 10.1002/anie.201705471 10.1002/ange.201202175 10.1002/adsc.201300905 10.1021/acs.organomet.6b00356 10.1021/om900458e 10.1021/ja408137t 10.1002/anie.201609520 10.1002/anie.201607233 10.1002/anie.201205570 10.1021/ja408397v 10.1002/ange.201704184 10.1021/acs.joc.5b01047 10.1002/chem.201605937 10.1002/ejic.201700148 10.1002/cctc.201700042 10.1021/acs.chemrev.5b00203 10.1002/ange.201608345 10.1002/ange.201607579 10.1021/acs.chemrev.6b00043 10.1021/acs.orglett.6b02610 10.1002/zaac.200900313 10.1002/ange.201205570 10.1021/ol4001679 10.1002/anie.200906302 10.1021/acscatal.6b01045 10.1021/jacs.7b07167 10.1021/acscatal.5b02953 10.1039/B802882F 10.1039/C3QI00079F 10.1021/om500966t 10.1021/jacs.7b00879 10.1002/chem.201701442 10.1038/nature09913 10.1002/anie.201306629 10.1016/S0022-328X(00)81751-9 10.1039/C5SC02855H 10.1002/ange.201702406 10.1021/acscatal.7b00943 10.1002/ange.201607233 10.1002/anie.200301628 10.1021/acs.orglett.6b03254 10.1021/ja00360a054 10.1002/ange.201506075 10.1002/chem.201604991 10.1016/j.ica.2016.02.064 10.1002/ange.201606218 10.1002/anie.201709441 10.1016/j.apcata.2010.06.052 10.1021/cr100088b 10.1002/anie.201606979 10.1021/ic00188a003 10.1021/jacs.6b07245 10.1021/jacs.6b08128 10.1002/anie.201704184 10.1039/C4RA14417A 10.1002/ange.200906302 10.1002/ejic.200300832 10.1039/C4CC08163C 10.1002/anie.201202175 10.1002/ange.201705471 10.1002/ange.201205946 |
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| Copyright | 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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| Keywords | N-heterocyclic silylene transfer semi-hydrogenation E-olefins manganese stereoselective catalysis |
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| References | 2015; 34 2017; 7 2016; 308 2017; 46 1984; 23 1976 2010; 385 2015; 80 2009; 635 2017; 9 2014; 136 2013 2013; 52 125 2011; 473 2014; 1 1983; 105 2013; 15 2001 2017; 36 2012 2012; 51 124 1973; 47 2014; 16 2010; 110 2015 2015; 54 127 2016; 116 2010; 2 2015; 6 2015; 5 2017; 2017 2015; 51 2010; 39 2017; 23 2017; 171 2010 2010; 49 122 2004 2003 2003; 42 115 2017 2017; 56 129 2016; 18 2015; 8 2017; 455 2014; 356 2017; 139 2009; 28 2016; 6 2017; 53 2016 2016; 55 128 2017; 829 2017; 92 2015; 115 2013; 32 2017; 10 2017; 56 2013; 135 2017 2017; 19 2016; 138 2015 2015 2015; 54 127 127 1966; 46 2014; 33 e_1_2_2_24_2 e_1_2_2_47_2 e_1_2_2_6_1 e_1_2_2_20_1 e_1_2_2_2_2 e_1_2_2_62_2 e_1_2_2_85_2 e_1_2_2_28_2 e_1_2_2_43_2 e_1_2_2_66_2 e_1_2_2_66_1 e_1_2_2_89_1 e_1_2_2_81_2 e_1_2_2_81_3 e_1_2_2_13_2 e_1_2_2_59_2 e_1_2_2_51_2 e_1_2_2_74_2 e_1_2_2_51_3 e_1_2_2_17_2 e_1_2_2_32_2 e_1_2_2_55_2 e_1_2_2_78_2 e_1_2_2_36_1 e_1_2_2_70_1 e_1_2_2_48_2 e_1_2_2_5_2 e_1_2_2_21_1 e_1_2_2_1_1 e_1_2_2_40_2 e_1_2_2_86_2 e_1_2_2_29_2 e_1_2_2_63_2 e_1_2_2_44_1 e_1_2_2_67_1 e_1_2_2_9_3 e_1_2_2_9_2 e_1_2_2_25_2 e_1_2_2_82_2 e_1_2_2_37_2 e_1_2_2_10_3 e_1_2_2_10_2 e_1_2_2_75_2 e_1_2_2_18_2 e_1_2_2_52_2 e_1_2_2_56_1 e_1_2_2_33_2 e_1_2_2_79_2 