Nucleation and Growth Mechanism of Anion‐Derived Solid Electrolyte Interphase in Rechargeable Batteries

• Published in: Angewandte Chemie International Edition Vol. 60; no. 15; pp. 8521 - 8525
• Main Authors: Yan, Chong, Jiang, Li‐Li, Yao, Yu‐Xing, Lu, Yang, Huang, Jia‐Qi, Zhang, Qiang
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 06.04.2021
• Edition: International ed. in English
• Subjects: Anions; Atomic force microscopes; Atomic force microscopy; Batteries; Crystallization; Electrochemistry; Electrolytes; Growth models; interfacial chemistry; Interphase; Ion transport; isothermal electrochemical crystallization; Lithium; Nucleation; nucleation and growth mechanism; Rechargeable batteries; solid electrolyte interphase; Solid electrolytes; Surface reactions; Two dimensional models; two-dimension (2D) growth; nucleation and growth mechanism; isothermal electrochemical crystallization; two-dimension (2D) growth; solid electrolyte interphase; interfacial chemistry

Solid electrolyte interphase (SEI) has been widely employed to describe the new phase formed between anode and electrolyte in working batteries. Significant advances have been achieved on the structure and composition of SEI as well as on the possible ion transport mechanism. However, the nucleation...