Simultaneous Modulation of Magnetic and Dielectric Transition via Spin‐Crossover‐Tuned Spin Arrangement and Charge Distribution

• Published in: Angewandte Chemie International Edition Vol. 57; no. 28; pp. 8468 - 8472
• Main Authors: Zheng, Hui, Meng, Yin‐Shan, Zhou, Guang‐Li, Duan, Chun‐Ying, Sato, Osamu, Hayami, Shinya, Luo, Yi, Liu, Tao
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 09.07.2018
• Edition: International ed. in English
• Subjects: Antiferromagnetism; Charge distribution; coordination chemistry; Dielectric properties; Electrical properties; External stimuli; Heat treatment; Ions; iron; Irradiation; Light irradiation; magnetic interactions; Magnetic properties; multifuntional materials; Radiation; spin-crossover complexes; iron; magnetic interactions; multifuntional materials; coordination chemistry; spin-crossover complexes

Magnetic and dielectric properties have been tuned simultaneously by external stimuli with rapid and sensitive response, which is crucial to monitor the magnetic state via capacitive measurement. Herein, positive charged FeII ions were linked via negative charged [(Tp)FeIII(CN)3]− (Tp=hydrotris(pyra...