e_1_2_2_33_3 e_1_2_2_14_2 e_1_2_2_71_1 e_1_2_2_4_2 e_1_2_2_22_2 e_1_2_2_49_2 e_1_2_2_49_3 e_1_2_2_41_1 e_1_2_2_60_3 e_1_2_2_83_2 e_1_2_2_64_1 e_1_2_2_8_2 e_1_2_2_26_2 e_1_2_2_45_2 e_1_2_2_87_2 e_1_2_2_45_3 e_1_2_2_68_1 e_1_2_2_60_2 e_1_2_2_11_2 e_1_2_2_38_2 e_1_2_2_19_2 e_1_2_2_30_2 e_1_2_2_19_1 e_1_2_2_30_3 e_1_2_2_53_1 e_1_2_2_30_4 e_1_2_2_15_3 e_1_2_2_15_2 e_1_2_2_34_2 e_1_2_2_57_2 e_1_2_2_76_2 e_1_2_2_34_3 e_1_2_2_72_1 e_1_2_2_3_2 e_1_2_2_23_2 e_1_2_2_61_3 e_1_2_2_84_3 e_1_2_2_61_2 e_1_2_2_65_1 e_1_2_2_42_2 e_1_2_2_84_2 e_1_2_2_7_2 e_1_2_2_27_2 e_1_2_2_69_1 e_1_2_2_88_1 e_1_2_2_46_2 e_1_2_2_80_2 e_1_2_2_12_2 e_1_2_2_58_2 e_1_2_2_39_2 e_1_2_2_50_3 e_1_2_2_50_2 e_1_2_2_73_1 e_1_2_2_31_2 e_1_2_2_16_3 e_1_2_2_16_2 e_1_2_2_54_2 e_1_2_2_35_1 e_1_2_2_77_1 |
| References_xml | – volume: 18 start-page: 5189 year: 2016 end-page: 5191 publication-title: Org. Lett. – volume: 9 start-page: 1744 year: 2017 end-page: 1748 publication-title: ChemCatChem – start-page: 2673 year: 2004 end-page: 2677 publication-title: Eur. J. Inorg. Chem. – volume: 54 127 127 start-page: 12431 12608 12608 year: 2015 2015 2015 end-page: 12436 12613 12613 publication-title: Angew. Chem. Int. Ed. Angew. Chem. Angew. Chem. – volume: 138 start-page: 13700 year: 2016 end-page: 13705 publication-title: J. Am. Chem. Soc. – volume: 56 129 start-page: 11237 11389 year: 2017 2017 end-page: 11241 11393 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 10 start-page: 83 year: 2017 end-page: 86 publication-title: ChemSusChem – volume: 8 start-page: 776 year: 2015 end-page: 785 publication-title: ChemSusChem – start-page: 2372 year: 2001 end-page: 2373 publication-title: Chem. Commun. – volume: 6 start-page: 7143 year: 2015 end-page: 7149 publication-title: Chem. Sci. – volume: 7 start-page: 3864 year: 2017 end-page: 3868 publication-title: ACS Catal. – volume: 18 start-page: 6196 year: 2016 end-page: 6199 publication-title: Org. Lett. – volume: 138 start-page: 8809 year: 2016 end-page: 8814 publication-title: J. Am. Chem. Soc. – volume: 135 start-page: 15617 year: 2013 end-page: 15626 publication-title: J. Am. Chem. Soc. – volume: 80 start-page: 6922 year: 2015 end-page: 6929 publication-title: J. Org. Chem. – volume: 1 start-page: 134 year: 2014 end-page: 148 publication-title: Inorg. Chem. Front. – volume: 55 128 start-page: 15096 15320 year: 2016 2016 end-page: 15099 15323 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 52 125 start-page: 14131 14381 year: 2013 2013 end-page: 14134 14384 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 473 start-page: 55 year: 2011 end-page: 60 publication-title: Nature – volume: 6 start-page: 4710 year: 2016 end-page: 4714 publication-title: ACS Catal. – volume: 54 127 start-page: 2214 2242 year: 2015 2015 end-page: 2218 2246 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 6 start-page: 2121 year: 2016 end-page: 2125 publication-title: ACS Catal. – volume: 32 start-page: 5034 year: 2013 end-page: 5037 publication-title: Organometallics – volume: 105 start-page: 6752 year: 1983 end-page: 6753 publication-title: J. Am. Chem. Soc. – volume: 47 start-page: 403 year: 1973 end-page: 412 publication-title: J. Organomet. Chem. – volume: 138 start-page: 8588 year: 2016 end-page: 8594 publication-title: J. Am. Chem. Soc. – volume: 55 128 start-page: 12868 13060 year: 2016 2016 end-page: 12872 13064 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 55 128 start-page: 11806 11984 year: 2016 2016 end-page: 11809 11988 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 46 start-page: 16412 year: 2017 end-page: 16418 publication-title: Dalton Trans. – volume: 139 start-page: 4901 year: 2017 end-page: 4915 publication-title: J. Am. Chem. Soc. – volume: 136 start-page: 882 year: 2014 end-page: 885 publication-title: J. Am. Chem. Soc. – volume: 115 start-page: 6621 year: 2015 end-page: 6686 publication-title: Chem. Rev. – volume: 23 start-page: 5934 year: 2017 end-page: 5938 publication-title: Chem. Eur. J. – volume: 55 128 start-page: 14369 14581 year: 2016 2016 end-page: 14372 14584 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 5 start-page: 5077 year: 2015 end-page: 5086 publication-title: RSC Adv. – volume: 356 start-page: 1093 year: 2014 end-page: 1097 publication-title: Adv. Synth. Catal. – start-page: 714 year: 1976 end-page: 719 publication-title: J. Chem. Soc. Dalton Trans. – volume: 15 start-page: 1112 year: 2013 end-page: 1115 publication-title: Org. Lett. – volume: 56 start-page: 15901 year: 2017 end-page: 15904 publication-title: Angew. Chem. Int. Ed. – volume: 171 start-page: 404 year: 2017 end-page: 425 publication-title: Chem. Eng. Sci. – volume: 52 125 start-page: 355 373 year: 2013 2013 end-page: 360 378 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 34 start-page: 5088 year: 2015 end-page: 5094 publication-title: Organometallics – volume: 455 start-page: 707 year: 2017 end-page: 714 publication-title: Inorg. Chim. Acta – volume: 110 start-page: 4079 year: 2010 end-page: 4124 publication-title: Chem. Rev. – volume: 23 start-page: 5663 year: 2017 end-page: 5667 publication-title: Chem. Eur. J. – volume: 16 start-page: 3020 year: 2014 end-page: 3023 publication-title: Org. Lett. – start-page: 4344 year: 2017 end-page: 4362 publication-title: Eur. J. Org. Chem. – volume: 138 start-page: 12956 year: 2016 end-page: 12962 publication-title: J. Am. Chem. Soc. – volume: 385 start-page: 108 year: 2010 end-page: 113 publication-title: Appl. Catal. A – volume: 2017 start-page: 1284 year: 2017 end-page: 1291 publication-title: Eur. J. Inorg. Chem. – volume: 308 start-page: 191 year: 2016 end-page: 235 publication-title: Coord. Chem. Rev. – volume: 51 start-page: 2384 year: 2015 end-page: 2387 publication-title: Chem. Commun. – volume: 2 start-page: 724 year: 2010 end-page: 761 publication-title: ChemCatChem – volume: 39 start-page: 656 year: 2010 end-page: 675 publication-title: Chem. Soc. Rev. – volume: 116 start-page: 8848 year: 2016 end-page: 8872 publication-title: Chem. Rev. – volume: 135 start-page: 6703 year: 2013 end-page: 6713 publication-title: J. Am. Chem. Soc. – volume: 135 start-page: 15310 year: 2013 end-page: 15313 publication-title: J. Am. Chem. Soc. – volume: 46 start-page: 89 year: 1966 publication-title: Org. Synth. – volume: 23 start-page: 11560 year: 2017 end-page: 11569 publication-title: Chem. Eur. J. – volume: 635 start-page: 2503 year: 2009 end-page: 2510 publication-title: Z. Anorg. Allg. Chem. – volume: 51 124 start-page: 11478 11645 year: 2012 2012 end-page: 11482 11649 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 92 start-page: 1 year: 2017 end-page: 4 publication-title: Catal. Commun. – volume: 23 start-page: 3043 year: 1984 end-page: 3044 publication-title: Inorg. Chem. – volume: 56 129 start-page: 5825 5919 year: 2017 2017 end-page: 5828 5922 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 53 start-page: 732 year: 2017 end-page: 735 publication-title: Chem. Commun. – volume: 139 start-page: 13499 year: 2017 end-page: 13506 publication-title: J. Am. Chem. Soc. – volume: 56 129 start-page: 8393 8513 year: 2017 2017 end-page: 8397 8517 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 19 start-page: 2604 year: 2017 end-page: 2606 publication-title: Org. Lett. – volume: 55 128 start-page: 14653 14873 year: 2016 2016 end-page: 14657 14877 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 829 start-page: 2 year: 2017 end-page: 10 publication-title: J. Organomet. Chem. – volume: 33 start-page: 6885 year: 2014 end-page: 6897 publication-title: Organometallics – volume: 36 start-page: 220 year: 2017 end-page: 227 publication-title: Organometallics – volume: 51 124 start-page: 6167 6271 year: 2012 2012 end-page: 6171 6275 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 28 start-page: 5493 year: 2009 end-page: 5504 publication-title: Organometallics – volume: 55 128 start-page: 15364 15590 year: 2016 2016 end-page: 15368 15594 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 116 start-page: 2886 year: 2016 end-page: 2936 publication-title: Chem. Rev. – volume: 49 122 start-page: 2058 2102 year: 2010 2010 end-page: 2062 2106 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 42 115 start-page: 2826 2932 year: 2003 2003 end-page: 2830 2936 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – ident: e_1_2_2_77_1 – ident: e_1_2_2_28_2 doi: 10.1021/jacs.6b04271 – ident: e_1_2_2_62_2 doi: 10.1021/om400805v – ident: e_1_2_2_37_2 doi: 10.1021/acs.chemrev.5b00340 – ident: e_1_2_2_43_2 doi: 10.1002/ejoc.201700376 – ident: e_1_2_2_55_2 doi: 10.1002/cssc.201601057 – ident: e_1_2_2_33_3 doi: 10.1002/ange.201306629 – ident: e_1_2_2_42_2 doi: 10.1016/j.ccr.2015.06.015 – ident: e_1_2_2_14_2 doi: 10.1021/ja402480v – ident: e_1_2_2_2_2 doi: 10.1016/j.jorganchem.2016.07.014 – ident: e_1_2_2_5_2 doi: 10.1039/b108132b – ident: e_1_2_2_34_2 doi: 10.1002/anie.201205946 – ident: e_1_2_2_71_1 doi: 10.1039/dt9760000714 – ident: e_1_2_2_81_2 doi: 10.1002/anie.201608345 – ident: e_1_2_2_10_2 doi: 10.1002/anie.201409739 – ident: e_1_2_2_22_2 doi: 10.1016/j.ces.2017.05.021 – ident: e_1_2_2_79_2 doi: 10.1039/C6CC09067B – ident: e_1_2_2_39_2 doi: 10.1002/cssc.201402812 – ident: e_1_2_2_38_2 – ident: e_1_2_2_19_2 doi: 10.1002/ange.200301628 – ident: e_1_2_2_31_2 doi: 10.1021/ol501137x – ident: e_1_2_2_20_1 doi: 10.15227/orgsyn.046.0089 – ident: e_1_2_2_61_2 doi: 10.1002/anie.201607579 – ident: e_1_2_2_9_3 doi: 10.1002/ange.201606979 – ident: e_1_2_2_50_2 doi: 10.1002/anie.201606218 – ident: e_1_2_2_59_2 doi: 10.1021/ja4116346 – ident: e_1_2_2_44_1 – ident: e_1_2_2_65_1 doi: 10.1021/acs.organomet.5b00684 – ident: e_1_2_2_66_2 doi: 10.1002/ange.201609520 – ident: e_1_2_2_48_2 doi: 10.1021/jacs.6b03709 – ident: e_1_2_2_47_2 doi: 10.1016/j.catcom.2016.12.017 – ident: e_1_2_2_40_2 doi: 10.1002/cctc.201000126 – ident: e_1_2_2_10_3 doi: 10.1002/ange.201409739 – ident: e_1_2_2_30_2 doi: 10.1002/anie.201506075 – ident: e_1_2_2_45_2 doi: 10.1002/anie.201702406 – ident: e_1_2_2_18_2 doi: 10.1039/C7DT03301J – ident: e_1_2_2_78_2 doi: 10.1021/acs.orglett.7b00935 – ident: e_1_2_2_51_2 doi: 10.1002/anie.201705471 – ident: e_1_2_2_15_3 doi: 10.1002/ange.201202175 – ident: e_1_2_2_58_2 doi: 10.1002/adsc.201300905 – ident: e_1_2_2_23_2 doi: 10.1021/acs.organomet.6b00356 – ident: e_1_2_2_86_2 doi: 10.1021/om900458e – ident: e_1_2_2_13_2 doi: 10.1021/ja408137t – ident: e_1_2_2_66_1 doi: 10.1002/anie.201609520 – ident: e_1_2_2_56_1 – ident: e_1_2_2_53_1 – ident: e_1_2_2_49_2 doi: 10.1002/anie.201607233 – ident: e_1_2_2_16_2 doi: 10.1002/anie.201205570 – ident: e_1_2_2_83_2 doi: 10.1021/ja408397v – ident: e_1_2_2_60_3 doi: 10.1002/ange.201704184 – ident: e_1_2_2_29_2 doi: 10.1021/acs.joc.5b01047 – ident: e_1_2_2_8_2 doi: 10.1002/chem.201605937 – ident: e_1_2_2_21_1 – ident: e_1_2_2_7_2 doi: 10.1002/ejic.201700148 – ident: e_1_2_2_54_2 doi: 10.1002/cctc.201700042 – ident: e_1_2_2_72_1 doi: 10.1021/acs.chemrev.5b00203 – ident: e_1_2_2_81_3 doi: 10.1002/ange.201608345 – ident: e_1_2_2_61_3 doi: 10.1002/ange.201607579 – ident: e_1_2_2_74_2 doi: 10.1021/acs.chemrev.6b00043 – ident: e_1_2_2_80_2 doi: 10.1021/acs.orglett.6b02610 – ident: e_1_2_2_89_1 doi: 10.1002/zaac.200900313 – ident: e_1_2_2_16_3 doi: 10.1002/ange.201205570 – ident: e_1_2_2_32_2 doi: 10.1021/ol4001679 – ident: e_1_2_2_84_2 doi: 10.1002/anie.200906302 – ident: e_1_2_2_25_2 doi: 10.1021/acscatal.6b01045 – ident: e_1_2_2_17_2 doi: 10.1021/jacs.7b07167 – ident: e_1_2_2_27_2 doi: 10.1021/acscatal.5b02953 – ident: e_1_2_2_75_2 doi: 10.1039/B802882F – ident: e_1_2_2_3_2 doi: 10.1039/C3QI00079F – ident: e_1_2_2_12_2 doi: 10.1021/om500966t – ident: e_1_2_2_57_2 doi: 10.1021/jacs.7b00879 – ident: e_1_2_2_36_1 – ident: e_1_2_2_88_1 doi: 10.1002/chem.201701442 – ident: e_1_2_2_35_1 doi: 10.1038/nature09913 – ident: e_1_2_2_33_2 doi: 10.1002/anie.201306629 – ident: e_1_2_2_41_1 – ident: e_1_2_2_6_1 – ident: e_1_2_2_70_1 doi: 10.1016/S0022-328X(00)81751-9 – ident: e_1_2_2_11_2 doi: 10.1039/C5SC02855H – ident: e_1_2_2_45_3 doi: 10.1002/ange.201702406 – ident: e_1_2_2_52_2 doi: 10.1021/acscatal.7b00943 – ident: e_1_2_2_49_3 doi: 10.1002/ange.201607233 – ident: e_1_2_2_19_1 doi: 10.1002/anie.200301628 – ident: e_1_2_2_26_2 doi: 10.1021/acs.orglett.6b03254 – ident: e_1_2_2_1_1 – ident: e_1_2_2_68_1 doi: 10.1021/ja00360a054 – ident: e_1_2_2_30_4 doi: 10.1002/ange.201506075 – ident: e_1_2_2_46_2 doi: 10.1002/chem.201604991 – ident: e_1_2_2_67_1 doi: 10.1016/j.ica.2016.02.064 – ident: e_1_2_2_50_3 doi: 10.1002/ange.201606218 – ident: e_1_2_2_63_2 doi: 10.1002/anie.201709441 – ident: e_1_2_2_85_2 doi: 10.1016/j.apcata.2010.06.052 – ident: e_1_2_2_76_2 doi: 10.1021/cr100088b – ident: e_1_2_2_9_2 doi: 10.1002/anie.201606979 – ident: e_1_2_2_73_1 – ident: e_1_2_2_69_1 doi: 10.1021/ic00188a003 – ident: e_1_2_2_82_2 doi: 10.1021/jacs.6b07245 – ident: e_1_2_2_24_2 doi: 10.1021/jacs.6b08128 – ident: e_1_2_2_60_2 doi: 10.1002/anie.201704184 – ident: e_1_2_2_4_2 doi: 10.1039/C4RA14417A – ident: e_1_2_2_30_3 doi: 10.1002/ange.201506075 – ident: e_1_2_2_84_3 doi: 10.1002/ange.200906302 – ident: e_1_2_2_64_1 doi: 10.1002/ejic.200300832 – ident: e_1_2_2_87_2 doi: 10.1039/C4CC08163C – ident: e_1_2_2_15_2 doi: 10.1002/anie.201202175 – ident: e_1_2_2_51_3 doi: 10.1002/ange.201705471 – ident: e_1_2_2_34_3 doi: 10.1002/ange.201205946 |
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| Snippet | The synthesis and structures of the first SiII‐donor supported manganese(II) complexes [L1]MnCl2, [L2]MnCl2, and [L3]2MnCl2 are reported, bearing a pincer‐type... The synthesis and structures of the first Si II ‐donor supported manganese(II) complexes [L1]MnCl 2 , [L2]MnCl 2 , and [L3] 2 MnCl 2 are reported, bearing a... The synthesis and structures of the first Si -donor supported manganese(II) complexes [L1]MnCl , [L2]MnCl , and [L3] MnCl are reported, bearing a pincer-type... The synthesis and structures of the first SiII -donor supported manganese(II) complexes [L1]MnCl2 , [L2]MnCl2 , and [L3]2 MnCl2 are reported, bearing a... |
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| SubjectTerms | Alkenes Alkynes Ammonia Catalysts Catalytic converters Chemical synthesis Chemistry Coordination compounds E-olefins Functional groups Hydrogen storage Ligands Manganese N-heterocyclic silylene Nitrogen dioxide Pyridines stereoselective catalysis Substrates transfer semi-hydrogenation |
| Title | Stereoselective Transfer Semi‐Hydrogenation of Alkynes to E‐Olefins with N‐Heterocyclic Silylene–Manganese Catalysts |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.201705745 https://www.ncbi.nlm.nih.gov/pubmed/29228457 https://www.proquest.com/docview/2023050967 https://www.proquest.com/docview/1976003095 |
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